为了研究等温锻造温度对机械外壳用Mg-8Al-1Zn-0.5Ca镁合金组织与性能的影响,选择5种等温锻造温度对合金试样进行锻造试验,并进行了显微组织分析、耐腐蚀和耐磨损性能的测试与分析。结果发现:随着等温锻造温度从340℃增加至420℃,Mg-8Al...为了研究等温锻造温度对机械外壳用Mg-8Al-1Zn-0.5Ca镁合金组织与性能的影响,选择5种等温锻造温度对合金试样进行锻造试验,并进行了显微组织分析、耐腐蚀和耐磨损性能的测试与分析。结果发现:随着等温锻造温度从340℃增加至420℃,Mg-8Al-1Zn-0.5Ca镁合金的平均晶粒尺寸先减小后增大、腐蚀电位先正移后负移、磨损体积先减小后增大,合金的耐腐蚀和耐磨损性能先变好后变差。相较于等温锻造温度为340℃,等温锻造温度为400℃时的Mg-8Al-1Zn-0.5Ca镁合金的平均晶粒尺寸减小了76.1%、腐蚀电位正移141 m V、磨损体积减小了66.2%。研究结果表明,Mg-8Al-1Zn-0.5Ca镁合金的等温锻造温度优选为400℃。展开更多
The single-phase Mg-4Li-0.5Ca alloy was rolled at three different temperatures(250,300 and 350℃)and followed by annealing at 200°C for 10 min.To evaluate the mechanical properties,the tensile test was conducted ...The single-phase Mg-4Li-0.5Ca alloy was rolled at three different temperatures(250,300 and 350℃)and followed by annealing at 200°C for 10 min.To evaluate the mechanical properties,the tensile test was conducted at a constant strain rate of 10^(-3)s^(-1).Factors influencing the tensile strength and strain hardening properties were assessed by microscopy,XRD and EBSD analysis.Besides,Kocks-Mecking plots(K-M)were used to determine the different stages of strain hardening exhibited by the variously processed Mg-4Li-0.5Ca alloy test specimens.The ultimate tensile strength has decreased as hot-rolling temperature in creases with increased ductility.The strain hardening properties such as hardening capacity(Hc),strain hardening exponent(n)are increased significantly with an increase in hot rolling temperature and subsequent annealing.展开更多
The influences of the PbO-B2O3-CuV2O6 （PBC） additives on the microwave dielectric properties of （Pb0.5Ca0.5） （Fe0.5Nb0.5）O3 （PCFN） ceramics were investigated as a function of sintering temperature from 950 ℃ ...The influences of the PbO-B2O3-CuV2O6 （PBC） additives on the microwave dielectric properties of （Pb0.5Ca0.5） （Fe0.5Nb0.5）O3 （PCFN） ceramics were investigated as a function of sintering temperature from 950 ℃ to 1 100 ℃. The sintering temperature of the specimens with the glass could be lowered from 1125 ℃ to 1 025℃ without the degradation of microwave dielectric properties. The microwave results showed that the dielectric constant cr was not significantly different while Qf values decreased with the increase of CuV206 content of PBC glass. For the specimens doped with PB-CV0.1 glass （81% PbO-9% B203-10% CuV2O6） and sintered at 1 025 ℃ for 3 h, the microwave dielectric properties of Qf=4 823 GHz, Cr=107.1 with TCF=＋15.03 ×10^-6/℃ were obtained.展开更多
The microstructure revolution and mechanical properties of as-extruded and peak-aged Mg−6Zn−1Mn−4Sn−0.5Ca(ZMT614−0.5Ca)alloy were studied by OM,SEM,TEM,hardness testing and tensile testing.The results showed that the ...The microstructure revolution and mechanical properties of as-extruded and peak-aged Mg−6Zn−1Mn−4Sn−0.5Ca(ZMT614−0.5Ca)alloy were studied by OM,SEM,TEM,hardness testing and tensile testing.The results showed that the as-cast ZMT614−0.5Ca alloy mainly consisted of α-Mg,Mg−Zn and CaMgSn phase.The hot extrusion process effectively refined the microstructure and led to a completely dynamic recrystallized microstructure.The average grain size of as-extruded alloy was^4.85μm.After solution treatment,remained CaMgSn with high melting point played a significant role in pinning effect and impeding the migration of grain boundary.After aging treatment,peak-aged ZMT614−0.5Ca alloy exhibited a good combination of strength and ductility,with yield strength,ultimate tensile strength and elongation being 338 MPa,383 MPa and 7.5%,respectively.The yield strength of the alloy increased significantly by around 36%compared with that in as-extruded condition,which should be attributed to the precipitation strengthening of β'phase.展开更多
The effects of heat treatment on microstructures and hardening response of Mg-6Zn4）.5Er4）.5Ca （wt%） alloy were investigated by optical microscope （OM）, scanning elec- tron microscope （SEM）, and transmission el...The effects of heat treatment on microstructures and hardening response of Mg-6Zn4）.5Er4）.5Ca （wt%） alloy were investigated by optical microscope （OM）, scanning elec- tron microscope （SEM）, and transmission electron microscope （TEM） in this paper. The results show that the Mg（Zn4）.5Er- 0.5Ca alloy contains Mg3Zn6Erx quasicrystalline phase （I- phase） and Ca2Mg6Zn3 phase under as-cast condition. Most of the Ca2Mg6Zn3 phases and I-phases dissolve into matrix during heat treatment at 475 ℃ for 5 h. After the as-solution alloy was aged at 175 ℃ for 36 h, a large amount of MgZn2 precipitate with several nanometers precipitate. It is suggested that the trace addition of Ca results in refining the size of the precipitate, and the presence of the nanoscale MgZn2 phase is the main factor to improve the peak-aged hardness greatly to 87 HV, which in- creases about 40 % compared with that of as-cast alloy.展开更多
This work investigated the microwave dielectric properties of A-site substitution by rare earth La3＋in（Pb0.5Ca0.5）（Fe0.5Ta0.5）O3（PCFT） system.A single perovskite phase was obtained only when the doping content ...This work investigated the microwave dielectric properties of A-site substitution by rare earth La3＋in（Pb0.5Ca0.5）（Fe0.5Ta0.5）O3（PCFT） system.A single perovskite phase was obtained only when the doping content was 2%.Suitable La3＋ doping improved microwave dielectric performances.Excessive La3＋doping caused the formation of secondary phase,which resulted in the decreasing of permittivity εrand quality factor Qfvalues.Especially,when the doping content is 2%-5%,permittivity εrwas above 75 and Qfvalues were 6 902-7 416 GHz.展开更多
文摘为了研究等温锻造温度对机械外壳用Mg-8Al-1Zn-0.5Ca镁合金组织与性能的影响,选择5种等温锻造温度对合金试样进行锻造试验,并进行了显微组织分析、耐腐蚀和耐磨损性能的测试与分析。结果发现:随着等温锻造温度从340℃增加至420℃,Mg-8Al-1Zn-0.5Ca镁合金的平均晶粒尺寸先减小后增大、腐蚀电位先正移后负移、磨损体积先减小后增大,合金的耐腐蚀和耐磨损性能先变好后变差。相较于等温锻造温度为340℃,等温锻造温度为400℃时的Mg-8Al-1Zn-0.5Ca镁合金的平均晶粒尺寸减小了76.1%、腐蚀电位正移141 m V、磨损体积减小了66.2%。研究结果表明,Mg-8Al-1Zn-0.5Ca镁合金的等温锻造温度优选为400℃。
文摘The single-phase Mg-4Li-0.5Ca alloy was rolled at three different temperatures(250,300 and 350℃)and followed by annealing at 200°C for 10 min.To evaluate the mechanical properties,the tensile test was conducted at a constant strain rate of 10^(-3)s^(-1).Factors influencing the tensile strength and strain hardening properties were assessed by microscopy,XRD and EBSD analysis.Besides,Kocks-Mecking plots(K-M)were used to determine the different stages of strain hardening exhibited by the variously processed Mg-4Li-0.5Ca alloy test specimens.The ultimate tensile strength has decreased as hot-rolling temperature in creases with increased ductility.The strain hardening properties such as hardening capacity(Hc),strain hardening exponent(n)are increased significantly with an increase in hot rolling temperature and subsequent annealing.
基金Project supported by the National Natural Science Foundation of China (Grant No.60578041)the National High Tech-nology Research and Development Program of China (Grant No.715-006-0060)
文摘The influences of the PbO-B2O3-CuV2O6 （PBC） additives on the microwave dielectric properties of （Pb0.5Ca0.5） （Fe0.5Nb0.5）O3 （PCFN） ceramics were investigated as a function of sintering temperature from 950 ℃ to 1 100 ℃. The sintering temperature of the specimens with the glass could be lowered from 1125 ℃ to 1 025℃ without the degradation of microwave dielectric properties. The microwave results showed that the dielectric constant cr was not significantly different while Qf values decreased with the increase of CuV206 content of PBC glass. For the specimens doped with PB-CV0.1 glass （81% PbO-9% B203-10% CuV2O6） and sintered at 1 025 ℃ for 3 h, the microwave dielectric properties of Qf=4 823 GHz, Cr=107.1 with TCF=＋15.03 ×10^-6/℃ were obtained.
基金Project(2016YFB0301101)supported by the National Key Research and Development Program of ChinaProjects(51571040,U1764253,51531002)supported by the National Natural Science Foundation of China。
文摘The microstructure revolution and mechanical properties of as-extruded and peak-aged Mg−6Zn−1Mn−4Sn−0.5Ca(ZMT614−0.5Ca)alloy were studied by OM,SEM,TEM,hardness testing and tensile testing.The results showed that the as-cast ZMT614−0.5Ca alloy mainly consisted of α-Mg,Mg−Zn and CaMgSn phase.The hot extrusion process effectively refined the microstructure and led to a completely dynamic recrystallized microstructure.The average grain size of as-extruded alloy was^4.85μm.After solution treatment,remained CaMgSn with high melting point played a significant role in pinning effect and impeding the migration of grain boundary.After aging treatment,peak-aged ZMT614−0.5Ca alloy exhibited a good combination of strength and ductility,with yield strength,ultimate tensile strength and elongation being 338 MPa,383 MPa and 7.5%,respectively.The yield strength of the alloy increased significantly by around 36%compared with that in as-extruded condition,which should be attributed to the precipitation strengthening of β'phase.
基金financial supported by the National Natural Science Foundation of China(No.51301006)the Projects of Beijing Municipal Science and Technology Commission(No.Z131100003213019)+1 种基金the Projects of Beijing Municipal Commission of Education(Nos.KM201310005001 and KM201410005014)Beijing Natural Science Foundation(No.2142005)
文摘The effects of heat treatment on microstructures and hardening response of Mg-6Zn4）.5Er4）.5Ca （wt%） alloy were investigated by optical microscope （OM）, scanning elec- tron microscope （SEM）, and transmission electron microscope （TEM） in this paper. The results show that the Mg（Zn4）.5Er- 0.5Ca alloy contains Mg3Zn6Erx quasicrystalline phase （I- phase） and Ca2Mg6Zn3 phase under as-cast condition. Most of the Ca2Mg6Zn3 phases and I-phases dissolve into matrix during heat treatment at 475 ℃ for 5 h. After the as-solution alloy was aged at 175 ℃ for 36 h, a large amount of MgZn2 precipitate with several nanometers precipitate. It is suggested that the trace addition of Ca results in refining the size of the precipitate, and the presence of the nanoscale MgZn2 phase is the main factor to improve the peak-aged hardness greatly to 87 HV, which in- creases about 40 % compared with that of as-cast alloy.
基金Project supported by the National Natural Science Foundation of China (Grant No.60578041)the National High Technology Research and Development Program of China (Grant No.715-006-0060)
文摘This work investigated the microwave dielectric properties of A-site substitution by rare earth La3＋in（Pb0.5Ca0.5）（Fe0.5Ta0.5）O3（PCFT） system.A single perovskite phase was obtained only when the doping content was 2%.Suitable La3＋ doping improved microwave dielectric performances.Excessive La3＋doping caused the formation of secondary phase,which resulted in the decreasing of permittivity εrand quality factor Qfvalues.Especially,when the doping content is 2%-5%,permittivity εrwas above 75 and Qfvalues were 6 902-7 416 GHz.
