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新型抗水氯氧镁水泥的研究 被引量:33
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作者 余红发 《硅酸盐学报》 EI CAS CSCD 北大核心 1992年第4期374-381,共8页
研究了新型抗水氯氧镁水泥的水化产物、显微结构和主要性能。XRD,DTA,SEM和EDAX分析表明,其主要水化产物5·1·8在不同条件下有4种形态,且Ca,P和S元素固溶量不同。未反应MgO微粒均匀分散在5·1·8凝胶内是其结构的主要... 研究了新型抗水氯氧镁水泥的水化产物、显微结构和主要性能。XRD,DTA,SEM和EDAX分析表明,其主要水化产物5·1·8在不同条件下有4种形态,且Ca,P和S元素固溶量不同。未反应MgO微粒均匀分散在5·1·8凝胶内是其结构的主要特征,不稳定的针杆状5·1·8晶体只在孔洞内少量形成。从显微结构的观点分析了其抗水机理。 展开更多
关键词 氯氧镁水泥 5·1·8 结晶相 凝胶相 抗水性
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Effect of Mixing on Properties and Microstructure of Magnesium Oxychloride Cement 被引量:5
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作者 HE Zhenhui YANG Hongjian +2 位作者 SONG Hui GUO Tao WU Songyi 《Journal of the Chinese Ceramic Society》 2016年第1期38-45,共8页
This paper investigated the effect of mixing on the properties of magnesium oxychloride cement, such as apparent viscosity, setting time, compressive strength, and specific strength as well. The phase composition and ... This paper investigated the effect of mixing on the properties of magnesium oxychloride cement, such as apparent viscosity, setting time, compressive strength, and specific strength as well. The phase composition and crystallographic structure of the cement were determined by X-ray diffraction and scanning electron microscopy. The results indicate that the increases of stirring rate and mixing time change apparent viscosity distinctly, shorten setting time and enhance mechanical property. Magnesium oxychloride cement after mixing for 20 min exhibits the optimal mechanical performance. The effect of stirring rate on the phase composition of magnesium oxychloride cement dominates over the effect of mixing time. The increases of stirring rate and mixing time can increase the dispersion state and accelerate the neutralization, thus promoting the strength of magnesium oxychloride cement due to the formation of stable 5·1·8 phase, needle-like crystals and continuous crystalline structure in the whole cement matrix. The properties and microstructure of magnesium oxychloride cement at a stirring rate of 280 rpm are better than those at 140 rpm. 展开更多
关键词 magnesium oxychloride cement polynuclearaquo hydroxoco magnesium complex ions stirring rate mixing time 5·1·8 phase
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