A catalyst consisting of platinum nanoparticles on a ZIF-8 support（Pt@ZIF-8） was synthesized in a straightforward one-step procedure,by adding a nanostructured platinum sol during the formation of ZIF-8 at room temp...A catalyst consisting of platinum nanoparticles on a ZIF-8 support（Pt@ZIF-8） was synthesized in a straightforward one-step procedure,by adding a nanostructured platinum sol during the formation of ZIF-8 at room temperature.Pt@ZIF-8 was highly porous and well crystallized.The Pt nanoparticles were well dispersed within the ZIF-8 support.In the hydrogenation of 1,4-butynediol,Pt@ZIF-8 exhibited high activity,excellent selectivity for 1,4-butenediol of greater than 94%,and reusability.The Pt@ZIF-8 catalyst did not require further additives.The favorable catalytic performance was attributed primarily to the modification of the ZIF-8 support by the platinum nanoparticles.展开更多
采用动电位扫描、扫描电子显微镜和X-射线衍射分析分别研究了不同质量浓度的糖精和1,4-丁炔二醇对镍电沉积层的极化作用、表面形貌及晶体取向的影响。结果表明:在瓦特镀镍液中加入糖精和1,4-丁炔二醇,极化曲线均向负电位方向移动。糖精...采用动电位扫描、扫描电子显微镜和X-射线衍射分析分别研究了不同质量浓度的糖精和1,4-丁炔二醇对镍电沉积层的极化作用、表面形貌及晶体取向的影响。结果表明:在瓦特镀镍液中加入糖精和1,4-丁炔二醇,极化曲线均向负电位方向移动。糖精质量浓度增加至2.0 g/L时,极化曲线不再向负电位方向移动,镀层呈现(200)面择优取向。当1,4-丁炔二醇质量浓度增加到0.5 g/L时,其显著提高了镍电沉积过电位230 m V,有效增大成核密度,其镀层微观形貌平整均匀,择优取向并未发生改变。展开更多
基金supported by the National Natural Science Foundation of China(21573031 and 21428301)the Fundamental Research Funds for the Central Universities(DUT15ZD106 and DUT15RC(4)09)~~
文摘A catalyst consisting of platinum nanoparticles on a ZIF-8 support（Pt@ZIF-8） was synthesized in a straightforward one-step procedure,by adding a nanostructured platinum sol during the formation of ZIF-8 at room temperature.Pt@ZIF-8 was highly porous and well crystallized.The Pt nanoparticles were well dispersed within the ZIF-8 support.In the hydrogenation of 1,4-butynediol,Pt@ZIF-8 exhibited high activity,excellent selectivity for 1,4-butenediol of greater than 94%,and reusability.The Pt@ZIF-8 catalyst did not require further additives.The favorable catalytic performance was attributed primarily to the modification of the ZIF-8 support by the platinum nanoparticles.
文摘采用动电位扫描、扫描电子显微镜和X-射线衍射分析分别研究了不同质量浓度的糖精和1,4-丁炔二醇对镍电沉积层的极化作用、表面形貌及晶体取向的影响。结果表明:在瓦特镀镍液中加入糖精和1,4-丁炔二醇,极化曲线均向负电位方向移动。糖精质量浓度增加至2.0 g/L时,极化曲线不再向负电位方向移动,镀层呈现(200)面择优取向。当1,4-丁炔二醇质量浓度增加到0.5 g/L时,其显著提高了镍电沉积过电位230 m V,有效增大成核密度,其镀层微观形貌平整均匀,择优取向并未发生改变。
