A new cadmium（N） compound, {[ CdLu-（4,4＇-dps） ]2（H2O）2]＇（4＇abs ）2（H2O）2n 1 （4,4＇-dps = 4,4＇-dipyridylsulfide, 4-abs = deprotonated 4-amino benzenesulfonic acid）, has been synthesized and structurally ...A new cadmium（N） compound, {[ CdLu-（4,4＇-dps） ]2（H2O）2]＇（4＇abs ）2（H2O）2n 1 （4,4＇-dps = 4,4＇-dipyridylsulfide, 4-abs = deprotonated 4-amino benzenesulfonic acid）, has been synthesized and structurally characterized. It belongs to the orthorhombic system, space group Pbcn with a = 19.950（3）, b = 10.6381（13）, c = 18.055（2）A, V= 3831.8（8） A3, Z = 4, C32H36CdN6010S4, Mr = 905.31, F（000） = 1848, μ= 0.850 mm^-1, Dc = 1.569 Mg/m^3, the final R = 0.0238 and wR = 0.0589 for 3080 observed reflections with I 〉 2σ（I）. Complex I is a one-dimensional linear chain coordination polymer and the repeat unit is comprised of doubly charged cadmium complex cation, uncoordinated 4-aminobenzene sulfonate anions and water molecules. The cadmium（H） ion adopts a six-coordinate distorted octahedral geometry. Complex 1 is stabilized and linked into a three-dimensional layered structure through intermolecular O-H…O and N-H…O hydrogen bonds together with electrostatic force. The cyclic voltammograms and fluorescence spectrum of 1 were also measured. It shows one irreversible redox process and emits a very strong and sharp fluorescent band at about 341 nm.展开更多
A new coordination polymer [Zn（isop）（bps）]n 1（H2isop=benzene-1,3-dicer-boxylic acid,bps=4,4 -dipyridyl sulfide） has been prepared and structurally characterized by X-ray diffraction method.It crystallizes in mon...A new coordination polymer [Zn（isop）（bps）]n 1（H2isop=benzene-1,3-dicer-boxylic acid,bps=4,4 -dipyridyl sulfide） has been prepared and structurally characterized by X-ray diffraction method.It crystallizes in monoclinic,space group P21/n with a=12.1936（11）,b=10.7720（9）,c=13.0685（11）,V=1709.0（3）3,C18H12N2O4SZn,Mr=417.76,Z=4,Dc=1.624g/cm3,S=1.046,F（000）=848,the final R=0.0305 and wR=0.0858 for 3085 independent reflections with Rint=0.0147.Single-crystal X-ray diffraction analyses reveal that 1 is a 4-fold interpenetrating diamondoid network. The zinc（Ⅱ） atom is coordinated by two nitrogen atoms of two bps and two carboxylate oxygen atoms of isop ligands, resulting in a tetrahedral geometry.展开更多
基金supported by the National Natural Science Foundation of China (No. 20471026)the Natural Science Foundation of Henan Province (No. 0311021200)
文摘A new cadmium（N） compound, {[ CdLu-（4,4＇-dps） ]2（H2O）2]＇（4＇abs ）2（H2O）2n 1 （4,4＇-dps = 4,4＇-dipyridylsulfide, 4-abs = deprotonated 4-amino benzenesulfonic acid）, has been synthesized and structurally characterized. It belongs to the orthorhombic system, space group Pbcn with a = 19.950（3）, b = 10.6381（13）, c = 18.055（2）A, V= 3831.8（8） A3, Z = 4, C32H36CdN6010S4, Mr = 905.31, F（000） = 1848, μ= 0.850 mm^-1, Dc = 1.569 Mg/m^3, the final R = 0.0238 and wR = 0.0589 for 3080 observed reflections with I 〉 2σ（I）. Complex I is a one-dimensional linear chain coordination polymer and the repeat unit is comprised of doubly charged cadmium complex cation, uncoordinated 4-aminobenzene sulfonate anions and water molecules. The cadmium（H） ion adopts a six-coordinate distorted octahedral geometry. Complex 1 is stabilized and linked into a three-dimensional layered structure through intermolecular O-H…O and N-H…O hydrogen bonds together with electrostatic force. The cyclic voltammograms and fluorescence spectrum of 1 were also measured. It shows one irreversible redox process and emits a very strong and sharp fluorescent band at about 341 nm.
基金supported by Chongqing University of Posts and Telecommunications Youth Fund (A2006-50)
文摘A new coordination polymer [Zn（isop）（bps）]n 1（H2isop=benzene-1,3-dicer-boxylic acid,bps=4,4 -dipyridyl sulfide） has been prepared and structurally characterized by X-ray diffraction method.It crystallizes in monoclinic,space group P21/n with a=12.1936（11）,b=10.7720（9）,c=13.0685（11）,V=1709.0（3）3,C18H12N2O4SZn,Mr=417.76,Z=4,Dc=1.624g/cm3,S=1.046,F（000）=848,the final R=0.0305 and wR=0.0858 for 3085 independent reflections with Rint=0.0147.Single-crystal X-ray diffraction analyses reveal that 1 is a 4-fold interpenetrating diamondoid network. The zinc（Ⅱ） atom is coordinated by two nitrogen atoms of two bps and two carboxylate oxygen atoms of isop ligands, resulting in a tetrahedral geometry.
