A new triterpene and a saponin, named 2α,3β23-trihydroxyurs-20-en-28-oic acid (1) and 2α,3β,23-trihydroxyurs-20-en-28-oic acid O-α-L-rhanmopyranosyl-(1→4)-O-β-D-glucopyranosyl-(1→6)-O-β-D-glucopyranosyl...A new triterpene and a saponin, named 2α,3β23-trihydroxyurs-20-en-28-oic acid (1) and 2α,3β,23-trihydroxyurs-20-en-28-oic acid O-α-L-rhanmopyranosyl-(1→4)-O-β-D-glucopyranosyl-(1→6)-O-β-D-glucopyranosyl ester (2), have been isolated from the aerial part of CenteUa asiatica. Their structures were elucidated by spectral methods, including 2D-NMR spectra.展开更多
Two new l-(6'-O-acyl-β-D-glucopyranosyl)pyridinium-3-carboxylates,lonijaponinicotinosides A(1)and B(2),were isolated from an aqueous extract of the flower buds of Lonicera japonica.Their structures were determ...Two new l-(6'-O-acyl-β-D-glucopyranosyl)pyridinium-3-carboxylates,lonijaponinicotinosides A(1)and B(2),were isolated from an aqueous extract of the flower buds of Lonicera japonica.Their structures were determined by spectroscopic data analysis,and confirmed by comparison with synthetic 1-β-Dglucopyranosylpyridinium-3-carboxylate.展开更多
文摘A new triterpene and a saponin, named 2α,3β23-trihydroxyurs-20-en-28-oic acid (1) and 2α,3β,23-trihydroxyurs-20-en-28-oic acid O-α-L-rhanmopyranosyl-(1→4)-O-β-D-glucopyranosyl-(1→6)-O-β-D-glucopyranosyl ester (2), have been isolated from the aerial part of CenteUa asiatica. Their structures were elucidated by spectral methods, including 2D-NMR spectra.
基金Financial support from the National Natural Science Foundation of China(NNSFCNos.20772156 and 30825044)+1 种基金the Program for Changjiang Scholars and Innovative Research Team in University(PCSIRT,No.IRT1007)the National Science and Technology Project of China(Nos.2012ZX09301002-002 and 2011ZX0 9307-002-01)
文摘Two new l-(6'-O-acyl-β-D-glucopyranosyl)pyridinium-3-carboxylates,lonijaponinicotinosides A(1)and B(2),were isolated from an aqueous extract of the flower buds of Lonicera japonica.Their structures were determined by spectroscopic data analysis,and confirmed by comparison with synthetic 1-β-Dglucopyranosylpyridinium-3-carboxylate.