Compound Zn(phen)3BDA (1) (BDA=6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthylene-4,4′-disul- fonate, phen= 1,10-phenanthroline) composes of the anion part (racemic-(R,S)-6,6′-dibromo-2,2′-dimethoxy-1,1′- binaphthy...Compound Zn(phen)3BDA (1) (BDA=6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthylene-4,4′-disul- fonate, phen= 1,10-phenanthroline) composes of the anion part (racemic-(R,S)-6,6′-dibromo-2,2′-dimethoxy-1,1′- binaphthylene-4,4′-disulfonate ) and the cation part which consists of a racemic octahedrally coordinated zinc center defined six nitrogen atoms from three phen rings to form an inorganic chirality that can be resolution by chiral organic ligand, the 3D framework was formed through the strong H-bonding interaction between sulfonate and water. CCDC: 277924.展开更多
The crystal structure of Mn(BDA)(bpy)2(H2O)(H2O)2 (1)(BDA=6,6′-dibromo-2,2′-dimethoxy-1,1′-bi- naphthylene-4,4′-disulfonate, bpy=2,2′-bipyridine) composes of a manganese center which is surrounded by two nitrogen...The crystal structure of Mn(BDA)(bpy)2(H2O)(H2O)2 (1)(BDA=6,6′-dibromo-2,2′-dimethoxy-1,1′-bi- naphthylene-4,4′-disulfonate, bpy=2,2′-bipyridine) composes of a manganese center which is surrounded by two nitrogen atoms from 2,2′-bipyridine and four oxygen atoms from three water and sulfonate group of BDA that also participate in H-bonding interactions to form 3D network as well as some uncoordinated water. CCDC: 277922.展开更多
文摘Compound Zn(phen)3BDA (1) (BDA=6,6′-dibromo-2,2′-dimethoxy-1,1′-binaphthylene-4,4′-disul- fonate, phen= 1,10-phenanthroline) composes of the anion part (racemic-(R,S)-6,6′-dibromo-2,2′-dimethoxy-1,1′- binaphthylene-4,4′-disulfonate ) and the cation part which consists of a racemic octahedrally coordinated zinc center defined six nitrogen atoms from three phen rings to form an inorganic chirality that can be resolution by chiral organic ligand, the 3D framework was formed through the strong H-bonding interaction between sulfonate and water. CCDC: 277924.
文摘The crystal structure of Mn(BDA)(bpy)2(H2O)(H2O)2 (1)(BDA=6,6′-dibromo-2,2′-dimethoxy-1,1′-bi- naphthylene-4,4′-disulfonate, bpy=2,2′-bipyridine) composes of a manganese center which is surrounded by two nitrogen atoms from 2,2′-bipyridine and four oxygen atoms from three water and sulfonate group of BDA that also participate in H-bonding interactions to form 3D network as well as some uncoordinated water. CCDC: 277922.
