以玻璃微珠、流化床裂化催化剂颗粒、褐煤和聚氯乙烯颗粒为实验物料,开展粉体流动性表征与料仓下料实验。研究发现,不同粉体的流动性差异较大,相应的料仓重力下料结果也不同;实验所用粉体的下料流率远低于传统Brown and Richards模型的...以玻璃微珠、流化床裂化催化剂颗粒、褐煤和聚氯乙烯颗粒为实验物料,开展粉体流动性表征与料仓下料实验。研究发现,不同粉体的流动性差异较大,相应的料仓重力下料结果也不同;实验所用粉体的下料流率远低于传统Brown and Richards模型的预测值。分析表明,颗粒间相互作用导致的粉体黏附团聚是阻碍细颗粒粉体下料流动的主要原因。基于上述分析,利用剪切测试结合摩尔应力圆理论获得床层拉伸应力,并借助Rumpf方程构建的颗粒间相互作用与粉体床层应力之间的模型来获得不同粉体的颗粒间作用力;继而采用Bond数对粉体床层空隙率进行修正,揭示了颗粒间相互作用对粉体床层结构的影响,并在此基础上建立了粉体下料流率预测模型。新建立的耦合颗粒间作用力的粉体流率模型,有效改善了传统模型对细颗粒粉体流率预测值偏高的弊端,显著降低了流率预测偏差。展开更多
An acrylic acid/acrylate ester copolymer was employed as a dispersant for Y\|TZP aqueous suspensions. The adsorption of the copolymer on Y\|TZP powder was characterized by using the COD(chemical oxygen demand) method....An acrylic acid/acrylate ester copolymer was employed as a dispersant for Y\|TZP aqueous suspensions. The adsorption of the copolymer on Y\|TZP powder was characterized by using the COD(chemical oxygen demand) method. The addition of this dispersant caused a dramatic increase of the \%ζ\% potential in alkaline region and broadened the stable pH region. SEM and effective diameter analysis showed that the copolymer pronouncedly improved the stability of the suspension. The force\|distance curve was measured by using the colloidal probe AFM method. The stabilizing mechanism of the dispersant was also discussed.展开更多
文摘以玻璃微珠、流化床裂化催化剂颗粒、褐煤和聚氯乙烯颗粒为实验物料,开展粉体流动性表征与料仓下料实验。研究发现,不同粉体的流动性差异较大,相应的料仓重力下料结果也不同;实验所用粉体的下料流率远低于传统Brown and Richards模型的预测值。分析表明,颗粒间相互作用导致的粉体黏附团聚是阻碍细颗粒粉体下料流动的主要原因。基于上述分析,利用剪切测试结合摩尔应力圆理论获得床层拉伸应力,并借助Rumpf方程构建的颗粒间相互作用与粉体床层应力之间的模型来获得不同粉体的颗粒间作用力;继而采用Bond数对粉体床层空隙率进行修正,揭示了颗粒间相互作用对粉体床层结构的影响,并在此基础上建立了粉体下料流率预测模型。新建立的耦合颗粒间作用力的粉体流率模型,有效改善了传统模型对细颗粒粉体流率预测值偏高的弊端,显著降低了流率预测偏差。
文摘An acrylic acid/acrylate ester copolymer was employed as a dispersant for Y\|TZP aqueous suspensions. The adsorption of the copolymer on Y\|TZP powder was characterized by using the COD(chemical oxygen demand) method. The addition of this dispersant caused a dramatic increase of the \%ζ\% potential in alkaline region and broadened the stable pH region. SEM and effective diameter analysis showed that the copolymer pronouncedly improved the stability of the suspension. The force\|distance curve was measured by using the colloidal probe AFM method. The stabilizing mechanism of the dispersant was also discussed.
