Dendritic polyesters bearing COOH groups at the focal points were grafted onto nanometer silica premodified with 3-aminopropyltriethoxysilane by N,N′-dicyclohexylcarbodiimide mediated amidation. The products were cha...Dendritic polyesters bearing COOH groups at the focal points were grafted onto nanometer silica premodified with 3-aminopropyltriethoxysilane by N,N′-dicyclohexylcarbodiimide mediated amidation. The products were characterized qualitatively by FTIR, TGA and elemental analysis. It was shown that a significant grafting (10%15% net grafting for this reaction) was obtained despite the steric hindrance of the dendrons.展开更多
文摘Dendritic polyesters bearing COOH groups at the focal points were grafted onto nanometer silica premodified with 3-aminopropyltriethoxysilane by N,N′-dicyclohexylcarbodiimide mediated amidation. The products were characterized qualitatively by FTIR, TGA and elemental analysis. It was shown that a significant grafting (10%15% net grafting for this reaction) was obtained despite the steric hindrance of the dendrons.