A batch equilibrium techniques was used to examine the effect of dissolved organic matter (DOM) extracted from both non-treated sludge (NTS) and heat-expanded sludge (HES) on the sorption and desorption of chlor...A batch equilibrium techniques was used to examine the effect of dissolved organic matter (DOM) extracted from both non-treated sludge (NTS) and heat-expanded sludge (HES) on the sorption and desorption of chlorotoluron (3-(3-chloro-p-tolyl)-1,1-dimethylurea) in two types of soils, a yellow fluvo-aquic and a red soil from China. Without DOM,sorption of chlorotoluron was significantly greater (P 〈 0.05) in the red soil than in the yellow fluvo-aquic soil. However,with DOM the effect was dependent on the soil type and nature of DOM. Chlorotoluron sorption was lower in the yellow fluvo-aquic soil than in the red soil, suggesting that with the same DOM levels the yellow fluvo-aquic soil had a lower sorption capacity for this herbicide. Application of DOM from both NTS and HES led to a general decrease in sorption to the soils and an increase in desorption from the soils. Desorption of chlorotoluron also significantly increased (P 〈 0.05) with an increase in the DOM concentration. Additionally, for sorption and desorption, at each DOM treatment level the NTS treatments were significantly lower (P 〈 0.05) than the HES treatments. This implied that non-treated sludge had a greater effect on the sorption and desorption of chlorotoluron than heat-expanded sludge.展开更多
渤海是我国重要的油气田经济海区,目前已陆续开发。沉积物类型及其氧化还原环境的研究对于了解沉积物的形成、来源,以及埋葬后的早期成岩作用具有重要意义。海洋沉积的环境是海洋地质学的重要研究内容之一,以往这方面的研究大多集中于...渤海是我国重要的油气田经济海区,目前已陆续开发。沉积物类型及其氧化还原环境的研究对于了解沉积物的形成、来源,以及埋葬后的早期成岩作用具有重要意义。海洋沉积的环境是海洋地质学的重要研究内容之一,以往这方面的研究大多集中于地球化学领域,而从化学角度研究这个问题的报道则很少,且缺乏系统性(Parker et al.,1983;展开更多
基金Project supported by the National Natural Science Foundation of China (No. 30170537).
文摘A batch equilibrium techniques was used to examine the effect of dissolved organic matter (DOM) extracted from both non-treated sludge (NTS) and heat-expanded sludge (HES) on the sorption and desorption of chlorotoluron (3-(3-chloro-p-tolyl)-1,1-dimethylurea) in two types of soils, a yellow fluvo-aquic and a red soil from China. Without DOM,sorption of chlorotoluron was significantly greater (P 〈 0.05) in the red soil than in the yellow fluvo-aquic soil. However,with DOM the effect was dependent on the soil type and nature of DOM. Chlorotoluron sorption was lower in the yellow fluvo-aquic soil than in the red soil, suggesting that with the same DOM levels the yellow fluvo-aquic soil had a lower sorption capacity for this herbicide. Application of DOM from both NTS and HES led to a general decrease in sorption to the soils and an increase in desorption from the soils. Desorption of chlorotoluron also significantly increased (P 〈 0.05) with an increase in the DOM concentration. Additionally, for sorption and desorption, at each DOM treatment level the NTS treatments were significantly lower (P 〈 0.05) than the HES treatments. This implied that non-treated sludge had a greater effect on the sorption and desorption of chlorotoluron than heat-expanded sludge.
文摘渤海是我国重要的油气田经济海区,目前已陆续开发。沉积物类型及其氧化还原环境的研究对于了解沉积物的形成、来源,以及埋葬后的早期成岩作用具有重要意义。海洋沉积的环境是海洋地质学的重要研究内容之一,以往这方面的研究大多集中于地球化学领域,而从化学角度研究这个问题的报道则很少,且缺乏系统性(Parker et al.,1983;