A simple ultrasound-assisted co-precipitation method was developed to prepare ferroferric oxide/graphene oxide magnetic nanoparticles(Fe_3O_4/CO MNPs).The hysteresis loop of Fe_3O_4/GO MNPs demonstrated that the sampl...A simple ultrasound-assisted co-precipitation method was developed to prepare ferroferric oxide/graphene oxide magnetic nanoparticles(Fe_3O_4/CO MNPs).The hysteresis loop of Fe_3O_4/GO MNPs demonstrated that the sample was typical of superparamagnetic material.The samples were characterized by transmission electron microscope,and it is found that the particles are of small size.The Fe_3O_4/GO MNPs were further used as an adsorbent to remove Rhodamine B.The effects of initial pH of the solution,the dosage of adsorbent,temperature,contact time and the presence of interfering dyes on adsorption performance were investigated as well.The adsorption equilibrium and kinetics data were fitted well with the Freundlich isotherm and the pseudosecond-order kinetic model respectively.The adsorption process followed intra-particle diffusion model with more than one process affecting the adsorption of Rhodamine B.And the adsorption process was endothermic in nature.Furthermore,the magnetic composite with a high adsorption capacity of Rhodamine B could be effectively and simply separated using an external magnetic field.And the used particles could be regenerated and recycled easily.The magnetic composite could find potential applications for the removal of dye pollutants.展开更多
采用超声辅助共沉淀法合成了以Eu^(3+)为激活离子的Ca Mo O_4荧光粉。通过X-射线衍射、扫描电镜(SEM)、荧光分光光度计对样品进行了表征和分析,研究了溶剂浓度、表面活性剂种类、表面活性剂添加量、超声时间等反应参数对Ca Mo O_4∶Eu^(...采用超声辅助共沉淀法合成了以Eu^(3+)为激活离子的Ca Mo O_4荧光粉。通过X-射线衍射、扫描电镜(SEM)、荧光分光光度计对样品进行了表征和分析,研究了溶剂浓度、表面活性剂种类、表面活性剂添加量、超声时间等反应参数对Ca Mo O_4∶Eu^(3+)发光性能的影响。结果表明:制备的样品为球形纯相四方晶系Ca Mo O_4晶体,在Ca Mo O_4∶Eu^(3+)中存在Mo O_4^(2-)到Eu^(3+)的能量传递。以50%丙酮溶液作为溶剂、PEG添加量为9 m L、Eu^(3+)掺杂浓度为10%、超声时间为10 min时,制备的样品在393 nm光激发下,Ca Mo O_4∶Eu^(3+)的最强峰所在位置是616 nm,实现了有效的红光发射,样品在紫外灯下呈现出明亮的红色。展开更多
Al/Co co-doped α-Ni（OH）2 samples were prepared by either ultrasonic co-precipitation method （Sample B） or co-precipitation method （Sample A）. The crystal structure and particle size distribution of the prepared...Al/Co co-doped α-Ni（OH）2 samples were prepared by either ultrasonic co-precipitation method （Sample B） or co-precipitation method （Sample A）. The crystal structure and particle size distribution of the prepared samples were examined by X-ray diffraction （XRD） and laser particle size analyzer, respectively. The results show that Sample B has more crystalline defects and smaller average diameter than Sample A. The cyclic voltammetry and electrochemical impedance spectroscopy measurements indicate that Sample B has better electrochemical performance than Sample A, such as better reaction reversibility, lower charge-transfer resistance and better cyclic stability. Proton diffusion coefficient of Sample B is 1.96×10-10cm2/s, which is two times as large as that （9.78×10-11cm2/s） of Sample A. The charge-discharge tests show that the discharge capacity （308 mA·h/g） of Sample B is 25 mA·h/g higher than that of Sample A （283 mA·h/g）.展开更多
基金Supported by the National Natural Science Foundation of China(21107143,21207033)the Fundamental Research Funds for the Central Universities,South-Central University for Nationalities(CZY15003)
文摘A simple ultrasound-assisted co-precipitation method was developed to prepare ferroferric oxide/graphene oxide magnetic nanoparticles(Fe_3O_4/CO MNPs).The hysteresis loop of Fe_3O_4/GO MNPs demonstrated that the sample was typical of superparamagnetic material.The samples were characterized by transmission electron microscope,and it is found that the particles are of small size.The Fe_3O_4/GO MNPs were further used as an adsorbent to remove Rhodamine B.The effects of initial pH of the solution,the dosage of adsorbent,temperature,contact time and the presence of interfering dyes on adsorption performance were investigated as well.The adsorption equilibrium and kinetics data were fitted well with the Freundlich isotherm and the pseudosecond-order kinetic model respectively.The adsorption process followed intra-particle diffusion model with more than one process affecting the adsorption of Rhodamine B.And the adsorption process was endothermic in nature.Furthermore,the magnetic composite with a high adsorption capacity of Rhodamine B could be effectively and simply separated using an external magnetic field.And the used particles could be regenerated and recycled easily.The magnetic composite could find potential applications for the removal of dye pollutants.
文摘采用超声辅助共沉淀法合成了以Eu^(3+)为激活离子的Ca Mo O_4荧光粉。通过X-射线衍射、扫描电镜(SEM)、荧光分光光度计对样品进行了表征和分析,研究了溶剂浓度、表面活性剂种类、表面活性剂添加量、超声时间等反应参数对Ca Mo O_4∶Eu^(3+)发光性能的影响。结果表明:制备的样品为球形纯相四方晶系Ca Mo O_4晶体,在Ca Mo O_4∶Eu^(3+)中存在Mo O_4^(2-)到Eu^(3+)的能量传递。以50%丙酮溶液作为溶剂、PEG添加量为9 m L、Eu^(3+)掺杂浓度为10%、超声时间为10 min时,制备的样品在393 nm光激发下,Ca Mo O_4∶Eu^(3+)的最强峰所在位置是616 nm,实现了有效的红光发射,样品在紫外灯下呈现出明亮的红色。
基金Project (10774030) supported by the National Natural Science Foundation of ChinaProject (2008J1-C161) supported by the Science and Technology Program of Guangzhou City of China
文摘Al/Co co-doped α-Ni（OH）2 samples were prepared by either ultrasonic co-precipitation method （Sample B） or co-precipitation method （Sample A）. The crystal structure and particle size distribution of the prepared samples were examined by X-ray diffraction （XRD） and laser particle size analyzer, respectively. The results show that Sample B has more crystalline defects and smaller average diameter than Sample A. The cyclic voltammetry and electrochemical impedance spectroscopy measurements indicate that Sample B has better electrochemical performance than Sample A, such as better reaction reversibility, lower charge-transfer resistance and better cyclic stability. Proton diffusion coefficient of Sample B is 1.96×10-10cm2/s, which is two times as large as that （9.78×10-11cm2/s） of Sample A. The charge-discharge tests show that the discharge capacity （308 mA·h/g） of Sample B is 25 mA·h/g higher than that of Sample A （283 mA·h/g）.
