Poly(TMPD)/MoO3 was constructed via a cooperative formation route from TMPD and molybdate ammonium at acidified conditions.XRD data showed a layered structure along c axis.IR and Raman spectra confirmed that TMPD had ...Poly(TMPD)/MoO3 was constructed via a cooperative formation route from TMPD and molybdate ammonium at acidified conditions.XRD data showed a layered structure along c axis.IR and Raman spectra confirmed that TMPD had been polymerized and intercalated into MoO3 layers.TGA curve gave the composition of [poly(TMPD)]0.23MoO3(H2O)0.31.Meanwhile,it was found that MoO3 accelerated the polymerization process of TMPD by entrapping the polymer and disturbing the balance between monomer and polymer with deposition of Poly(TMPD)/MoO3.According to this mechanism,a design for constructing layered polymer/MoO3 was proposed and a scheme was drawn also.展开更多
文摘Poly(TMPD)/MoO3 was constructed via a cooperative formation route from TMPD and molybdate ammonium at acidified conditions.XRD data showed a layered structure along c axis.IR and Raman spectra confirmed that TMPD had been polymerized and intercalated into MoO3 layers.TGA curve gave the composition of [poly(TMPD)]0.23MoO3(H2O)0.31.Meanwhile,it was found that MoO3 accelerated the polymerization process of TMPD by entrapping the polymer and disturbing the balance between monomer and polymer with deposition of Poly(TMPD)/MoO3.According to this mechanism,a design for constructing layered polymer/MoO3 was proposed and a scheme was drawn also.
