In order to improve the surface hydrophobicity, silicone rubber （SIR） samples were exposed to CF4 radio frequency （RF） capacitively coupled plasma （CCP）. Attenuated total reflection Fourier transform infrared （...In order to improve the surface hydrophobicity, silicone rubber （SIR） samples were exposed to CF4 radio frequency （RF） capacitively coupled plasma （CCP）. Attenuated total reflection Fourier transform infrared （ATR-FTIR） spectrum and X-ray photoelectron spectroscopy （XPS） were used to observe the variation of the functional groups of the modified SIR. Static contact angle （SCA） was employed to estimate the change of hydrophobicity of the modified SIR. The surface energy of SIR is reduced largely from 27.37 mJ/m^2 of original SIR sample to 2.94 mJ/m^2 of SIR sample treated by CF4 CCP modification at RF power of 200 W for a treatment time of 5 rnin. According to the XPS, ATR-FTIR and surface energy analysis, it is suggested that the improvement of hydrophobicity on the modified SIR surface is mainly ascribed to the decrease of surface energy, which is caused by the cooperation of the fluosilicic structure of Si--F or Si--F2 and the fluoric groups of C--CFn induced by the methyl replacement reaction and residual methyl groups of SIR surface.展开更多
The noble metal nanoparticles, such as gold, silver and copper, has been widely incorporated into the photoelectronic devices acting as a light-harvesting an- tenna and enhancing photocurrents through their light scat...The noble metal nanoparticles, such as gold, silver and copper, has been widely incorporated into the photoelectronic devices acting as a light-harvesting an- tenna and enhancing photocurrents through their light scattering or localized surface plasmon resonance effects. Here, this article presented the investigations into the use of gold nanocrystals to realize the plasmon-enhanced photocurrent generation in TiO2 nanorod-based quantum dots-sensitized solar cells （QDSSCs）. By introducing the gold nanocrystals, the short-circuit current density （Jsc） of QDSSCs was enhanced more than 10 % from 7.788 to 8.574 mA/cm^2 due to the direct injection of hot electrons from the gold nanocrystals to the photoanode. In order to confirm such conclusion, composite Au/TiO2 nanostructure was also fabricated. Indeed, the hot electrons injection resulted photocurrent density of ～5 mA/cm^2 was clearly observed under the visible light irradiation.展开更多
SY509-3-85 [篇名] Adhesion improvements for diamond-like carbon films on polycarbonate and polymethylmethacrylate substrates by ion plating with inductively coupled plasma；SY509-3-86 [篇名] An expert system to suppor...SY509-3-85 [篇名] Adhesion improvements for diamond-like carbon films on polycarbonate and polymethylmethacrylate substrates by ion plating with inductively coupled plasma；SY509-3-86 [篇名] An expert system to support the optimization of ion plating process: an OLAP-based fuzzy-cum-GA approach；……展开更多
Fort Myers,Florida,January4-9,2010 Plasma Spectrochemistry for Trace Element,Stable Isotope,and Elemental Speciation Analyses The 2010 Winter Conference on Plasma Spectrochemistry,sixteenth in a series of biennial mee...Fort Myers,Florida,January4-9,2010 Plasma Spectrochemistry for Trace Element,Stable Isotope,and Elemental Speciation Analyses The 2010 Winter Conference on Plasma Spectrochemistry,sixteenth in a series of biennial meetings sponsored by the ICP Information Newsletter,features developments in plasma spectrochemical analysis byinductively coupled plasma(ICP),展开更多
采用AG MP-1阴离子交换树脂,分别以7 mol/L HC l、2 mol/L HC l、0.5 mol/L HNO3作为淋洗剂,可有效分离Cu、Fe、Zn。介绍了方法的基本原理、化学分离过程及混合标准溶液与地质标样的分离结果。结果表明,Cu、Fe、Zn回收率均接近100%,标...采用AG MP-1阴离子交换树脂,分别以7 mol/L HC l、2 mol/L HC l、0.5 mol/L HNO3作为淋洗剂,可有效分离Cu、Fe、Zn。介绍了方法的基本原理、化学分离过程及混合标准溶液与地质标样的分离结果。结果表明,Cu、Fe、Zn回收率均接近100%,标准溶液在离子交换分离前后同位素组成一致,可以满足多接收器等离子体质谱对Cu、Fe、Zn同位素高精度分析的要求。展开更多
基金Project(05JT1034) supported by the Plan of Science and Technology Bureau of Hunan Province,China
文摘In order to improve the surface hydrophobicity, silicone rubber （SIR） samples were exposed to CF4 radio frequency （RF） capacitively coupled plasma （CCP）. Attenuated total reflection Fourier transform infrared （ATR-FTIR） spectrum and X-ray photoelectron spectroscopy （XPS） were used to observe the variation of the functional groups of the modified SIR. Static contact angle （SCA） was employed to estimate the change of hydrophobicity of the modified SIR. The surface energy of SIR is reduced largely from 27.37 mJ/m^2 of original SIR sample to 2.94 mJ/m^2 of SIR sample treated by CF4 CCP modification at RF power of 200 W for a treatment time of 5 rnin. According to the XPS, ATR-FTIR and surface energy analysis, it is suggested that the improvement of hydrophobicity on the modified SIR surface is mainly ascribed to the decrease of surface energy, which is caused by the cooperation of the fluosilicic structure of Si--F or Si--F2 and the fluoric groups of C--CFn induced by the methyl replacement reaction and residual methyl groups of SIR surface.
基金supported by the Program for Changjiang Scholars and Innovative Research Team in University(PCS IRT1126)the National Natural Science Foundation of China(11274093,61376061 and 61240053)
文摘The noble metal nanoparticles, such as gold, silver and copper, has been widely incorporated into the photoelectronic devices acting as a light-harvesting an- tenna and enhancing photocurrents through their light scattering or localized surface plasmon resonance effects. Here, this article presented the investigations into the use of gold nanocrystals to realize the plasmon-enhanced photocurrent generation in TiO2 nanorod-based quantum dots-sensitized solar cells （QDSSCs）. By introducing the gold nanocrystals, the short-circuit current density （Jsc） of QDSSCs was enhanced more than 10 % from 7.788 to 8.574 mA/cm^2 due to the direct injection of hot electrons from the gold nanocrystals to the photoanode. In order to confirm such conclusion, composite Au/TiO2 nanostructure was also fabricated. Indeed, the hot electrons injection resulted photocurrent density of ～5 mA/cm^2 was clearly observed under the visible light irradiation.
文摘SY509-3-85 [篇名] Adhesion improvements for diamond-like carbon films on polycarbonate and polymethylmethacrylate substrates by ion plating with inductively coupled plasma；SY509-3-86 [篇名] An expert system to support the optimization of ion plating process: an OLAP-based fuzzy-cum-GA approach；……
文摘Fort Myers,Florida,January4-9,2010 Plasma Spectrochemistry for Trace Element,Stable Isotope,and Elemental Speciation Analyses The 2010 Winter Conference on Plasma Spectrochemistry,sixteenth in a series of biennial meetings sponsored by the ICP Information Newsletter,features developments in plasma spectrochemical analysis byinductively coupled plasma(ICP),
文摘采用AG MP-1阴离子交换树脂,分别以7 mol/L HC l、2 mol/L HC l、0.5 mol/L HNO3作为淋洗剂,可有效分离Cu、Fe、Zn。介绍了方法的基本原理、化学分离过程及混合标准溶液与地质标样的分离结果。结果表明,Cu、Fe、Zn回收率均接近100%,标准溶液在离子交换分离前后同位素组成一致,可以满足多接收器等离子体质谱对Cu、Fe、Zn同位素高精度分析的要求。
