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稀土超强酸SO^4^(2-)/TiO_2-Nd_2O_3催化合成环己烯 被引量:3
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作者 方智利 聂启祥 郑龙珍 《化学研究与应用》 CAS CSCD 北大核心 2007年第9期1028-1032,共5页
Nanosized rare earth solid superacid SO42/TiO2-Nd2O3 was prepared and was used as a catalyst for cyclohexand dehydration to form cyclohexene.The influence of various preparation parameters such as the concentration of... Nanosized rare earth solid superacid SO42/TiO2-Nd2O3 was prepared and was used as a catalyst for cyclohexand dehydration to form cyclohexene.The influence of various preparation parameters such as the concentration of Nd3+,the concentration of H2SO4 and the calcination temperature on the catalytic activity was studied.It indicates that SO42-/TiO2-Nd2O3 has fairly high catalytic activity on the dehydration of cyclohexand and the yield of cyclohexene can reach 79.73%.The SO42-/TiO2-Nd2O3 catalytic mechanism for cyclohexand dehydration and the Nd3+ effect on the catalytic activity was also disccused. 展开更多
关键词 ^稀土固体超强so4^2-/tio2-nd2o3 环己烯 环己醇 合成
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