The presence of sulfonamide antibiotics in aquatic environments has received increasing attention in recent years.Sulfadiazine(SD),a widely used heterocyclic sulfonamide pharmaceutical,has entered into the receiving w...The presence of sulfonamide antibiotics in aquatic environments has received increasing attention in recent years.Sulfadiazine(SD),a widely used heterocyclic sulfonamide pharmaceutical,has entered into the receiving water body.In this paper,gamma rays are used to irradiate samples of sulfadiazine antibiotics-containing wastewater.The results demonstrate that SD can be effectively degraded by irradiation,but the mineralization degree of SD(in terms of TOC) is not as efficient as the SD degradation.The addition of Fe^(2+) can significantly enhance the SD degradation and mineralization through the generation of hydroxyl radical by catalytic decomposition of H_2O_2 from water radiolysis.Ion chromatography analysis indicates that sulfate ions(SO_4^(2-)) and formate(HCOO^-) are the main intermediate products.Gamma irradiation is a promising technology for removing low-concentration antibiotics from water and wastewater.展开更多
文中简述了天然水流体中的短链羧酸产出状况。短链羧酸地球化学的研究目前集中于沉积盆地和表生环境。根据C H O体系中某些C H O化合物的化学关系和热力学分析 ,推测深部水热流体中有可能存在短链羧酸。研究高温热液矿床矿物流体包裹体...文中简述了天然水流体中的短链羧酸产出状况。短链羧酸地球化学的研究目前集中于沉积盆地和表生环境。根据C H O体系中某些C H O化合物的化学关系和热力学分析 ,推测深部水热流体中有可能存在短链羧酸。研究高温热液矿床矿物流体包裹体的水溶有机组分可能是检验这一推测的突破口。某些石英脉型热液矿床的矿物流体包裹体压碎浸取和离子色谱分析确定 ,成矿流体中存在少量短链羧酸 ,而且甲酸是优势物种。文章讨论了矿物包裹体浸取实验结果需要进一步探讨的问题 ,认为研究水热成矿流体短链羧酸地球化学具有重要的理论意义。展开更多
基金supported by the National Natural Science Foundation of China(No.51338005)
文摘The presence of sulfonamide antibiotics in aquatic environments has received increasing attention in recent years.Sulfadiazine(SD),a widely used heterocyclic sulfonamide pharmaceutical,has entered into the receiving water body.In this paper,gamma rays are used to irradiate samples of sulfadiazine antibiotics-containing wastewater.The results demonstrate that SD can be effectively degraded by irradiation,but the mineralization degree of SD(in terms of TOC) is not as efficient as the SD degradation.The addition of Fe^(2+) can significantly enhance the SD degradation and mineralization through the generation of hydroxyl radical by catalytic decomposition of H_2O_2 from water radiolysis.Ion chromatography analysis indicates that sulfate ions(SO_4^(2-)) and formate(HCOO^-) are the main intermediate products.Gamma irradiation is a promising technology for removing low-concentration antibiotics from water and wastewater.
文摘文中简述了天然水流体中的短链羧酸产出状况。短链羧酸地球化学的研究目前集中于沉积盆地和表生环境。根据C H O体系中某些C H O化合物的化学关系和热力学分析 ,推测深部水热流体中有可能存在短链羧酸。研究高温热液矿床矿物流体包裹体的水溶有机组分可能是检验这一推测的突破口。某些石英脉型热液矿床的矿物流体包裹体压碎浸取和离子色谱分析确定 ,成矿流体中存在少量短链羧酸 ,而且甲酸是优势物种。文章讨论了矿物包裹体浸取实验结果需要进一步探讨的问题 ,认为研究水热成矿流体短链羧酸地球化学具有重要的理论意义。
