Mixed phase TiO2photocatalysts doped with C and Y were synthesized by a sol‐gel process.The effects of C and Y doping and annealing temperatures on the structural and optical properties,and photocatalytic activity we...Mixed phase TiO2photocatalysts doped with C and Y were synthesized by a sol‐gel process.The effects of C and Y doping and annealing temperatures on the structural and optical properties,and photocatalytic activity were investigated.We found that both C and Y doping can broaden the absorption spectrum of TiO2to the visible light region and inhibit recombination of photogenerated electron/hole pairs.The incorporation of Y into the TiO2lattice inhibited growth of crystalline grains,which increased the specific surface area and enhanced the photocatalytic activity.The photocatalytic performance of the samples was investigated in the photocatalytic degradation of methyl blue under visible light irradiation.The rate of methyl blue degradation over the(C,Y)‐co‐doped TiO2sample was much higher than those of undoped TiO2,C‐TiO2,and Y‐TiO2.Additionally,the apparent first‐order rate constant of the co‐doped sample was3.5times as large as that of undoped mix phase TiO2under the same experimental conditions.The enhanced photocatalytic activity can be attributed to the synergic effect of(C,Y)‐co‐doping and the formation of an appropriate crystalline structure.展开更多
传统的单移相控制下,当电压传输比不等于1时,双主动全桥(dual active bridge,DAB)直流变换器的部分开关管在轻载状态下会失去零电压开通的特性,从而造成开关损耗的增加。三重移相控制引入了内部移相角,比传统的移相控制多两个自由度,使...传统的单移相控制下,当电压传输比不等于1时,双主动全桥(dual active bridge,DAB)直流变换器的部分开关管在轻载状态下会失去零电压开通的特性,从而造成开关损耗的增加。三重移相控制引入了内部移相角,比传统的移相控制多两个自由度,使控制具有更大的灵活性。在三重移相控制的基础上,提出一种改善DAB特性的优化调制策略,使所有开关管在全功率范围内具有软开关的特性,并且能够减小轻载状态下变换器的电流应力和导通损耗,从而提高了变换器的效率。此外,提出的求解最优控制量的算法具有广泛的适用性,可以扩展至DAB变换器其他的最优化问题。实验结果验证了所提出调制策略的有效性。展开更多
以无工频牵引变压器电力牵引传动系统为应用背景,对其中的全桥隔离DC/DC变换器开展研究。首先,全面地分析和归纳全桥隔离DC/DC变换器系统中存在回流功率的现象,定义电源侧回流功率和负载侧回流功率,为同时限制变换器两端回流功率提出一...以无工频牵引变压器电力牵引传动系统为应用背景,对其中的全桥隔离DC/DC变换器开展研究。首先,全面地分析和归纳全桥隔离DC/DC变换器系统中存在回流功率的现象,定义电源侧回流功率和负载侧回流功率,为同时限制变换器两端回流功率提出一种三重相移控制方法。然后,在此基础上,给出最小回流功率控制算法。同时,为了减小变换器启动时的冲击电流,给出一种全桥隔离DC/DC变换器软启动控制方法。最后,研制了1.5 k W小功率实验平台并进行实验验证,实验结果表明,该软启动方法可有效地减小变换器启动时的电流冲击,所提出的三重相移控制方法相对于传统相移控制方法和双重相移控制方法显著提高了系统效率。展开更多
基金supported by the National High Technology Research and Development Program of China(863 Program,2015AA034601)the Natural Science Foundation of Yunnan Province(2016FB084)+1 种基金the Scientific Research Foundation of the Department of Education of Yunnan Province(2015Z003)the Open Fund of Yunnan Key Laboratory for Micro/nano Materials&Technology(ZZ2016006)~~
文摘Mixed phase TiO2photocatalysts doped with C and Y were synthesized by a sol‐gel process.The effects of C and Y doping and annealing temperatures on the structural and optical properties,and photocatalytic activity were investigated.We found that both C and Y doping can broaden the absorption spectrum of TiO2to the visible light region and inhibit recombination of photogenerated electron/hole pairs.The incorporation of Y into the TiO2lattice inhibited growth of crystalline grains,which increased the specific surface area and enhanced the photocatalytic activity.The photocatalytic performance of the samples was investigated in the photocatalytic degradation of methyl blue under visible light irradiation.The rate of methyl blue degradation over the(C,Y)‐co‐doped TiO2sample was much higher than those of undoped TiO2,C‐TiO2,and Y‐TiO2.Additionally,the apparent first‐order rate constant of the co‐doped sample was3.5times as large as that of undoped mix phase TiO2under the same experimental conditions.The enhanced photocatalytic activity can be attributed to the synergic effect of(C,Y)‐co‐doping and the formation of an appropriate crystalline structure.
文摘传统的单移相控制下,当电压传输比不等于1时,双主动全桥(dual active bridge,DAB)直流变换器的部分开关管在轻载状态下会失去零电压开通的特性,从而造成开关损耗的增加。三重移相控制引入了内部移相角,比传统的移相控制多两个自由度,使控制具有更大的灵活性。在三重移相控制的基础上,提出一种改善DAB特性的优化调制策略,使所有开关管在全功率范围内具有软开关的特性,并且能够减小轻载状态下变换器的电流应力和导通损耗,从而提高了变换器的效率。此外,提出的求解最优控制量的算法具有广泛的适用性,可以扩展至DAB变换器其他的最优化问题。实验结果验证了所提出调制策略的有效性。
文摘以无工频牵引变压器电力牵引传动系统为应用背景,对其中的全桥隔离DC/DC变换器开展研究。首先,全面地分析和归纳全桥隔离DC/DC变换器系统中存在回流功率的现象,定义电源侧回流功率和负载侧回流功率,为同时限制变换器两端回流功率提出一种三重相移控制方法。然后,在此基础上,给出最小回流功率控制算法。同时,为了减小变换器启动时的冲击电流,给出一种全桥隔离DC/DC变换器软启动控制方法。最后,研制了1.5 k W小功率实验平台并进行实验验证,实验结果表明,该软启动方法可有效地减小变换器启动时的电流冲击,所提出的三重相移控制方法相对于传统相移控制方法和双重相移控制方法显著提高了系统效率。
