Cu Ni Si合金在时效过程中的导电率变化反映了合金中时效析出相的相变过程,因而通过测量时效过程中导电率的变化就可反映该合金时效析出转变的相变动力学方程,在此基础上,还可进一步求得时效时间和温度两个参数下的二元导电率方程。试...Cu Ni Si合金在时效过程中的导电率变化反映了合金中时效析出相的相变过程,因而通过测量时效过程中导电率的变化就可反映该合金时效析出转变的相变动力学方程,在此基础上,还可进一步求得时效时间和温度两个参数下的二元导电率方程。试验结果表明由该导电率方程所得的计算值能较好地与试验值相符,因此可以较准确的预测出某一工艺参数下可能达到的性能,以求达到减少试验次数和成本的目的,从而为该合金的生产工艺的制定提供参考依据。展开更多
The precipitation behaviors of the Cu-Ni-Si alloys during aging were studied by analyzing the variations of electric conductivity.The Avrami-equation of phase transformation kinetics and the Avrami-equation of electri...The precipitation behaviors of the Cu-Ni-Si alloys during aging were studied by analyzing the variations of electric conductivity.The Avrami-equation of phase transformation kinetics and the Avrami-equation of electric conductivity during aging were established for Cu-Ni-Si alloys,on the basis of linear relationship between the electric conductivity and the volume fraction of precipitates,and the calculation results coincide well with the experiment ones.The transformation kinetics curves were established to characterize the aging process.The characteristics of precipitates in the supersaturated solid solution alloy aged at 723 K were established,and the results show that the precipitates areβ-Ni3Si andδ-Ni2Si phases.展开更多
文摘Cu Ni Si合金在时效过程中的导电率变化反映了合金中时效析出相的相变过程,因而通过测量时效过程中导电率的变化就可反映该合金时效析出转变的相变动力学方程,在此基础上,还可进一步求得时效时间和温度两个参数下的二元导电率方程。试验结果表明由该导电率方程所得的计算值能较好地与试验值相符,因此可以较准确的预测出某一工艺参数下可能达到的性能,以求达到减少试验次数和成本的目的,从而为该合金的生产工艺的制定提供参考依据。
基金Project(2006AA03Z517) supported by the National High-tech Research and Development Program of ChinaProject(08MX15) supported by the Mittal Programs of Central South University, China
文摘The precipitation behaviors of the Cu-Ni-Si alloys during aging were studied by analyzing the variations of electric conductivity.The Avrami-equation of phase transformation kinetics and the Avrami-equation of electric conductivity during aging were established for Cu-Ni-Si alloys,on the basis of linear relationship between the electric conductivity and the volume fraction of precipitates,and the calculation results coincide well with the experiment ones.The transformation kinetics curves were established to characterize the aging process.The characteristics of precipitates in the supersaturated solid solution alloy aged at 723 K were established,and the results show that the precipitates areβ-Ni3Si andδ-Ni2Si phases.