采用溶胶-凝胶法制备TiO2/Ti膜电极,设计了三维电极电助光催化降解反应装置,并将其用于降解水中的双酚A。结果表明,三维电场协同TiO2光催化氧化技术对双酚A的降解效果较好,反应120 m in后降解率可达100%;在本试验条件下,最佳阳极偏电压...采用溶胶-凝胶法制备TiO2/Ti膜电极,设计了三维电极电助光催化降解反应装置,并将其用于降解水中的双酚A。结果表明,三维电场协同TiO2光催化氧化技术对双酚A的降解效果较好,反应120 m in后降解率可达100%;在本试验条件下,最佳阳极偏电压为8 V;当溶液的电导率较小时,增大电导率有利于对双酚A的降解,但当电导率较大时,对双酚A的降解率反而随电导率的增大而逐渐减小;电助光催化降解双酚A的反应符合表观一级动力学方程。展开更多
The electrochemically assisted photocatalytic degradation of direct sky blue aqueous solution with three dimensional electrodes was studied. The degradation rates as high as 99%, with a high decolorization ratios of 9...The electrochemically assisted photocatalytic degradation of direct sky blue aqueous solution with three dimensional electrodes was studied. The degradation rates as high as 99%, with a high decolorization ratios of 96 8% and TOC concentration reduction of about 80 5% were observed during a period of 30 min in presence of both photocatalyst and filler electrodes. The kinetics of electrochemically assisted photocatalytic degradation of direct sky blue was also investigated.展开更多
文摘采用溶胶-凝胶法制备TiO2/Ti膜电极,设计了三维电极电助光催化降解反应装置,并将其用于降解水中的双酚A。结果表明,三维电场协同TiO2光催化氧化技术对双酚A的降解效果较好,反应120 m in后降解率可达100%;在本试验条件下,最佳阳极偏电压为8 V;当溶液的电导率较小时,增大电导率有利于对双酚A的降解,但当电导率较大时,对双酚A的降解率反而随电导率的增大而逐渐减小;电助光催化降解双酚A的反应符合表观一级动力学方程。
文摘The electrochemically assisted photocatalytic degradation of direct sky blue aqueous solution with three dimensional electrodes was studied. The degradation rates as high as 99%, with a high decolorization ratios of 96 8% and TOC concentration reduction of about 80 5% were observed during a period of 30 min in presence of both photocatalyst and filler electrodes. The kinetics of electrochemically assisted photocatalytic degradation of direct sky blue was also investigated.
