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吸附性碳材料对水中痕量邻苯二甲酸二甲酯的吸附性能及特征研究 被引量:3
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作者 杜尔登 崔旭峰 +1 位作者 宋澄杰 李香青 《给水排水》 CSCD 北大核心 2013年第7期125-130,共6页
针对环境水体中内分泌干扰物的污染问题,选择邻苯二甲酸二甲酯(DMP)作为典型污染物,以颗粒活性炭、酸化活性炭、粉末活性炭和碳纳米管作为吸附剂,考察吸附剂对DMP的吸附性能和吸附特性。研究结果表明:吸附性碳材料对DMP具有良好的吸附性... 针对环境水体中内分泌干扰物的污染问题,选择邻苯二甲酸二甲酯(DMP)作为典型污染物,以颗粒活性炭、酸化活性炭、粉末活性炭和碳纳米管作为吸附剂,考察吸附剂对DMP的吸附性能和吸附特性。研究结果表明:吸附性碳材料对DMP具有良好的吸附性能,四种碳材料的吸附容量大小为:粉状活性炭>颗粒活性炭>酸化活性炭>碳纳米管。粉末活性炭的单层最大吸附容量为678.3 mg/L。Freundlich和Temkin吸附等温线方程能够较好地拟合吸附数据,Langmuir吸附等温线方程对粉末状吸附剂(粉末活性炭、碳纳米管)吸附拟合效果较好。粉末活性炭、颗粒活性炭、酸化活性炭的吸附过程符合一级吸附动力学模型,而碳纳米管吸附过程符合二级吸附动力学模型。 展开更多
关键词 邻苯二甲酸二甲酯 活性炭 纳米管 吸附等温线 吸附动力学
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Date palm kernel-based GAC and its dynamic modeling of residual chlorine breakthrough curve in multimedia filter 被引量:1
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作者 Rusul Naseer Mohammed 吕锡武 Saad Abualhail 《Journal of Southeast University(English Edition)》 EI CAS 2012年第2期169-174,共6页
First, the date palm kernel is used to produce granular activated carbon (GAC) by a physiochemical activation process. The process involves six steps: washing, drying, crushing, sieving, carbonization, and activati... First, the date palm kernel is used to produce granular activated carbon (GAC) by a physiochemical activation process. The process involves six steps: washing, drying, crushing, sieving, carbonization, and activation. Secondly, the ability of the produced GAC to remove pollutants is examined through batch experiments of residual chlorine adsorption whereas the equilibrium isotherm experimental data are tested for the Langmuir and Freundlich isotherms equations. Thirdly, the experimental and theoretical study of dynamic adsorption process and the effect of major operating parameters on dynamic adsorption are investigated. The results show that the Langmuir isotherm gives the best fitting to experimental data, which indicates that the residual chlorine adsorption can be characterized by mono layer adsorption behavior. The produced GAC has a great potential as an adsorbent for residual chlorine in water systems and it can compete favorably with the conventional adsorbents. The Thomas extended model with combined mass transfer resistances is used for verifying the experimental results and the results show that the proposed model coincides well with the experimental data of the dynamic adsorption process. 展开更多
关键词 residual chlorine adsorption granuler activated carbon (GAC) model isotherm multimedia filter date palm kernel
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