A new fluorescent reagent, salicylaldehyde-5-bromo-salicyloyhydrazone (SABSH ), was synthesized and its ionization constants were established spectropho-tometrically. The fluorescent reaction of this reagent with scan...A new fluorescent reagent, salicylaldehyde-5-bromo-salicyloyhydrazone (SABSH ), was synthesized and its ionization constants were established spectropho-tometrically. The fluorescent reaction of this reagent with scandium was studied in detail.Based on this chelation reaction, a spectrofluorimetric method was developed for the determi-nation of scandium in a water-ethanol(1:1, V/V) medium at pH 4. 8. Under these condi-tions, the Sc-SABSH complex has excitation and emission maxima at 392 and 466 nm, re-spectively. The linear range of the method is from 0.0 to 1.0μg/10 mL, the relative stan-dard deviation of the method is 0.95% and the detection limit is o. 15 ng/mL of scandium when a standard additions method is used in the assay. The molar ratlo of scandium to reagent is 1: 1. Interferences of forty other ions were studied. The method has been suc-cessfully applied to the determination of trace scandium in geologic samples-展开更多
In ethanol, the copper(II) complex with the 2′-(2-thienylidene)-h ydroxybenzoylhydrazide, Cu(C12H10N2O2S)2, was synthesized, and it′s structure was characterized by IR, UV and elemental analysis. The single crystal ...In ethanol, the copper(II) complex with the 2′-(2-thienylidene)-h ydroxybenzoylhydrazide, Cu(C12H10N2O2S)2, was synthesized, and it′s structure was characterized by IR, UV and elemental analysis. The single crystal structure has been determined by X-ray diffraction analysis. The crystal belongs to monoclinic system, space group C2/c with cell constants, a=2.273 6(4) nm, b=0.592 12(9) nm, c=1.828 1(3) nm, β=109.735(5)°, V=2.316 4(7) nm3, Z=4, μ=1.164 mm-1, Dc=1.595 g·cm-3, F(000)=1 140, R=0.048 6, wR=0.101 6. In the compound copper(II) atom is four-coordinated with two nitrogen atoms from amide and two oxygen atoms from keto group. Their biological activities have been measused. The results show that the anti-bacterial activity of the coordination compound is much better that of the ligand. CCDC: 272938.展开更多
文摘A new fluorescent reagent, salicylaldehyde-5-bromo-salicyloyhydrazone (SABSH ), was synthesized and its ionization constants were established spectropho-tometrically. The fluorescent reaction of this reagent with scandium was studied in detail.Based on this chelation reaction, a spectrofluorimetric method was developed for the determi-nation of scandium in a water-ethanol(1:1, V/V) medium at pH 4. 8. Under these condi-tions, the Sc-SABSH complex has excitation and emission maxima at 392 and 466 nm, re-spectively. The linear range of the method is from 0.0 to 1.0μg/10 mL, the relative stan-dard deviation of the method is 0.95% and the detection limit is o. 15 ng/mL of scandium when a standard additions method is used in the assay. The molar ratlo of scandium to reagent is 1: 1. Interferences of forty other ions were studied. The method has been suc-cessfully applied to the determination of trace scandium in geologic samples-
文摘In ethanol, the copper(II) complex with the 2′-(2-thienylidene)-h ydroxybenzoylhydrazide, Cu(C12H10N2O2S)2, was synthesized, and it′s structure was characterized by IR, UV and elemental analysis. The single crystal structure has been determined by X-ray diffraction analysis. The crystal belongs to monoclinic system, space group C2/c with cell constants, a=2.273 6(4) nm, b=0.592 12(9) nm, c=1.828 1(3) nm, β=109.735(5)°, V=2.316 4(7) nm3, Z=4, μ=1.164 mm-1, Dc=1.595 g·cm-3, F(000)=1 140, R=0.048 6, wR=0.101 6. In the compound copper(II) atom is four-coordinated with two nitrogen atoms from amide and two oxygen atoms from keto group. Their biological activities have been measused. The results show that the anti-bacterial activity of the coordination compound is much better that of the ligand. CCDC: 272938.
