Recent progress in the research of radical anion ligands and their complexes with metals were summarized in this review.Radical anions were sorted into several types including iminosemiquinonate and iminoquinonate rad...Recent progress in the research of radical anion ligands and their complexes with metals were summarized in this review.Radical anions were sorted into several types including iminosemiquinonate and iminoquinonate radical,nitroxide radical,heterocycle radical etc.Structural characteristics and properties of the corresponding complexes were introduced.The complexes exhibited novel properties and possibility for applications in organic magnetic materials and transition metal catalysis.展开更多
基金supported by the National Natural Science Foundation of China(20972025,U1362110)PetroChina Innovation Foundation(2013D-5006-0503)+2 种基金Scientific Research Foundation for the Returned Overseas Chinese Scholars,Program for New Century Excellent Talents in University(NCET-07-0142)Heilongjiang Province(41417837-8-08016)Department of Education of Heilongjiang Province(1154H14,1154G53)
文摘Recent progress in the research of radical anion ligands and their complexes with metals were summarized in this review.Radical anions were sorted into several types including iminosemiquinonate and iminoquinonate radical,nitroxide radical,heterocycle radical etc.Structural characteristics and properties of the corresponding complexes were introduced.The complexes exhibited novel properties and possibility for applications in organic magnetic materials and transition metal catalysis.
