Three new complexes, [Zn(dtb)(4,4'-bipy)]·5H2O (1), [Zn(dtb)(bpp)]·H2O (2) and [Zn(dtb)(phen)2]·CH3CH2OH·H2O (3) (dtb = 5,5'-dithiobis(2-nitrobenzoic acid), 4,4'-bipy = 4,4'-bipyrid...Three new complexes, [Zn(dtb)(4,4'-bipy)]·5H2O (1), [Zn(dtb)(bpp)]·H2O (2) and [Zn(dtb)(phen)2]·CH3CH2OH·H2O (3) (dtb = 5,5'-dithiobis(2-nitrobenzoic acid), 4,4'-bipy = 4,4'-bipyridine, bpp = 1,3-bi(4-pyridyl) propane, phen = 1,10-phenanthroline), have been constructed by dtb ligand and zinc salt in the presence of different assistant N-containing ligands under hydrothermal conditions. The structures of the complexes were established by single-crystal X-ray diffraction analysis. Although compounds 1 and 2 are both 2D networks, the cavities’ forms and pitch of helix are different. The structure of compound 3 shows a 1D helical chain, and is extended by the supermolecule interactions into a 2D framework. These neutral polymeric complexes exhibit structural and dimensional diversity due to the different coordination modes of the flexible dtb ligand and the effect of assistant ligands.展开更多
基金Supported by the National Natural Science Foundation of China (Grant No. 20771090)Teaching and Research Award Program for Outstanding Young Teachers in Higher Education InstitutesSpecialized Research Fund for the Doctoral Program of Higher Education (Grant No. 20050697005)
文摘Three new complexes, [Zn(dtb)(4,4'-bipy)]·5H2O (1), [Zn(dtb)(bpp)]·H2O (2) and [Zn(dtb)(phen)2]·CH3CH2OH·H2O (3) (dtb = 5,5'-dithiobis(2-nitrobenzoic acid), 4,4'-bipy = 4,4'-bipyridine, bpp = 1,3-bi(4-pyridyl) propane, phen = 1,10-phenanthroline), have been constructed by dtb ligand and zinc salt in the presence of different assistant N-containing ligands under hydrothermal conditions. The structures of the complexes were established by single-crystal X-ray diffraction analysis. Although compounds 1 and 2 are both 2D networks, the cavities’ forms and pitch of helix are different. The structure of compound 3 shows a 1D helical chain, and is extended by the supermolecule interactions into a 2D framework. These neutral polymeric complexes exhibit structural and dimensional diversity due to the different coordination modes of the flexible dtb ligand and the effect of assistant ligands.
