Using La2(SO4)3 and the active carbon powder as reactants, La2O2S∶Mn2+ red phosphor was synthesized by microwave radiation method. The phosphor was characterized by means of X-ray diffraction (XRD), scanning electron...Using La2(SO4)3 and the active carbon powder as reactants, La2O2S∶Mn2+ red phosphor was synthesized by microwave radiation method. The phosphor was characterized by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), laser-diffraction size analyzer and fluorospectrophotometer. The XRD analysis showed that the phosphor was pure phase La2O2S. The phosphor of La2O2S∶Mn2+ showed hexagonal crystal structure with diverse shapes, such as spherical and rod, with average particle size of 10.22 μm. The emission and excitation spectra of the phosphor were determined by fluorospectrophotometer and the results showed that the excitation spectrum of the phosphor under 600 nm emission wavelength was excitation bands between 250 nm and 350 nm with a peak value of 303 nm. Then ,when exicited under UV 303 nm, the phosphor showed broad band emission of 550~700 nm with a peak at 607 nm. In addition, the optimal effects were obtained for the phosphor preparation when the concentration of the activator Mn2+ was xMn=0.01, the ratio of C and O (nC / nO) in the reactants was 0.6∶1, and the time of reaction was about 1 h. La2O2S∶Mn2+ has strong absorption of UV spectrum and can emit bright red light.展开更多
In order to improve the efficiency of heating and the uniformity of temperature distribution in recycling asphalt mixtures, a pyramidal radiation heater is designed. The principles of designing horn surface size and a...In order to improve the efficiency of heating and the uniformity of temperature distribution in recycling asphalt mixtures, a pyramidal radiation heater is designed. The principles of designing horn surface size and antenna length are established according to the law of energy conservation and microwave antenna radiation theory. Modeling and simulation are carried out using IE3D software. The simulation results demonstrate that, with a fixed horn surface size, the shortened electric antenna length is the main factor leading to the improved heating uniformity. On the other hand, with a fixed antenna length and diminished surface size, the standing wave ratio decreases with the improved radiation efficiency. Furthermore, the efficiency of radiation drops with increased distance between the horn surface and the asphalt pavement. Microwave heating experiments are carried out using this type of heater. The temperature distribution of asphalt samples is obtained by the grid temperature measurement method, and Matlab simulation is performed. The experimental results are in good agreement with the simulation.展开更多
文摘Using La2(SO4)3 and the active carbon powder as reactants, La2O2S∶Mn2+ red phosphor was synthesized by microwave radiation method. The phosphor was characterized by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), laser-diffraction size analyzer and fluorospectrophotometer. The XRD analysis showed that the phosphor was pure phase La2O2S. The phosphor of La2O2S∶Mn2+ showed hexagonal crystal structure with diverse shapes, such as spherical and rod, with average particle size of 10.22 μm. The emission and excitation spectra of the phosphor were determined by fluorospectrophotometer and the results showed that the excitation spectrum of the phosphor under 600 nm emission wavelength was excitation bands between 250 nm and 350 nm with a peak value of 303 nm. Then ,when exicited under UV 303 nm, the phosphor showed broad band emission of 550~700 nm with a peak at 607 nm. In addition, the optimal effects were obtained for the phosphor preparation when the concentration of the activator Mn2+ was xMn=0.01, the ratio of C and O (nC / nO) in the reactants was 0.6∶1, and the time of reaction was about 1 h. La2O2S∶Mn2+ has strong absorption of UV spectrum and can emit bright red light.
基金The Key Project of Science and Technology of Ministry of Education(No.03081,105085)the SciTech Achievements Transformation Program of Jiangsu Province(No.BA2006068)
文摘In order to improve the efficiency of heating and the uniformity of temperature distribution in recycling asphalt mixtures, a pyramidal radiation heater is designed. The principles of designing horn surface size and antenna length are established according to the law of energy conservation and microwave antenna radiation theory. Modeling and simulation are carried out using IE3D software. The simulation results demonstrate that, with a fixed horn surface size, the shortened electric antenna length is the main factor leading to the improved heating uniformity. On the other hand, with a fixed antenna length and diminished surface size, the standing wave ratio decreases with the improved radiation efficiency. Furthermore, the efficiency of radiation drops with increased distance between the horn surface and the asphalt pavement. Microwave heating experiments are carried out using this type of heater. The temperature distribution of asphalt samples is obtained by the grid temperature measurement method, and Matlab simulation is performed. The experimental results are in good agreement with the simulation.
