The equilibrium of the solid-liquid interface in pressurized solidification process of binary alloys was studied using the Gibbs theory, and the stability of the solid-liquid interface was discussed based on the consi...The equilibrium of the solid-liquid interface in pressurized solidification process of binary alloys was studied using the Gibbs theory, and the stability of the solid-liquid interface was discussed based on the consideration of the effects of pressure on the diffusion coefficient, the interface growth rate and tile equilibrium liquid composition. A mathematical description of the equi- librium status, the relationship of temperature, pressure, composition and interfacial tension was obtained, and further, a mathematical representation of the curvature radius of solid-liquid interface was developed, which facilitates a thorough understanding of the controlled variables of the interfacial stability.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.50875143 and 50675113)the support of the Scientific Research Foundation for the Returned Overseas Chinese Scholars,Ministry of Education of Chinathe support of State Key Laboratory of Materials Processing and Die & Mould Technology,Huazhong University of Science and Technology
文摘The equilibrium of the solid-liquid interface in pressurized solidification process of binary alloys was studied using the Gibbs theory, and the stability of the solid-liquid interface was discussed based on the consideration of the effects of pressure on the diffusion coefficient, the interface growth rate and tile equilibrium liquid composition. A mathematical description of the equi- librium status, the relationship of temperature, pressure, composition and interfacial tension was obtained, and further, a mathematical representation of the curvature radius of solid-liquid interface was developed, which facilitates a thorough understanding of the controlled variables of the interfacial stability.