铝合金中通常含有一些时效析出相及杂质相等第二相粒子,这些第二相粒子对铝合金局部腐蚀行为产生重大影响。概括了析出相θ(Al_2Cu)、η(MgZn_2)、β(Mg_3Al_2)及含 Fe 杂质相 FeAl_3等在铝合金局部腐蚀中的作用机制,重点介绍了 S 相(Al...铝合金中通常含有一些时效析出相及杂质相等第二相粒子,这些第二相粒子对铝合金局部腐蚀行为产生重大影响。概括了析出相θ(Al_2Cu)、η(MgZn_2)、β(Mg_3Al_2)及含 Fe 杂质相 FeAl_3等在铝合金局部腐蚀中的作用机制,重点介绍了 S 相(Al_2CuMg)和 T1相(Al_2CuLi)对铝合金局部腐蚀作用机制的不同观点。展开更多
The corrosion behaviours of four kinds of rolled magnesium alloys of AZ31, AZ91, AM60 and ZK60 were studied in 1 mol/L sodium chloride solution. The results of EIS and potentiodynamic polarization show that the corros...The corrosion behaviours of four kinds of rolled magnesium alloys of AZ31, AZ91, AM60 and ZK60 were studied in 1 mol/L sodium chloride solution. The results of EIS and potentiodynamic polarization show that the corrosion resistance of the four materials is ranked as ZK60>AM60>AZ31>AZ91. The corrosion processes of the four magnesium alloys were also analyzed by SEM and energy dispersive spectroscopy(EDS). The results show that the corrosion patterns of the four alloys are localized corrosion and the galvanic couples formed by the second phase particles and the matrix are the main source of the localized corrosion of magnesium alloys. The corrosion resistance of the different magnesium alloys has direct relationship with the concentration of alloying elements and microstructure of magnesium alloys. The ratio of the β phase in AZ91 is higher than that in AZ31 and the β phase can form micro-galvanic cell with the alloy matrix, as a result, the corrosion resistance of AZ31 will be higher than AZ91. The manganese element in AM60 magnesium alloy can form the second phase particle of AlMnFe, which can reduce the Fe content in magnesium alloy matrix, purifying the microstructure of alloy, as a result, the corrosion resistance of AM60 is improved. However, due to the more noble galvanic couples of AlMnFe and matrix, the microscopic corrosion morphology of AM60 is more localized. The zirconium element in ZK60 magnesium alloy can refine grain, form stable compounds with Fe and Si, and purify the composition of alloy, which results in the good corrosion resistance of ZK60 magnesium alloy.展开更多
文摘铝合金中通常含有一些时效析出相及杂质相等第二相粒子,这些第二相粒子对铝合金局部腐蚀行为产生重大影响。概括了析出相θ(Al_2Cu)、η(MgZn_2)、β(Mg_3Al_2)及含 Fe 杂质相 FeAl_3等在铝合金局部腐蚀中的作用机制,重点介绍了 S 相(Al_2CuMg)和 T1相(Al_2CuLi)对铝合金局部腐蚀作用机制的不同观点。
基金Project(50471043) supported by the National Natural Science Foundation of China
文摘The corrosion behaviours of four kinds of rolled magnesium alloys of AZ31, AZ91, AM60 and ZK60 were studied in 1 mol/L sodium chloride solution. The results of EIS and potentiodynamic polarization show that the corrosion resistance of the four materials is ranked as ZK60>AM60>AZ31>AZ91. The corrosion processes of the four magnesium alloys were also analyzed by SEM and energy dispersive spectroscopy(EDS). The results show that the corrosion patterns of the four alloys are localized corrosion and the galvanic couples formed by the second phase particles and the matrix are the main source of the localized corrosion of magnesium alloys. The corrosion resistance of the different magnesium alloys has direct relationship with the concentration of alloying elements and microstructure of magnesium alloys. The ratio of the β phase in AZ91 is higher than that in AZ31 and the β phase can form micro-galvanic cell with the alloy matrix, as a result, the corrosion resistance of AZ31 will be higher than AZ91. The manganese element in AM60 magnesium alloy can form the second phase particle of AlMnFe, which can reduce the Fe content in magnesium alloy matrix, purifying the microstructure of alloy, as a result, the corrosion resistance of AM60 is improved. However, due to the more noble galvanic couples of AlMnFe and matrix, the microscopic corrosion morphology of AM60 is more localized. The zirconium element in ZK60 magnesium alloy can refine grain, form stable compounds with Fe and Si, and purify the composition of alloy, which results in the good corrosion resistance of ZK60 magnesium alloy.
