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Effect of Fe/SiO2 and CaO/SiO2 mass ratios on metal recovery rate and metal content in slag in oxygen-enriched direct smelting of jamesonite concentrate 被引量:5
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作者 Zhong-tang ZHANG Xi DAI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2020年第2期501-508,共8页
The oxygen-enriched direct smelting of jamesonite concentrate was carried out at 1250℃by changing the slag composition.The effects of Fe/SiO2 and Ca O/SiO2 mass ratios on the metal recovery rate as well as metal cont... The oxygen-enriched direct smelting of jamesonite concentrate was carried out at 1250℃by changing the slag composition.The effects of Fe/SiO2 and Ca O/SiO2 mass ratios on the metal recovery rate as well as metal content in slag were investigated.Experimental results indicated that the metal(Pb+Sb)recovery rate was up to 88.30%,and metal(Pb+Sb)content in slag was below 1 wt.%under the condition of slag composition of 21-22 wt.%Fe,19-20 wt.%SiO2 and 17-18 wt.%Ca O with Fe/SiO2 mass ratio of 1.1:1 and Ca O/SiO2 mass ratio of 0.9:1.The microanalysis of the alloy and slag demonstrated that the main phases in the alloy contained metallic Pb,metallic Sb and a small amount of Cu2 Sb and Fe Sb2 intermetallic compounds.The slag was mainly composed of kirschsteinite and fayalite.Zinc in the raw material was mainly oxidized into the slag phase in the form of zinc oxide. 展开更多
关键词 jamesonite concentrate metallurgical process intensification slag type PYROMETALLURGY oxygen-enriched direct smelting
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脆硫铅锑精矿富氧直接熔炼渣型理论研究 被引量:2
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作者 张忠堂 戴曦 《中国有色金属学报》 EI CAS CSCD 北大核心 2020年第6期1427-1436,共10页
对脆硫铅锑精矿富氧直接熔炼渣型理论进行研究。根据富氧直接熔炼过程炉渣组成特性,选取FeO-SiO2-CaO-ZnO渣系为研究对象。采用热力学软件Factsage计算并绘制FeO-SiO2-CaO-ZnO渣系相图,考察CaO与SiO2质量比、Fe与SiO2质量比、ZnO含量及... 对脆硫铅锑精矿富氧直接熔炼渣型理论进行研究。根据富氧直接熔炼过程炉渣组成特性,选取FeO-SiO2-CaO-ZnO渣系为研究对象。采用热力学软件Factsage计算并绘制FeO-SiO2-CaO-ZnO渣系相图,考察CaO与SiO2质量比、Fe与SiO2质量比、ZnO含量及温度对该渣系熔化温度及黏度的作用规律,并在此理论基础上进行实验研究。理论研究表明,熔炼过程炉渣中Fe与SiO2质量比和CaO与SiO2质量比的增大均会提高炉渣的熔化温度。随着体系温度的升高,炉渣的黏度逐渐减小,1250℃时,炉渣的黏度均小于0.5 Pa·s。实验结果表明:熔炼过程产出合金品位为95.56%,合金直收率达到58.47%,渣中金属含量(Pb与Sb)小于1%(质量分数)。熔炼产物工艺矿物学研究发现,合金中主要物相为金属Pb、金属Sb以及少量Cu2Sb、FeSb2金属间化合物,炉渣主要由钙铁橄榄石、铁橄榄石组成,原料中锌主要以氧化锌形式进入渣相。 展开更多
关键词 脆硫铅锑精矿 直接熔炼 渣型 金属直收率
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