The past 5 years have witnessed the rapid development of organic solar cells based on nonfullerene acceptors(NFAs)[1-26].The state-of-the-art NFA-based single-junction and tandem solar cells afforded 18.22%(certified ...The past 5 years have witnessed the rapid development of organic solar cells based on nonfullerene acceptors(NFAs)[1-26].The state-of-the-art NFA-based single-junction and tandem solar cells afforded 18.22%(certified 17.6%)and 17.36%(certified 17.29%)power conversion efficiencies(PCEs),respectively[27,28].Wide-bandgap(WBG)polymer donors are ideal partners for NFAs.They present complementary absorption with that of low-bandgap NFAs and deep the highest occupied molecular orbital(HOMO)levels.Therefore,solar cells based on a WBG polymer and a NFA can generate high short-circuit current density(Jsc)and open-circuit voltage(Voc)[29].Meanwhile,some WBG polymers show high crystallinity and mobility,gifting the solar cells high fill factors(FF)[30].Recently,our group first reported efficient WBG D-A copolymer donors based on fused-ring aromatic lactone(FRAL)acceptor units.展开更多
基金supported by the Ministry of Science and Technology(No.2014CB643502)the Naional Natrual Science Foundation of China(Nos.51373078,51422304,91433101)the Natrual Science Foundation of Tianjin City(No.17JCZDJC31100)~~
基金the National Key Research and Development Program of China(2017YFA0206600)the National Natural Science Foundation of China(51773045,21772030,51922032 and 21961160720)the Youth Association for Promoting Innovation(CAS)for financial support。
文摘The past 5 years have witnessed the rapid development of organic solar cells based on nonfullerene acceptors(NFAs)[1-26].The state-of-the-art NFA-based single-junction and tandem solar cells afforded 18.22%(certified 17.6%)and 17.36%(certified 17.29%)power conversion efficiencies(PCEs),respectively[27,28].Wide-bandgap(WBG)polymer donors are ideal partners for NFAs.They present complementary absorption with that of low-bandgap NFAs and deep the highest occupied molecular orbital(HOMO)levels.Therefore,solar cells based on a WBG polymer and a NFA can generate high short-circuit current density(Jsc)and open-circuit voltage(Voc)[29].Meanwhile,some WBG polymers show high crystallinity and mobility,gifting the solar cells high fill factors(FF)[30].Recently,our group first reported efficient WBG D-A copolymer donors based on fused-ring aromatic lactone(FRAL)acceptor units.
基金supported by the National Natural Science Foundation of China(21734008,61721005,21674093,51473142)the Zhejiang Province Science and Technology Plan,China(2018C01047)~~
