In this paper the authors present the REE concentrations and Sr and Nd isotopic compositions of fluorites from the Bailashui tin deposit of the Furong ore field,southern Hunan Province. The results showed that the tot...In this paper the authors present the REE concentrations and Sr and Nd isotopic compositions of fluorites from the Bailashui tin deposit of the Furong ore field,southern Hunan Province. The results showed that the total amount of REE in fluorites is usually low,ranging from 0.705 to 8.785 μg/g with the chondrite-normalized REE dis-tribution patterns similar to those of the Qitianling granites in the study area,characterized by LREE-enrichment patterns with pronounced negative Eu anomalies. The fluorites vary in Sr isotopic composition within the range of 0.7083-0.7091,the values are lower than those of the granites and higher than those of the host carbonate rocks in this area. The εNd(t) values of fluorites vary between -9.4 and +10.3,revealing that both the crust-and mantle-source materials were involved in the ore-forming hydrothermal fluids. Combined with previous studies on this ore deposit,the Bailashui tin deposit is temporally and spatially closely related with granitic magmatism in this area. The hydro-thermal fluorites are the product of fluid/rock interactions between granitic magmatic hydrothermal fluid and marine carbonate rocks. The REE and F in the ore-forming fluid were derived from the granites,whereas Sr in the ore-forming fluid came mainly from the granitic magmatic hydrothermal fluid and marine carbonate rocks,although variations in Sr isotopic composition cannot be explained by a simple mixture of these two end-members. Evidence demonstrated that the ore-forming fluids are of crustal-mantle mixing origin,but that the fluids were probably in-completely homogenized and this may be caused by inhomogeneous mixing of the fluids of different sources.展开更多
On 20 March, 2002, a super dust storm attacked Beijing, which was stronger than any dust storm ever recorded. The con-centration of total suspended particulates (TSP) reached 10.9 mg·m-3, 54 times as high as the ...On 20 March, 2002, a super dust storm attacked Beijing, which was stronger than any dust storm ever recorded. The con-centration of total suspended particulates (TSP) reached 10.9 mg·m-3, 54 times as high as the national air quality standard. The concentrations of major crustal elements, such as Ca, AI, Fe, Na, Mg and Ti, were 30-58 times higher than those in non-dust storm days. The concentrations of pollution elements, such as Zn, Cu, Pb, As, Cd and S, were also about several or even nearly ten times higher than those in normal days. The enrichment factors of Pb, As, Cd and S in PM2.5 were as high as 12.7, 29.6, 43.5,28.4, indicating that these pollutants came from the mixing of mineral aerosol with pollution aerosol emitted by pollution sources on the way of dust storm’s long-range transport. The overlap of invaded air mass from dust with pollution air mass from Beijing local area was another reason for the enhancement of pollutants. During dust storm, fine particles (PM2.5) accounted for 30% of TSP and pollutants in PM2.5 accounted for even as high as 45%-69% of TSP. The increase of pollutants after dust storm proved further that mineral aerosol, especially the fine particles from dust storm favored the transformation and accumulation of pollutants. It must be noted that Fe (II) was detected again in this dust storm, which provided new evidence for the mechanism of coupling and feedback between iron and sulfur in the atmosphere and the ocean. The increase of both pollutants and nutrient, Fe(Ⅱ), during dust storm illuminated that dust storm is an important factor affecting the global environment change.展开更多
萨拉乌苏河流域位于我国北方沙漠/黄土过渡带和生态脆弱带,它对全球气候变化反映非常敏感,是研究全球气候变化响应的理想区域.对该区域滴哨沟湾剖面地球化学元素氧化物及其比值变化进行了分析,结果表明:约220 ka BP以来我国北方气候变...萨拉乌苏河流域位于我国北方沙漠/黄土过渡带和生态脆弱带,它对全球气候变化反映非常敏感,是研究全球气候变化响应的理想区域.对该区域滴哨沟湾剖面地球化学元素氧化物及其比值变化进行了分析,结果表明:约220 ka BP以来我国北方气候变化极不稳定,存在着不同时间尺度的频繁变化,这种不稳定性无论是在冰期还是间冰期都有很好的反映.其中倒数第二次间冰期存在3次气候波动;倒数第二次冰期存在7个气候旋回;末次间冰期存在7个气候旋回;末次冰期存在9个气候旋回.这些气候变化与深海氧同位素、极地冰芯反映的全球变化具有良好的对应关系,反映了该区气候变化与全球变化的高度一致性.展开更多
基金financially supported jointly by the Key Program of Knowledge Innovation from the Chinese Academy of Sciences (Grant KZCX-3-SW-125)the National Natural Science Foundation of China (Grant Nos.40472053 and 40673021)Special Foundation on Fundamental Scientific Research as Operating Expenses among Commonweal Scientific Research In-stitutes at National Level (Grant K2007-1-12)
文摘In this paper the authors present the REE concentrations and Sr and Nd isotopic compositions of fluorites from the Bailashui tin deposit of the Furong ore field,southern Hunan Province. The results showed that the total amount of REE in fluorites is usually low,ranging from 0.705 to 8.785 μg/g with the chondrite-normalized REE dis-tribution patterns similar to those of the Qitianling granites in the study area,characterized by LREE-enrichment patterns with pronounced negative Eu anomalies. The fluorites vary in Sr isotopic composition within the range of 0.7083-0.7091,the values are lower than those of the granites and higher than those of the host carbonate rocks in this area. The εNd(t) values of fluorites vary between -9.4 and +10.3,revealing that both the crust-and mantle-source materials were involved in the ore-forming hydrothermal fluids. Combined with previous studies on this ore deposit,the Bailashui tin deposit is temporally and spatially closely related with granitic magmatism in this area. The hydro-thermal fluorites are the product of fluid/rock interactions between granitic magmatic hydrothermal fluid and marine carbonate rocks. The REE and F in the ore-forming fluid were derived from the granites,whereas Sr in the ore-forming fluid came mainly from the granitic magmatic hydrothermal fluid and marine carbonate rocks,although variations in Sr isotopic composition cannot be explained by a simple mixture of these two end-members. Evidence demonstrated that the ore-forming fluids are of crustal-mantle mixing origin,but that the fluids were probably in-completely homogenized and this may be caused by inhomogeneous mixing of the fluids of different sources.
文摘On 20 March, 2002, a super dust storm attacked Beijing, which was stronger than any dust storm ever recorded. The con-centration of total suspended particulates (TSP) reached 10.9 mg·m-3, 54 times as high as the national air quality standard. The concentrations of major crustal elements, such as Ca, AI, Fe, Na, Mg and Ti, were 30-58 times higher than those in non-dust storm days. The concentrations of pollution elements, such as Zn, Cu, Pb, As, Cd and S, were also about several or even nearly ten times higher than those in normal days. The enrichment factors of Pb, As, Cd and S in PM2.5 were as high as 12.7, 29.6, 43.5,28.4, indicating that these pollutants came from the mixing of mineral aerosol with pollution aerosol emitted by pollution sources on the way of dust storm’s long-range transport. The overlap of invaded air mass from dust with pollution air mass from Beijing local area was another reason for the enhancement of pollutants. During dust storm, fine particles (PM2.5) accounted for 30% of TSP and pollutants in PM2.5 accounted for even as high as 45%-69% of TSP. The increase of pollutants after dust storm proved further that mineral aerosol, especially the fine particles from dust storm favored the transformation and accumulation of pollutants. It must be noted that Fe (II) was detected again in this dust storm, which provided new evidence for the mechanism of coupling and feedback between iron and sulfur in the atmosphere and the ocean. The increase of both pollutants and nutrient, Fe(Ⅱ), during dust storm illuminated that dust storm is an important factor affecting the global environment change.
文摘萨拉乌苏河流域位于我国北方沙漠/黄土过渡带和生态脆弱带,它对全球气候变化反映非常敏感,是研究全球气候变化响应的理想区域.对该区域滴哨沟湾剖面地球化学元素氧化物及其比值变化进行了分析,结果表明:约220 ka BP以来我国北方气候变化极不稳定,存在着不同时间尺度的频繁变化,这种不稳定性无论是在冰期还是间冰期都有很好的反映.其中倒数第二次间冰期存在3次气候波动;倒数第二次冰期存在7个气候旋回;末次间冰期存在7个气候旋回;末次冰期存在9个气候旋回.这些气候变化与深海氧同位素、极地冰芯反映的全球变化具有良好的对应关系,反映了该区气候变化与全球变化的高度一致性.
