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聚乙二醇对振荡反应的影响 被引量:14
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作者 贺占博 黄智 顾惕人 《物理化学学报》 SCIE CAS CSCD 北大核心 1995年第8期741-745,共5页
It was found from experiments that the addition of polythylene glycol (PEG) can make the B-Z and B-R reactions producing double induction periods, i.e. before the general induction period there is an earlier stage of ... It was found from experiments that the addition of polythylene glycol (PEG) can make the B-Z and B-R reactions producing double induction periods, i.e. before the general induction period there is an earlier stage of induction in which there is no any change of color and state. The lifetime of the earlier stage is not noly effected by the concentration of PEG, but also by the time of the last reagent added. It was also found that there are two linear relationships between the concentration of PEG and the reduced viscodity of PEG solution or/and the lifetime of the earlier stage of induction. Another characteristic of PEG effect is that it can decrease the period change during the oscillat ing reactions. These experimental results are not only useful in the research pf chemical oscillation, but also give a simple method for determining colligative properties of macro molecule sultion. 展开更多
关键词 聚乙二醇 振荡反应 诱导期
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甘露醇—溴酸钾—硫酸锰—硫酸—丙酮体系的新型B-Z振荡反应 被引量:4
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作者 刘利花 景晓燕 +1 位作者 张密林 刘顺隆 《哈尔滨工程大学学报》 EI CAS CSCD 2002年第4期122-124,127,共4页
为了研究振荡机理与物性的关系 ,研究了新型的振荡体系—甘露醇 (MO) -KBrO3 -MnSO4- (Act) -H2 SO4体系的振荡特性 ,即产生分区振荡和双诱导期 .通过改变反应物的初始浓度及反应温度 ,用电极测出溶液电势随时间的变化曲线 ,得到动力学... 为了研究振荡机理与物性的关系 ,研究了新型的振荡体系—甘露醇 (MO) -KBrO3 -MnSO4- (Act) -H2 SO4体系的振荡特性 ,即产生分区振荡和双诱导期 .通过改变反应物的初始浓度及反应温度 ,用电极测出溶液电势随时间的变化曲线 ,得到动力学参数tin1、tin2 、tp1、tp2 与各反应物的定量关系和表观活化能 .结合反应物和各种添加物对振荡的影响 ,推导出振荡体系各部分的反应过程和反应机理 ,即第一振荡区的机理符合FKN机理 ,第二振荡区符合Br2 -水解模式 . 展开更多
关键词 甘露醇 分区振荡 诱导期
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