Daytime radiative cooling with high solar refection and mid-infrared emission offers a sustainable way for cooling without energy consumption.However,so far sub-ambient daytime radiative coolers typically possess whit...Daytime radiative cooling with high solar refection and mid-infrared emission offers a sustainable way for cooling without energy consumption.However,so far sub-ambient daytime radiative coolers typically possess white/silver color with limited aesthetics and applications.Although various colored radiative cooling designs have been pursued previously,multi-colored daytime radiative cooling to a temperature below ambient has not been realized as the solar thermal effect in the visible range lead to signifcant thermal load.Here,we demonstrate that photoluminescence(PL)based colored radiative coolers(PCRCs)with high internal quantum effciency enable sub-ambient full-color cooling.As an example of experimental demonstration,we develop a scalable electrostatic-spinning/inkjet printing approach to realize the sub-ambient multi-colored radiative coolers based on quantum-dot photoluminescence.The unique features of obtained PCRCs are that the quantum dots atop convert the ultraviolet–visible sunlight into emitted light to minimize the solar-heat generation,and cellulose acetate based nanofbers as the underlayer that strongly refect sunlight and radiate thermal load.As a result,the green,yellow and red colors of PCRCs achieve temperatures of 5.4–2.2℃ below ambient under sunlight(peak solar irradiance>740 Wm),respectively.With the excellent cooling performance and scalable process,our designed PCRC opens a promising pathway towards colorful applications and scenarios of radiative cooling.展开更多
基金supported by the National Natural Science Foundation of China(51971133,51902200,52071213,32000981 and 52072241)Shanghai Science and Technology Committee(18JC1410500,19ZR1425300 and 19ZR1425100)+2 种基金the National High-Level Talent Program for Young Scholars,Shenzhen Science and Technology Research Funding(JCYJ20190806170011328)China National Postdoctoral Program for Innovative Talents(BX20190352)Guangdong Province Fundamental Research Funds(2019A1515111209).
基金jointly supported by the National Key Research and Development Program of China(2021YFA1400700,2020YFA0406104,and 2017YFA0205700)the National Natural Science Foundation of China(52002168,12022403,11874211,61735008,62134009,and 62121005)+4 种基金Science Foundation of Jiangsu(BK20190311)Key Science and Technology Innovation Programme of Shandong Province(2019JZZY020704)Excellent Research Programme of Nanjing University(ZYJH005)the Fundamental Research Funds for the Central Universities(021314380214,021314380190,021314380140,and 021314380150)support from the XPLORER PRIZE。
文摘Daytime radiative cooling with high solar refection and mid-infrared emission offers a sustainable way for cooling without energy consumption.However,so far sub-ambient daytime radiative coolers typically possess white/silver color with limited aesthetics and applications.Although various colored radiative cooling designs have been pursued previously,multi-colored daytime radiative cooling to a temperature below ambient has not been realized as the solar thermal effect in the visible range lead to signifcant thermal load.Here,we demonstrate that photoluminescence(PL)based colored radiative coolers(PCRCs)with high internal quantum effciency enable sub-ambient full-color cooling.As an example of experimental demonstration,we develop a scalable electrostatic-spinning/inkjet printing approach to realize the sub-ambient multi-colored radiative coolers based on quantum-dot photoluminescence.The unique features of obtained PCRCs are that the quantum dots atop convert the ultraviolet–visible sunlight into emitted light to minimize the solar-heat generation,and cellulose acetate based nanofbers as the underlayer that strongly refect sunlight and radiate thermal load.As a result,the green,yellow and red colors of PCRCs achieve temperatures of 5.4–2.2℃ below ambient under sunlight(peak solar irradiance>740 Wm),respectively.With the excellent cooling performance and scalable process,our designed PCRC opens a promising pathway towards colorful applications and scenarios of radiative cooling.
