fragments, F- and Cl- including two isotope species 35Cl- and 37Cl-, are observed in the photoexcitations of CFC13. The ion-pair anion efficiency spectra of 35Cl- and 37Cl- are recorded in the photon energy range of 7...fragments, F- and Cl- including two isotope species 35Cl- and 37Cl-, are observed in the photoexcitations of CFC13. The ion-pair anion efficiency spectra of 35Cl- and 37Cl- are recorded in the photon energy range of 7.75-22.00 eV. The threshold of ion-pair dissociation CFCl3-CFC12＋＋Cl- is experimentally determined to be 7.944-0.04 eV. With the references of the high-resolution photoabsorption spectra reported in the literatures, we make tentative assignments of the electron valence-to-Rydberg transitions. Furthermore, the multibody ion-pair fragmentation processes to Cl- are discussed by comparison between the calculated thermochemical thresholds and the experimental efficiency spectrum.展开更多
文摘fragments, F- and Cl- including two isotope species 35Cl- and 37Cl-, are observed in the photoexcitations of CFC13. The ion-pair anion efficiency spectra of 35Cl- and 37Cl- are recorded in the photon energy range of 7.75-22.00 eV. The threshold of ion-pair dissociation CFCl3-CFC12＋＋Cl- is experimentally determined to be 7.944-0.04 eV. With the references of the high-resolution photoabsorption spectra reported in the literatures, we make tentative assignments of the electron valence-to-Rydberg transitions. Furthermore, the multibody ion-pair fragmentation processes to Cl- are discussed by comparison between the calculated thermochemical thresholds and the experimental efficiency spectrum.
文摘为了在中国科学院大气物理研究所的全球海洋模式(LASG/IAP Climate Ocean Model,LICOM)中研究不同的风场引起的海气传输速度对三氯一氟甲烷(CFC-11)在海洋中的分布和吸收产生的影响,同时选出更适用于LICOM模式模拟海洋对气体吸收的风场,本文做了4组对比实验,即传输速度为常数(实验-C)以及依赖3个不同风场(Esbensen and Kushnir观测风场(实验-EK)、National Centers for Environmental Prediction(NCEP)再分析风场(实验-NP)、QuikSCAT卫星风场(实验-QS))的实验。在对比分析中重点考察了CFC-11的海气通量、海表浓度、水柱总量、传输过程等。结果显示,不同风场带来的传输速度差异会造成模拟结果在局部海域存在显著差异,但在大部分海域的差异并不显著。而且随着积分时间的增加,从海气通量、存储量两方面可以看出,不同模拟结果之间的差异有着减小的趋势。如1955年1月北大西洋局部地区,不同的风场下的海气通量模拟结果间的差异达到20%左右,到了1995年1月这种差异下降到15%左右。此外,传输速度的选取依赖风场计算值的全球平均值(试验-C)会造成模拟结果相对偏小,而风速相对较大的QuikSCAT卫星风场资料在一定程度上使得模式模拟结果与观测资料更为接近。
