K411 合金含有较多的W,Mo,Nb 等难溶金属元素。这些元素溶入γ′相和合金基体γ,提高了原子间结合力,从而强化了γ′相;同时难溶金属的 d 电子层被部分填充,提高了固溶体的空位形成能,降低了元素扩散系数,并增加了模量差和尺寸错配效应...K411 合金含有较多的W,Mo,Nb 等难溶金属元素。这些元素溶入γ′相和合金基体γ,提高了原子间结合力,从而强化了γ′相;同时难溶金属的 d 电子层被部分填充,提高了固溶体的空位形成能,降低了元素扩散系数,并增加了模量差和尺寸错配效应,进一步强化了固溶体。上述两个原因使 K411 合金有较高的高温强度,达到含 Co 合金M-M200水平。展开更多
Post-bond heat treatment(PBHT) applied to a transient liquid phase(TLP) bonding joint is an effective approach to remove the brittle borides and improve its properties.Herein,we proposed two types of PBHT strategies t...Post-bond heat treatment(PBHT) applied to a transient liquid phase(TLP) bonding joint is an effective approach to remove the brittle borides and improve its properties.Herein,we proposed two types of PBHT strategies to obtain a TLP bonded γ'-strengthened Co-based single crystal superalloy,and the microstructural characteristics and tensile properties of the two heat treated joints were compared to identify the optimal PBHT strategy.The evolution of the brittle boride in the joint after the PBHT was studied by using in-situ microscopy.The experimental results allowed to provide a theoretic model to quantitatively evaluate the distribution of the brittle phase after the optimal PBHT and analyze the joint fractures to understand the failure mechanisms.The obtained results revealed that a post-bond solid solution treatment performed to the joint at a high temperature(over 1275℃) could decrease the area fraction of the boride from 7.2 % to 1.4 % and increase the elongation from 1.9 % to 7.8 %.This work emphasizes the relevance of solid solution temperature when a PBHT strategy is applied.展开更多
文摘K411 合金含有较多的W,Mo,Nb 等难溶金属元素。这些元素溶入γ′相和合金基体γ,提高了原子间结合力,从而强化了γ′相;同时难溶金属的 d 电子层被部分填充,提高了固溶体的空位形成能,降低了元素扩散系数,并增加了模量差和尺寸错配效应,进一步强化了固溶体。上述两个原因使 K411 合金有较高的高温强度,达到含 Co 合金M-M200水平。
基金financially supported by the Project from the National Natural Science Foundation of China under Grant(No.51771191)the National Key Research and Development Program of China under Grant(No.2017YFA0700704)the Aerospace Power Foundation under Grant(DLJJ1825)。
文摘Post-bond heat treatment(PBHT) applied to a transient liquid phase(TLP) bonding joint is an effective approach to remove the brittle borides and improve its properties.Herein,we proposed two types of PBHT strategies to obtain a TLP bonded γ'-strengthened Co-based single crystal superalloy,and the microstructural characteristics and tensile properties of the two heat treated joints were compared to identify the optimal PBHT strategy.The evolution of the brittle boride in the joint after the PBHT was studied by using in-situ microscopy.The experimental results allowed to provide a theoretic model to quantitatively evaluate the distribution of the brittle phase after the optimal PBHT and analyze the joint fractures to understand the failure mechanisms.The obtained results revealed that a post-bond solid solution treatment performed to the joint at a high temperature(over 1275℃) could decrease the area fraction of the boride from 7.2 % to 1.4 % and increase the elongation from 1.9 % to 7.8 %.This work emphasizes the relevance of solid solution temperature when a PBHT strategy is applied.
