Eu3+-activated Gd2(MoO4)3 pseudo-pompon-like red-emitting phosphors were prepared by solid-state method. The structure, morphology, and luminescent properties of these powder samples were investigated by X-ray diffrac...Eu3+-activated Gd2(MoO4)3 pseudo-pompon-like red-emitting phosphors were prepared by solid-state method. The structure, morphology, and luminescent properties of these powder samples were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), and fluorescent spectrophotometry, respectively. The as-obtained phosphors were single crystalline phase with orthorhombic unit cell. The particles of the powder samples had the length of 5-12 m and width of 3-7 m with flake shape and large surface area, which is suitable for manufacture of white LEDs. The phosphor could be efficiently excited by the incident light of 348-425 nm, well matched with the output wavelength of near-UV (In,Ga)N chip, and re-emitted an intense red light peaking at 615 nm. By combing this phosphor with a ~395 nm-emitting (In,Ga)N chip, a red LED was fabricated, so that the applicability of this novel phosphor to white LEDs was confirmed. It is considered to be an efficient red-emitting conversion phosphor for solid-state lighting based on (In,Ga)N LEDs.展开更多
We report that β’-Gd2(MoO4)3 crystals have been grown by the Czochralski(CZ) method.We studied the growth conditions fo β’-Gd2(MoO4)3 crystal.A compatison between the resistance-heated method and radio frequency i...We report that β’-Gd2(MoO4)3 crystals have been grown by the Czochralski(CZ) method.We studied the growth conditions fo β’-Gd2(MoO4)3 crystal.A compatison between the resistance-heated method and radio frequency induction-heated method is described.Also,the in situ observation of the domain structure by the microscope and by synchrotron radiation X-ray topography under the conditions of DC polarization voltage and tempertature change were carried out.Experiments showed that multidomain structure including ferroelectric and ferroelastic domains occurred in β’-Gd2(MoO4)3 cystal.Usually ferroeletiric domains appeared in the as-grown crystal and ferroelastic domains appeared in the polished thinner piece.Both ferroelectric and ferroelastic domains disappeared when the temperature of the crystal piece was higher than the Curie tempperature Tc and they could be reproduced when the temperature of the crystal piece was lowered below TC.When a DC polarization voltage ranging from 150 to 500V was applied on a c-axis β’-Gd2(MoO4)3 piece having a thickness of 0.5mm ,the multidomain would gradually transform to a single domain.This resual means that it is possible to make a periodically poled β’-Gd2(MoO4)3 crystal.2001 Elsevier Science B.V.All rights reserved.展开更多
Polycrystalline Gd2(MoO4)3:Dy3+ phosphors have been synthesized by high temperature solid-state reaction method. The phosphors were characterized with X-ray diffractometer, thermogravimetric analysis and different sca...Polycrystalline Gd2(MoO4)3:Dy3+ phosphors have been synthesized by high temperature solid-state reaction method. The phosphors were characterized with X-ray diffractometer, thermogravimetric analysis and different scanning calorimeter, scanning electron microscopy, and photoluminescence spectrofluorimeter. Several peaks at 351, 389, 425, 452, and 472 nm appeared in photoluminescence excitation spectrum, which matched well with the emission of the ultraviolet (UV) and blue-light emitting diode (LED) chips. Upon excitation at 389 nm UV light, intense emissions centered at 484, 575 and 668 nm were attributed to the transitions of 4F9/2→6H15/2, 4F9/2→6H13/2 and 4F9/2→6H11/2 of Dy3+, respectively. The chromaticity coordinates and correlative color temperatures have been calculated and presented in the Commission International de I’Eclairage (CIE) diagrams. The results indicated that Gd1.9(MoO4)3:Dy0.13+ with CIE coordinates of (x=0.38, y=0.41) and the correlative color temperature of 4134 K is a potential candidate for white LEDs.展开更多
基金Project supported by the Natural Science Research Project of the Jiangsu Higher Education Institutions (08KJD150014)the QingLan Project of the Jiangsu Province (2008)the Basic Research Fund of Jiangsu Teachers University of Technology (KYY09031)
文摘Eu3+-activated Gd2(MoO4)3 pseudo-pompon-like red-emitting phosphors were prepared by solid-state method. The structure, morphology, and luminescent properties of these powder samples were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), and fluorescent spectrophotometry, respectively. The as-obtained phosphors were single crystalline phase with orthorhombic unit cell. The particles of the powder samples had the length of 5-12 m and width of 3-7 m with flake shape and large surface area, which is suitable for manufacture of white LEDs. The phosphor could be efficiently excited by the incident light of 348-425 nm, well matched with the output wavelength of near-UV (In,Ga)N chip, and re-emitted an intense red light peaking at 615 nm. By combing this phosphor with a ~395 nm-emitting (In,Ga)N chip, a red LED was fabricated, so that the applicability of this novel phosphor to white LEDs was confirmed. It is considered to be an efficient red-emitting conversion phosphor for solid-state lighting based on (In,Ga)N LEDs.
文摘We report that β’-Gd2(MoO4)3 crystals have been grown by the Czochralski(CZ) method.We studied the growth conditions fo β’-Gd2(MoO4)3 crystal.A compatison between the resistance-heated method and radio frequency induction-heated method is described.Also,the in situ observation of the domain structure by the microscope and by synchrotron radiation X-ray topography under the conditions of DC polarization voltage and tempertature change were carried out.Experiments showed that multidomain structure including ferroelectric and ferroelastic domains occurred in β’-Gd2(MoO4)3 cystal.Usually ferroeletiric domains appeared in the as-grown crystal and ferroelastic domains appeared in the polished thinner piece.Both ferroelectric and ferroelastic domains disappeared when the temperature of the crystal piece was higher than the Curie tempperature Tc and they could be reproduced when the temperature of the crystal piece was lowered below TC.When a DC polarization voltage ranging from 150 to 500V was applied on a c-axis β’-Gd2(MoO4)3 piece having a thickness of 0.5mm ,the multidomain would gradually transform to a single domain.This resual means that it is possible to make a periodically poled β’-Gd2(MoO4)3 crystal.2001 Elsevier Science B.V.All rights reserved.
基金Project supported by the National Natural Science Foundation of China (50872036)
文摘Polycrystalline Gd2(MoO4)3:Dy3+ phosphors have been synthesized by high temperature solid-state reaction method. The phosphors were characterized with X-ray diffractometer, thermogravimetric analysis and different scanning calorimeter, scanning electron microscopy, and photoluminescence spectrofluorimeter. Several peaks at 351, 389, 425, 452, and 472 nm appeared in photoluminescence excitation spectrum, which matched well with the emission of the ultraviolet (UV) and blue-light emitting diode (LED) chips. Upon excitation at 389 nm UV light, intense emissions centered at 484, 575 and 668 nm were attributed to the transitions of 4F9/2→6H15/2, 4F9/2→6H13/2 and 4F9/2→6H11/2 of Dy3+, respectively. The chromaticity coordinates and correlative color temperatures have been calculated and presented in the Commission International de I’Eclairage (CIE) diagrams. The results indicated that Gd1.9(MoO4)3:Dy0.13+ with CIE coordinates of (x=0.38, y=0.41) and the correlative color temperature of 4134 K is a potential candidate for white LEDs.
