The title complex, C37H34N6NiO5, has been prepared and characterized by X-ray diffraction analysis. It crystallizes in the monoclinic system, space group P2（1/c） with a = 1.15244（8）, b = 1.69679（12）, c = 1.78341...The title complex, C37H34N6NiO5, has been prepared and characterized by X-ray diffraction analysis. It crystallizes in the monoclinic system, space group P2（1/c） with a = 1.15244（8）, b = 1.69679（12）, c = 1.78341 （13） nm, β = 102.2320（10）°, V = 3.4082（4） nm^3, Z = 4, Mr = 701.41, F（000） = 1464, Dc = 1.367 g/cm^3 and μ（MoKα） = 0.622 mm^-1. The structure was refined to R = 0.0459 and wR = 0.1199 for 5718 observed reflections. The intramolecular hydrogen bonds in the crystal structure play important roles in the title complex＇s thermostability.展开更多
基金The project was supported by the Natural Science Foundation of Hubei Province (No. 00A046)
文摘The title complex, C37H34N6NiO5, has been prepared and characterized by X-ray diffraction analysis. It crystallizes in the monoclinic system, space group P2（1/c） with a = 1.15244（8）, b = 1.69679（12）, c = 1.78341 （13） nm, β = 102.2320（10）°, V = 3.4082（4） nm^3, Z = 4, Mr = 701.41, F（000） = 1464, Dc = 1.367 g/cm^3 and μ（MoKα） = 0.622 mm^-1. The structure was refined to R = 0.0459 and wR = 0.1199 for 5718 observed reflections. The intramolecular hydrogen bonds in the crystal structure play important roles in the title complex＇s thermostability.
