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非共沸环保制冷剂的特点和应用技术 被引量:3
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作者 陈九法 《制冷技术》 2004年第4期4-7,共4页
环保制冷剂有很多是非共沸的,如R407C和R417A,这些制冷剂与常规制冷剂有不同特点。本文将分析研究非共 沸制冷剂在系统的设计、调试、运行和维修中的难点,为制冷系统的安全、可靠和高效的运行提供技术支撑。
关键词 环保制冷剂 R407C 制冷系统 共沸 运行 高效 可靠 调试
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大滑移温度CO_(2)非共沸工质余热回收热泵热水系统实验研究
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作者 张涛 吴嘉峰 +2 位作者 刘剑 张小松 李明霞 《制冷学报》 CAS CSCD 北大核心 2024年第4期21-27,共7页
通过热泵技术将生产/生活中的低品位余热提质增效具有广泛的应用潜力。其中,非共沸工质能够实现热泵循环换热过程中的温度匹配,实现余热资源的深度利用。基于水源热泵热水实验台对基于大滑移温度的CO_(2)/R1234yf、CO_(2)/R290、CO_(2)/... 通过热泵技术将生产/生活中的低品位余热提质增效具有广泛的应用潜力。其中,非共沸工质能够实现热泵循环换热过程中的温度匹配,实现余热资源的深度利用。基于水源热泵热水实验台对基于大滑移温度的CO_(2)/R1234yf、CO_(2)/R290、CO_(2)/R600a和CO_(2)/R32非共沸工质进行实验分析,并以R290工质作为对照,研究蒸发器与冷凝器同时满足大温差情况下的热泵性能表现。结果表明:非共沸工质充注量主要影响循环过冷度,进而影响系统COP,当CO_(2)/R1234yf的质量分数为15%/85%时,循环存在最优充注量,在实验工况(热源进水温度25℃,出水温度5℃;热汇进水温度15℃,出水温度45℃)下最优充注量对应的COP为7.66。同时,在实验工况下,相较于R290单工质,CO_(2)/R290工质对最优COP提升了75.2%,对应q v(单位容积制热量)提升了107.7%;CO_(2)/R1234yf工质对最优COP提升了27.7%,对应q v提升了92.0%;CO_(2)/R32工质对最优COP提升了15.0%;而CO_(2)/R600a工质对最优COP仅提升1.7%,应用潜力较低。 展开更多
关键词 热泵 余热回收 非共沸混合物 滑移温度
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复叠式制冷系统低温环路制冷剂R744(CO2)/R290的实验研究 被引量:2
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作者 李新禹 牛宝联 徐杰 《天津工业大学学报》 CAS 北大核心 2009年第2期67-70,共4页
针对工质R13的替代研究,提出了一种非共沸混合工质55%R744(CO2)/45%R290作为复叠式制冷系统低温环路的制冷剂,并在复叠式制冷实验台上进行了不同蒸发器进口温度的实验及分析.通过将该工质在各工况下的实验结论与相应工况下R13的实验结... 针对工质R13的替代研究,提出了一种非共沸混合工质55%R744(CO2)/45%R290作为复叠式制冷系统低温环路的制冷剂,并在复叠式制冷实验台上进行了不同蒸发器进口温度的实验及分析.通过将该工质在各工况下的实验结论与相应工况下R13的实验结论进行对比分析,发现该物质的制冷量和制冷系数均高于R13;吸气温度、排气温度和压缩比均低于R13;当蒸发温度在-64^-67℃变化时,该物质的循环性能优于R13;在相同的初温下,当低温恒温室内空气温度降低到-55℃时,其制冷速率比R13快7.4%. 展开更多
关键词 自然工质 非共沸混合物 复叠式制冷系统
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基于大滑移温度非共沸工质双冷源制冷机组的分析 被引量:1
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作者 满亮 张小松 +1 位作者 刘剑 徐国英 《制冷学报》 CAS CSCD 北大核心 2017年第2期89-95,共7页
为了研究冷冻水温度对双冷源制冷机组各部件和整个系统损的影响,本文构建以R32/R236fa(质量比:60%/40%)为循环工质的双冷源冷水机组分析模型,利用双冷源制冷机组实验平台进行多组实验,通过理论分析和实验分析对系统性能进行研... 为了研究冷冻水温度对双冷源制冷机组各部件和整个系统损的影响,本文构建以R32/R236fa(质量比:60%/40%)为循环工质的双冷源冷水机组分析模型,利用双冷源制冷机组实验平台进行多组实验,通过理论分析和实验分析对系统性能进行研究。研究了冷凝温度为32℃、高低温冷冻水分别为18℃/8℃、17℃/6℃等7组时,制冷机组的理论损和实验损的变化情况。结果表明:当高低温冷冻水出水温度分别为17℃和8℃、冷凝温度为32℃时,双冷源制冷机组的总损最小为0.68 k W。此时,损最大的为压缩机,约占总损的52.7%;其次为冷凝器,约占总损的17.4%。 展开更多
关键词 非共沸混合物 冷水机组 实验工况 [火用]分析
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R407C在水平单管外凝结换热的实验研究 被引量:10
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作者 成昌锐 王秋旺 +1 位作者 刘星 陶文铨 《工程热物理学报》 EI CAS CSCD 北大核心 2001年第S1期50-52,共3页
本文用实验方法研究了R407C在水平单管外的凝结换热,并与HCFC22做了对比。试验管包括一根光管和两根双侧强化管。结果表明,R407C在水平管(包括光管和强化管)外的冷凝换热系数随着热流密度的增加而显著增加,而且,... 本文用实验方法研究了R407C在水平单管外的凝结换热,并与HCFC22做了对比。试验管包括一根光管和两根双侧强化管。结果表明,R407C在水平管(包括光管和强化管)外的冷凝换热系数随着热流密度的增加而显著增加,而且,强化管增长的程度要比光管的强烈。在相同的冷凝温度与热流密度范围内,无论对于光管还是强化管,R407C的管外冷凝换热系数都远小于HCFC22的值。对于所试验的两种强化管,HCFC22的管外冷凝换热系数的强化效果比R407C更明显。 展开更多
关键词 凝结换热 非共沸工质 光管及强化管
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采用非共沸混合工质机械过冷的跨临界CO_2制冷循环性能分析 被引量:13
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作者 代宝民 刘圣春 +3 位作者 孙志利 马牧宇 陈启 马一太 《制冷学报》 CAS CSCD 北大核心 2018年第6期46-53,69,共9页
本文提出了非共沸混合工质机械过冷跨临界CO_2制冷循环。在最优排气压力和最优过冷度下循环取得最大COP。最大COP、最优排气压力和过冷度与混合制冷剂的温度滑移密切相关。当选取合理温度滑移的混合工质作为机械过冷循环的制冷剂时,可... 本文提出了非共沸混合工质机械过冷跨临界CO_2制冷循环。在最优排气压力和最优过冷度下循环取得最大COP。最大COP、最优排气压力和过冷度与混合制冷剂的温度滑移密切相关。当选取合理温度滑移的混合工质作为机械过冷循环的制冷剂时,可明显提升CO_2制冷循环能效,降低排气压力。与基本CO_2制冷循环相比,在蒸发温度为-40℃、环境温度为35℃时,采用R32/R152a(40/60)循环总COP可提升46.53%,CO_2排气压力可降低2.758 MPa。总COP的提升程度受混合制冷剂的温度滑移影响显著,推荐机械过冷循环使用温度滑移合理的混合制冷剂。在温暖和炎热的气候地区及冷冻冷藏等低温应用领域,采用非共沸混合制冷剂机械过冷跨临界CO_2制冷循环整体性能的提升更加显著。 展开更多
关键词 CO2 非共沸工质 机械过冷 制冷循环 温度滑移
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Thermodynamic Analysis of a Mixed Refrigerant Ejector Refrigeration Cycle Operating with Two Vapor-liquid Separators 被引量:13
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作者 TAN Yingying CHEN Youming WANG Lin 《Journal of Thermal Science》 SCIE EI CAS CSCD 2018年第3期230-240,共11页
A mixed refrigerant ejector refrigeration cycle operating with two-stage vapor-liquid separators (MRERC2) is proposed to obtain refrigeration temperature at -40℃. The thermodynamic investigations on per- formance o... A mixed refrigerant ejector refrigeration cycle operating with two-stage vapor-liquid separators (MRERC2) is proposed to obtain refrigeration temperature at -40℃. The thermodynamic investigations on per- formance of MRERC2 using zeotropic mixture refrigerant R23/R134a are performed, and the comparisons of cycle performance between MRERC2 and MRERC1 CMRERC with one-stage vapor-liquid separator) are conducted. The results show that MRERC2 can achieve refrigeration temperature varying between -23.9℃ and -42.0℃ when ejector pressure ratio ranges from 1.6 to 2.3 at the generation temperature of 57.3-84.9℃. The parametric analysis indicates that increasing condensing temperature decreases coefficient of performance (COP) of MRERC2, and increasing ejector pressure ratio and mass fraction of the low boiling point component in the mixed refrigerant can improve COP of MRERC2. The MRERC2 shows its potential in utilizing low grade thermal energy as driving power to obtain low refrigeration temperature for the ejector refrigeration cycle. 展开更多
关键词 Ejector Refrigeration zeotropic Refrigerant Vapor-liquid Separator Refrigeration Temperature
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非共沸不互溶混合工质脉动热管启动特性分析 被引量:9
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作者 张超 徐荣吉 +1 位作者 陈静妍 吴青平 《化工进展》 EI CAS CSCD 北大核心 2019年第12期5279-5286,共8页
针对低加热功率下脉动热管难启动的问题,本文提出一种用于脉动热管相变传热的非共沸不互溶混合工质(HFE-7100和水),其中低沸点工质潜热小、比热容低、密度大,高沸点工质潜热大、比热容高、密度低。选取水为高沸点工质,HFE-7100为低沸点... 针对低加热功率下脉动热管难启动的问题,本文提出一种用于脉动热管相变传热的非共沸不互溶混合工质(HFE-7100和水),其中低沸点工质潜热小、比热容低、密度大,高沸点工质潜热大、比热容高、密度低。选取水为高沸点工质,HFE-7100为低沸点工质,并将两者按照4∶1、2∶1、1∶1、1∶2、1∶4比例混合,实验研究了不同混合比例工质在不同充灌率和不同加热功率下的启动特性。结果表明:相对于水,HFE-7100的低汽化潜热值和高(dp/d T)sat值等特点能够加快蒸发段气泡的形成,加速脉动热管的启动;相对于纯工质脉动热管,非共沸不互溶混合工质相当于缩短了脉动热管的有效长度,加快系统启动;在低加热功率下,纯工质脉动热管无法启动,但混合工质脉动热管能够正常启动,且混合比例为2∶1、1∶1和1∶2时启动较快;在高加热功率下,混合比例2∶1启动最快。同时,对于非共沸不互溶混合工质脉动热管,充灌率为30%时启动效果最好。 展开更多
关键词 脉动热管 非共沸 气液两相流 混合工质 充灌率
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Evaluation of zeotropic refrigerants based on nonlinear relationship between temperature and enthalpy 被引量:4
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作者 ZHAO Li GAO Pan 《Science China(Technological Sciences)》 SCIE EI CAS 2006年第3期322-331,共10页
In order to evaluate cycling characters of zeotropic refrigerants in air-con- ditioning operation, and to reveal distribution rules of temperature difference between refrigerants and heat transfer fluids in condenser ... In order to evaluate cycling characters of zeotropic refrigerants in air-con- ditioning operation, and to reveal distribution rules of temperature difference between refrigerants and heat transfer fluids in condenser and evaporator, theoretical researches were carried out based on nonlinear relationship between temperature and enthalpy in period of refrigerants’ phase change. Firstly, a phase changing model of refrigerants was built, and refrigerants state parameters were decided in the air-conditioning operation. Secondly, the state equation of refrigerants was applied for computing relationship be- tween temperature and enthalpy, else based on some suppositions, temperature differ- ences between 15 sorts of refrigerants and heat-transfer fluids were gotten too. Through concluding those temperature differences changing in condenser and evaporator, some rules were found. Lastly, after calculating and comparing the additive exergy loss among 15 sorts of refrigerants, which resulted from the changing of temperature difference, their cycling characters evaluation were presented. 展开更多
关键词 zeotropic refrigerants evaluation phase change TEMPERATURE distribution the additive EXERGY loss air CONDITIONING operation.
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Influence of Zeotropic Mixtures' Temperature Gliding on the Performance of Heat Transfer in Condenser or Evaporator 被引量:4
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作者 赵力 高攀 《Transactions of Tianjin University》 EI CAS 2005年第6期400-406,共7页
Many zeotropic refrigerant mixtures are proposed as alternatives to some chlorofluorocar-bons (CFCs) and hydrochlorofluorocarbons ( HCFCs). An advantage of zeotropic mixtures is the possibility of reduction in entropy... Many zeotropic refrigerant mixtures are proposed as alternatives to some chlorofluorocar-bons (CFCs) and hydrochlorofluorocarbons ( HCFCs). An advantage of zeotropic mixtures is the possibility of reduction in entropy generation by matching the temperature glidings of refrigerant and heat-transfer fluid in both condenser and evaporator. Zeotropic mixtures are compared with pure re-frigerants to evaluate their exergetic losses. On the other hand, the special phenomena which result from temperature gliding are proved by experiments. A simple equation is obtained, to evaluate dif-ferent zeotropic mixtures' exergetic losses. The maximum flow rate of heat-transfer fluids is found in order that refrigerants phase change can be completed. Lastly, some examples of zeotropic mix-tures ( R407C, R405A and R414B) are given, and their exergetic losses and maximum flow rate of heat-transfer fluids in condenser are forecasted. 展开更多
关键词 zeotropic mixtures temperature gliding exergetic loss maximum flow rate
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冷冻水流量和温度对基于混合工质的双温冷水机组性能影响 被引量:4
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作者 刘剑 张小松 《制冷学报》 CAS CSCD 北大核心 2015年第6期83-89,共7页
为研究冷冻水流量与温度变化对基于大滑移温度非共沸工质双温冷水机组性能的影响规律,本文在大滑移温度非共沸工质的双温冷水机组实验台进行了多组实验研究。实验分别研究了非共沸工质R32/R236fa在不同质量组分比例(0.4∶0.6,0.5∶0.5,... 为研究冷冻水流量与温度变化对基于大滑移温度非共沸工质双温冷水机组性能的影响规律,本文在大滑移温度非共沸工质的双温冷水机组实验台进行了多组实验研究。实验分别研究了非共沸工质R32/R236fa在不同质量组分比例(0.4∶0.6,0.5∶0.5,0.6∶0.4)下,冷冻水流量由0.25 m^3/h增大到0.45 m^3/h,以及高温冷冻水温度变化时,冷水机组性能的变化情况。实验结果表明,在冷却水进出口温度为32℃与37℃,高、低温冷冻水温度分别为7℃,16℃时,不同冷冻水流量下冷水机组的制冷效率(COP)最大为4.17,最小COP为3.27。此外,高温冷冻水温度变化对冷水机组COP存在明显影响。实验为大滑移温度的双温冷水机组的应用提出了数据基础。 展开更多
关键词 非共沸工质 变流量 COP 大滑移温度
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自动复叠制冷系统的应用研究 被引量:4
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作者 王新一 任绍民 《制冷》 2010年第3期1-3,共3页
自动复叠制冷系统具有广泛的应用价值,能够同时满足环保和对低温环境的需求。本文提出一种四级自动复叠制冷系统,对制冷剂选取原则和制冷循环流程进行介绍,通过选择合适的混合工质、搭建实验台,成功得到所设计的温度。
关键词 自动复叠制冷系统 混合工质 非共沸 应用研究
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非共沸工质蒸发式冷凝器多目标优化设计
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作者 熊远帆 李华山 龚宇烈 《化工进展》 EI CAS CSCD 北大核心 2024年第6期2950-2960,共11页
将蒸发式冷凝器应用于非共沸有机朗肯循环可以有效提高系统的热经济性。建立了蒸发式冷凝器的Kriging代理模型,以R601a组分质量分数、空气流量、喷淋水流量作为决策变量,换热面积和(火用)效率为目标函数,开展了目标函数的影响因素分析,... 将蒸发式冷凝器应用于非共沸有机朗肯循环可以有效提高系统的热经济性。建立了蒸发式冷凝器的Kriging代理模型,以R601a组分质量分数、空气流量、喷淋水流量作为决策变量,换热面积和(火用)效率为目标函数,开展了目标函数的影响因素分析,并采用非支配排序遗传算法和TOPSIS决策法开展多目标优化。结果表明,影响因素分析中,空气流量对目标函数的影响程度比喷淋水流量更大,而R601a组分质量分数为0.7左右时,换热面积有最小值且(火用)效率有最大值;Pareto前沿中,R601a组分质量分数对蒸发式冷凝器的设计存在最佳的取值范围,而空气流量、喷淋水流量的取值范围较广,几乎涵盖其整个变化范围。成本低、占用空间小且对可用能的有效利用程度大的方案为:R601a组分质量分数0.725,空气流量81.017kg/s,喷淋水流量58.302kg/s。对应的换热面积为316.883m^(2),(火用)效率为0.428。 展开更多
关键词 蒸发式冷凝器 非共沸 代理模型 多目标 优化设计
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Review on Applications of Zeotropic Mixtures 被引量:4
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作者 BAI Mengjie ZHAO Li ZHAO Ruikai 《Journal of Thermal Science》 SCIE EI CAS CSCD 2022年第2期285-307,共23页
Compared with the pure fluids,the zeotropic mixtures can balance the requirements of environmental protection,heat source matching and system safety,and exhibit excellent thermodynamic performance.However,compared to ... Compared with the pure fluids,the zeotropic mixtures can balance the requirements of environmental protection,heat source matching and system safety,and exhibit excellent thermodynamic performance.However,compared to the widespread applications of pure fluids,zeotropic mixtures are rarely exploited in thermodynamic cycles,and there is a lack of targeted summary on refrigeration systems,organic Rankine cycle systems and combined power and refrigeration systems.In the recent years,zeotropic mixtures are developing at an unprecedented pace,while the working fluids components are inevitably explored in the process.In this paper,the research progress of zeotropic mixtures in the field of refrigeration systems,organic Rankine cycle systems and combined power and refrigeration systems are reviewed.Based on the review of zeotropic working mixtures,the reasonable predictions can be proposed.In the future,environmental problems will still be one of the most important concerned issues.Therefore,the zeotropic mixtures consisting of natural hydrocarbons and carbon dioxide,which are environmentally friendly,have great potential for development.Furthermore,zeotropic mixtures of natural working fluids can improve comprehensive energy efficiency of combined systems and will play an important role in future carbon emission reduction technologies. 展开更多
关键词 combined power and refrigeration systems heat pump natural working fluids organic Rankine cycle REFRIGERATION zeotropic mixtures
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Performance analysis of a zeotropic mixture(R290/CO_2) for trans-critical power cycle 被引量:3
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作者 潘利生 魏小林 史维秀 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2015年第3期572-577,共6页
Low critical temperature limits the application of CO_2 trans-critical power cycle.The binary mixture of R290/CO_2has higher critical temperature.Using mixture fluid may solve the problem that subcritical CO_2 is hard... Low critical temperature limits the application of CO_2 trans-critical power cycle.The binary mixture of R290/CO_2has higher critical temperature.Using mixture fluid may solve the problem that subcritical CO_2 is hardly condensed by conventional cooling water.In this article,theoretical analysis is executed to study the performance of the zeotropic mixture for trans-critical power cycle using low-grade liquid heat source with temperature of200℃.The results indicated that the problem that CO_2 can't be condensed in power cycle by conventional cooling water can be solved by mixing R290 to CO_2.Variation trend of outlet temperature of thermal oil in supercritical heater with heating pressure is determined by the composition of the mixture fluid.Gliding temperature causes the maximum outlet temperature of cooling water with the increase of mass fraction of R290.There are the maximum values for cycle thermal efficiency and net power output with the increase of supercritical heating pressure. 展开更多
关键词 CO2 R290 zeotropic mixture Low-grade heat energy Trans-critical power cycle
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Performance Analysis of an Ejector Enhanced Two-Stage Auto-Cascade Refrigeration Cycle for Low Temperature Freezer 被引量:3
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作者 BAI Tao LU Yu +1 位作者 YAN Gang YU Jianlin 《Journal of Thermal Science》 SCIE EI CAS CSCD 2021年第6期2015-2026,共12页
In this paper,an ejector enhanced two-stage auto-cascade refrigeration cycle(EARC)using ternary mixture R600a/R32/R1150 is proposed for application of-80℃freezing.In EARC cycle,an ejector was employed to recover the ... In this paper,an ejector enhanced two-stage auto-cascade refrigeration cycle(EARC)using ternary mixture R600a/R32/R1150 is proposed for application of-80℃freezing.In EARC cycle,an ejector was employed to recover the expansion work in the throttling processes and lifted the suction pressure of the compressor.The performances of the ejector enhanced two-stage auto-cascade refrigeration cycle and conventional auto-cascade refrigeration cycle(CARC)were compared using thermodynamic analysis methods.The influences of the important operation parameters including mass fraction ratio of the mixture,fluid quality at the second separator inlet,condensation temperature,evaporation temperature,and expansion ratio of expansion valve on the performances of EARC cycle were discussed in detail.The results indicate that ternary mixture R600a/R32/R1150 has the optimal mass fraction ratio of 0.45/0.2/0.35 with respect to the maximum COP.The EARC cycle yields higher performance than the CARC cycle in terms of COP,exergy efficiency and volumetric refrigeration capacity.And 4.9%-36.5%improvement in COP and 6.9%-34.3%higher exergy efficiency could be obtained in EARC cycle comparing with CARC cycle.The finding of this study suggests that the EARC cycle has a promising application potential for low temperature freezing. 展开更多
关键词 two-stage auto-cascade refrigeration zeotropic mixture EJECTOR performance improvement exergy analysis
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Parametric Optimization of Organic Rankine Cycle with R245fa/R601a as Working Fluid 被引量:1
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作者 朱家玲 康振华 +1 位作者 安青松 李太禄 《Transactions of Tianjin University》 EI CAS 2015年第1期69-75,共7页
In order to select the appropriate working fluids and optimize parameters for medium-temperature geothermally-powered organic Rankine cycle(ORC), R245 fa is mixed with R601 a at geothermal water temperature of 110 ℃.... In order to select the appropriate working fluids and optimize parameters for medium-temperature geothermally-powered organic Rankine cycle(ORC), R245 fa is mixed with R601 a at geothermal water temperature of 110 ℃. Based on thermodynamics, the characteristics of mixture and its influence on the performance of ORC under different evaporating temperatures and composition proportions are analyzed. Results show that the zeotropic mixture R245fa/R601a(0.4/0.6) has the highest performance. When the evaporating temperature reaches 67 ℃, the outlet temperature of geothermal water is 61 ℃, the net power output is the highest and the thermal efficiency is about 9%. 展开更多
关键词 medium temperature geothermal source organic Rankine cycle zeotropic mixture optimization parameter system performance
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Exergy Analysis of Organic Rankine Cycles with Zeotropic Working Fluids
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作者 Antonio Mariani Davide Laiso +1 位作者 Biagio Morrone Andrea Unich 《Fluid Dynamics & Materials Processing》 EI 2023年第3期593-601,共9页
Waste heat recovery is one of the possible solutions to improve the efficiency of internal combustion engines.Instead of wasting the exhaust stream of an energy conversion system into the environment,its residual ener... Waste heat recovery is one of the possible solutions to improve the efficiency of internal combustion engines.Instead of wasting the exhaust stream of an energy conversion system into the environment,its residual energy content can be usefully recovered,for example in Organic Rankine Cycles(ORC).This technology has been largely consolidated in stationary power plants but not yet for mobile applications,such as road transport,due to the limitations in the layout and to the constraints on the size and weight of the ORC system.An ORC system installed on the exhaust line of a bus powered by a natural gas spark ignition engine has been investigated.The thermal power available at engine exhaust has been evaluated by measuring gas temperature and mass flow rate during real driving operation.The waste thermal power has been considered as heat input for the ORC plant simulation.A detailed heat exchanger model has been developed because it is a crucial component for the ORC performance.The exergy analysis of the ORC was performed comparing different working fluids:R601,R1233zd(E)and two zeotropic blends of the two organic pure fluids.The model allowed the evaluation of the ORC produced energy over the driving cycle and the potential benefit on the engine efficiency. 展开更多
关键词 Organic Rankine Cycle zeotropic mixtures exergy analysis waste heat recovery engine efficiency internal combustion engine
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丁二烯塔釜废烃的综合利用 被引量:1
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作者 张雪松 《河南化工》 CAS 2014年第9期24-29,共6页
丁二烯抽提过程中丁二烯塔釜会产生一定量的废烃,其中绝大部分是C4烯烃,余下部分是C5烃类、甲苯、TBC和少量聚合物。在NMP工艺中,这股物料可以进入装置的适当部位进行分离利用,解决了混合物直接处理相对困难的问题。该种处理方法还使得... 丁二烯抽提过程中丁二烯塔釜会产生一定量的废烃,其中绝大部分是C4烯烃,余下部分是C5烃类、甲苯、TBC和少量聚合物。在NMP工艺中,这股物料可以进入装置的适当部位进行分离利用,解决了混合物直接处理相对困难的问题。该种处理方法还使得部分TBC的循环使用成为可能,能够降低装置阻聚剂的消耗量,创造一定的经济价值。 展开更多
关键词 废烃 TBC 共沸 甲苯 C4炔烃
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非共沸混合制冷剂组分对冷凝器换热特性的影响 被引量:1
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作者 冯永斌 晏刚 钱文波 《低温工程》 CAS CSCD 北大核心 2009年第6期52-56,共5页
为了揭示非共沸混合工质在冷凝器内的换热特性,探明非共沸混合工质组分对制冷剂和换热流体间沿程温度的影响,通过建立冷凝器换热模型,对不同沸点差的二元环保型非共沸混合工质进行了理论分析。结果表明:由于非共沸混合工质比焓值与温度... 为了揭示非共沸混合工质在冷凝器内的换热特性,探明非共沸混合工质组分对制冷剂和换热流体间沿程温度的影响,通过建立冷凝器换热模型,对不同沸点差的二元环保型非共沸混合工质进行了理论分析。结果表明:由于非共沸混合工质比焓值与温度的非线性关系,换热流体间的沿程传热温差出现极值点;混合工质中富含低沸点组分时,冷凝器内部存在最小传热温差;反之,存在最大传热温差;混合工质沸点差增加,滑移温度的限制条件之差增大,窄点现象增强。 展开更多
关键词 制冷剂 非共沸 冷凝器 组分
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