Renewable porous biochar and 2 D MXene have attracted significant attention in high-end electromagnetic interference(EMI)shielding fields,due to unique orderly structures and excellent electrical conductivity(r)value....Renewable porous biochar and 2 D MXene have attracted significant attention in high-end electromagnetic interference(EMI)shielding fields,due to unique orderly structures and excellent electrical conductivity(r)value.In this work,the wood-derived porous carbon(WPC)skeleton from natural wood was performed as a template.And excellent conductive and ultra-light 3D MXene aerogel was then constructed to prepare the MXene aerogel/WPC composites,based on highly ordered honeycomb cells inner WPC as a microreactor.Higher carbonization temperature is more conducive to the graphitization degree of natural wood.MXene aerogel/WPC composites achieve the optimal EMI SE value of up to 71.3 d B at density as low as 0.197 g/cm^3.Such wall-like"mortar-brick"structures(WPC skeleton as"mortar"and MXene aerogel as"brick")not only effectively solve the unstable structure problem of MXene aerogel networks,but also greatly prolong the transmission paths of the electromagnetic waves and dissipate the incident electromagnetic waves in the form of heat and electric energy,thereby exhibiting the superior EMI shielding performance.In addition,MXene aerogel/WPC composites also exhibit good anisotropic compressive strength,excellent thermal insulation and flame retardant properties.Such ultra-light,green and efficient multi-functional bio-carbon-based composites have great application potential in the high-end EMI shielding fields of aerospace and national defence industry,etc.展开更多
The main purpose of this paper is to study the feasibility of using wood bottom ash to partially replace natural fine aggregate or crushed gneiss sand in the manufacturing of mortars. The experiment uses wood ash as f...The main purpose of this paper is to study the feasibility of using wood bottom ash to partially replace natural fine aggregate or crushed gneiss sand in the manufacturing of mortars. The experiment uses wood ash as fine aggregates, which passes through 5 mm sieve, in proportions of 5%, 10%, 15%, 20% and 25% by weight to replace partially river sand and crushed gneiss, and the both sand of the same size as the aggregate respectively. Experimental results show that density of mortar and the compressive strength of mortar decrease globally with the increase in wood ash content. At 56 days, and for all replacements with wood ash, compressive strengths values of mortar obtained with the mixture of wood ash and river sand is greater than 20 MPa, which is not the case for mortar made with crushed gneiss and wood ash. Moreover, for 5% of replacement with wood ash, compressive strengths of mortar obtained with the mixture of wood ash and river sand and the mixture of wood ash and crushed gneiss are respectively 37 MPa and 32 MPa at 56 days. These values satisfied the strength requirements. Hence, 5% replacement of crushed gneiss with wood ash is suggested and could be benefit for mortar. In addition, the replacement of sand by wood ash is preferable with river sand which contains fewer fines than crushed gneiss. The compressive strength of mortar with 25% wood ash + river sand could be suitable.展开更多
基金supported by the Foundation of National Natural Science Foundation of China(51973173)Natural Science Basic Research Plan for Distinguished Young Scholars in Shaanxi Province of China(2019JC-11)+2 种基金Space Supporting Fund from China Aerospace Science and Industry Corporation(2019-HT-XG)Foundation of Aeronautics Science Fund(2017ZF53071)the School-enterprise Collaborative Innovation Fund for Graduate Students of Northwestern Polytechnical University(XQ201913)。
文摘Renewable porous biochar and 2 D MXene have attracted significant attention in high-end electromagnetic interference(EMI)shielding fields,due to unique orderly structures and excellent electrical conductivity(r)value.In this work,the wood-derived porous carbon(WPC)skeleton from natural wood was performed as a template.And excellent conductive and ultra-light 3D MXene aerogel was then constructed to prepare the MXene aerogel/WPC composites,based on highly ordered honeycomb cells inner WPC as a microreactor.Higher carbonization temperature is more conducive to the graphitization degree of natural wood.MXene aerogel/WPC composites achieve the optimal EMI SE value of up to 71.3 d B at density as low as 0.197 g/cm^3.Such wall-like"mortar-brick"structures(WPC skeleton as"mortar"and MXene aerogel as"brick")not only effectively solve the unstable structure problem of MXene aerogel networks,but also greatly prolong the transmission paths of the electromagnetic waves and dissipate the incident electromagnetic waves in the form of heat and electric energy,thereby exhibiting the superior EMI shielding performance.In addition,MXene aerogel/WPC composites also exhibit good anisotropic compressive strength,excellent thermal insulation and flame retardant properties.Such ultra-light,green and efficient multi-functional bio-carbon-based composites have great application potential in the high-end EMI shielding fields of aerospace and national defence industry,etc.
文摘The main purpose of this paper is to study the feasibility of using wood bottom ash to partially replace natural fine aggregate or crushed gneiss sand in the manufacturing of mortars. The experiment uses wood ash as fine aggregates, which passes through 5 mm sieve, in proportions of 5%, 10%, 15%, 20% and 25% by weight to replace partially river sand and crushed gneiss, and the both sand of the same size as the aggregate respectively. Experimental results show that density of mortar and the compressive strength of mortar decrease globally with the increase in wood ash content. At 56 days, and for all replacements with wood ash, compressive strengths values of mortar obtained with the mixture of wood ash and river sand is greater than 20 MPa, which is not the case for mortar made with crushed gneiss and wood ash. Moreover, for 5% of replacement with wood ash, compressive strengths of mortar obtained with the mixture of wood ash and river sand and the mixture of wood ash and crushed gneiss are respectively 37 MPa and 32 MPa at 56 days. These values satisfied the strength requirements. Hence, 5% replacement of crushed gneiss with wood ash is suggested and could be benefit for mortar. In addition, the replacement of sand by wood ash is preferable with river sand which contains fewer fines than crushed gneiss. The compressive strength of mortar with 25% wood ash + river sand could be suitable.
