To eliminate thermal stress and cracks in the process of laser cladding, a kind of bioceramic coating with gradient compositional design was prepared on the surface of Ti alloy by using wide-band laser cladding. And e...To eliminate thermal stress and cracks in the process of laser cladding, a kind of bioceramic coating with gradient compositional design was prepared on the surface of Ti alloy by using wide-band laser cladding. And effect of Y2O3 content on gradient bioceramic composite coating was studied. The experimental results indicate that adding rare earth can refine grain. Different rare earth contents affect formation of HA and β-TCP in bioceramic coating. When the content of rare earth ranges from 0.4% to 0.6%, the active extent of rare earth in synthesizing HA and β-TCP is the best, which indicates that “monosodium glutamate” effect of rare earth plays a dominant role. However, when rare earth content is up to 0.8%, the amount of synthesizing HA and β-TCP in coating conversely goes down, which demonstrates that rare earth gradually losts its catalysis in manufacturing HA and β-TCP.展开更多
The gradient bioceramic coating was prepared on the surface of titanium alloy using wide-band laser cladding.The dynamics of gradient bioceramic composite coating containing hydroxyapatite(HA)prepared with mixture of ...The gradient bioceramic coating was prepared on the surface of titanium alloy using wide-band laser cladding.The dynamics of gradient bioceramic composite coating containing hydroxyapatite(HA)prepared with mixture of CaHPO4·2H2O and CaCO3 under the condition of wide-band laser was studied theoretically.The corresponding mathematical model and its numerical solution were presented.The examination experiment showed that HA bioceramic composite coatings can be obtained by appropriately choosing wide-band laser cladding parameters.The microstructure and surface morphology of HA bioceramic coating were observed by SEM and X-ray diffraction.The experimental results showed that the bioceramic coating is composed of HA,β-TCP,CaO,CaTiO3 and TiO2.The surface of bioceramic coating takes coral-shaped structure or short-rod piled structure,which helps osteoblast grow into bioceramic and improves the biocompatibility.展开更多
基金Project supported by Governor's Foundation of Guizhou Province (2004-07)
文摘To eliminate thermal stress and cracks in the process of laser cladding, a kind of bioceramic coating with gradient compositional design was prepared on the surface of Ti alloy by using wide-band laser cladding. And effect of Y2O3 content on gradient bioceramic composite coating was studied. The experimental results indicate that adding rare earth can refine grain. Different rare earth contents affect formation of HA and β-TCP in bioceramic coating. When the content of rare earth ranges from 0.4% to 0.6%, the active extent of rare earth in synthesizing HA and β-TCP is the best, which indicates that “monosodium glutamate” effect of rare earth plays a dominant role. However, when rare earth content is up to 0.8%, the amount of synthesizing HA and β-TCP in coating conversely goes down, which demonstrates that rare earth gradually losts its catalysis in manufacturing HA and β-TCP.
基金Sponsored by Governor′s Foundation of Guizhou Province(2004-10)
文摘The gradient bioceramic coating was prepared on the surface of titanium alloy using wide-band laser cladding.The dynamics of gradient bioceramic composite coating containing hydroxyapatite(HA)prepared with mixture of CaHPO4·2H2O and CaCO3 under the condition of wide-band laser was studied theoretically.The corresponding mathematical model and its numerical solution were presented.The examination experiment showed that HA bioceramic composite coatings can be obtained by appropriately choosing wide-band laser cladding parameters.The microstructure and surface morphology of HA bioceramic coating were observed by SEM and X-ray diffraction.The experimental results showed that the bioceramic coating is composed of HA,β-TCP,CaO,CaTiO3 and TiO2.The surface of bioceramic coating takes coral-shaped structure or short-rod piled structure,which helps osteoblast grow into bioceramic and improves the biocompatibility.