Multilayered Ti-Al based intermetallic sheets were fabricated by sintering alternately layered titanium and aluminum foils.The microstructure and phase formation of the obtained sheets under different sintering condit...Multilayered Ti-Al based intermetallic sheets were fabricated by sintering alternately layered titanium and aluminum foils.The microstructure and phase formation of the obtained sheets under different sintering conditions were evaluated by various techniques.The results reveal that when the sintering temperature is above the melting point of aluminum,the self-propagating high-temperature synthesis reaction occurs between Ti and Al,and forms various phases of Ti-based solid solutions including α-Ti Ti3Al,TiAl,TiAl2 and α-Ti including TiAl3,etc.When the sintering time increased,Ti-based solid solution,TiAl2 and TiAl3 disappeared gradually,and the sheet containing Ti3Al and TiAl phases in a multilayered structure formed finally.A lot of voids were also observed in the sintered structures,which were caused by the melting Al,Kirkendall effect and the difference of molar volumes between reactants and products.The voids were eliminated and a dense sample was obtained by the following hot press.展开更多
An overview of the recent findings about the chemo-hydro-mechanical behaviour of materials used for both geological and engineered barriers in nuclear waste disposal is presented, through some examples about the natur...An overview of the recent findings about the chemo-hydro-mechanical behaviour of materials used for both geological and engineered barriers in nuclear waste disposal is presented, through some examples about the natural Boom Clay （BC） and compacted bentonite-based materials. For the natural BC, it was found that compression index identified from both oedometer and isotropic compression tests is sim- ilar and the compressibility of BC from the Mol site is higher than that of BC from the Essen site： the shear strength of Mol BC is also higher than that of the Essen BC, suggesting a significant effect of carbo- nates content; the thermal volume change is strongly overconsolidation ratio （OCR） dependent-low OCR values promote thermal contraction while high OCR values favour thermal dilation; the volume change behaviour is also strongly time dependent and this time dependent behaviour is governed by the stress level and temperature; the effect of pore-water salinity on the volume change behaviour can be signif- icant when the smectite content is relatively high. For the bentonite-based materials, it was found that thermal contraction also occurs at low OCR values, but this is suction dependent--suction promotes ther- mal dilation. Under constant volume conditions, wetting results in a decrease of hydraulic conductivity, followed by an increase. This is found to be related to changes in macro-pores size-wetting induces a decrease of macro-pores size, followed by an increase due to the aggregates fissuring. The presence of technological voids can increase the hydraulic conductivity but does not influence the swelling pressure.展开更多
The Swedish astrophysicist and Nobel Prize winner Hannes Alfven said： Theories come and go -- the experiment is here forever. Often a theory, which we set up to describe an observed physical phenomenon, suffers from ...The Swedish astrophysicist and Nobel Prize winner Hannes Alfven said： Theories come and go -- the experiment is here forever. Often a theory, which we set up to describe an observed physical phenomenon, suffers from the lack of knowledge of decisive parameters, and therefore at best the theory becomes insufficient. Contrary, the experiment always reveals nature itself, though at prevailing experimental conditions. With essential parameters being out of control and even maybe unidentified, apparently similar experiments may deviate way beyond our expectations. However, these discrepancies offer us a chance to reflect on the character of the unknown parameters. In this way non-concordant experimental results may hold the key to the development of better theories - and to new experiments for the testing of their validity. Cavitation and cavitation nuclei are phenomena of that character.展开更多
The Al-Si coating of ultra-high strength steel has been applied to hot stamping more and more widely, owing to solving the problem of oxidation and decarburization. However, the evolution of Al-Si coating during the h...The Al-Si coating of ultra-high strength steel has been applied to hot stamping more and more widely, owing to solving the problem of oxidation and decarburization. However, the evolution of Al-Si coating during the heating process was rarely studied in the previous study. The tests about the influence of heating parameters, such as heating temperature, heating rates and dwell time, on properties of the Al-Si coating were carried out on the Gleeble-3500 thermal simulator. The properties of the Al-Si coating, for instance, volume fraction of FeAl intermetallics, α-Fe layer as well as porosity and 3D surface topography, were explored in the study. Results showed that more and more Kirkendall voids and cracks appeared in the Al-Si coating when the heating temperature exceeded 600°C. The heating rates almost had no influence on properties of the Al-Si coating when the temperature was equal to or lower than 500°C. The volume fraction of FeAl intermetallics in the coating with dwell time from 3 s to 8 min at 930°C was0, 6.19%, 17.03% and 20.65%, separately. The volume fraction of the α-Fe layer in the coating changed from zero to 31.52%with the prolonged dwell time. The porosity of the coating ranged from 0.51% to 4.98% with the extension of dwell time. The unsmooth degree of the surface of the coating rose gradually with the increasing of heating rates and the extension of dwell time.The 3D surface topography of the coating was determined by the comprehensive effect of atoms diffusion, new formed phases,surface tension and the degree of oxidation of the coating surface. Experiments indicated that rapid heating was not suitable for the coating when the temperature exceeded 500°C. Experiments also demonstrated that enough dwell time was essential to obtain the superior properties of the coating.展开更多
基金Project (2010DFA51650) supported by the Ministry of Science and Technology of China
文摘Multilayered Ti-Al based intermetallic sheets were fabricated by sintering alternately layered titanium and aluminum foils.The microstructure and phase formation of the obtained sheets under different sintering conditions were evaluated by various techniques.The results reveal that when the sintering temperature is above the melting point of aluminum,the self-propagating high-temperature synthesis reaction occurs between Ti and Al,and forms various phases of Ti-based solid solutions including α-Ti Ti3Al,TiAl,TiAl2 and α-Ti including TiAl3,etc.When the sintering time increased,Ti-based solid solution,TiAl2 and TiAl3 disappeared gradually,and the sheet containing Ti3Al and TiAl phases in a multilayered structure formed finally.A lot of voids were also observed in the sintered structures,which were caused by the melting Al,Kirkendall effect and the difference of molar volumes between reactants and products.The voids were eliminated and a dense sample was obtained by the following hot press.
文摘An overview of the recent findings about the chemo-hydro-mechanical behaviour of materials used for both geological and engineered barriers in nuclear waste disposal is presented, through some examples about the natural Boom Clay （BC） and compacted bentonite-based materials. For the natural BC, it was found that compression index identified from both oedometer and isotropic compression tests is sim- ilar and the compressibility of BC from the Mol site is higher than that of BC from the Essen site： the shear strength of Mol BC is also higher than that of the Essen BC, suggesting a significant effect of carbo- nates content; the thermal volume change is strongly overconsolidation ratio （OCR） dependent-low OCR values promote thermal contraction while high OCR values favour thermal dilation; the volume change behaviour is also strongly time dependent and this time dependent behaviour is governed by the stress level and temperature; the effect of pore-water salinity on the volume change behaviour can be signif- icant when the smectite content is relatively high. For the bentonite-based materials, it was found that thermal contraction also occurs at low OCR values, but this is suction dependent--suction promotes ther- mal dilation. Under constant volume conditions, wetting results in a decrease of hydraulic conductivity, followed by an increase. This is found to be related to changes in macro-pores size-wetting induces a decrease of macro-pores size, followed by an increase due to the aggregates fissuring. The presence of technological voids can increase the hydraulic conductivity but does not influence the swelling pressure.
文摘The Swedish astrophysicist and Nobel Prize winner Hannes Alfven said： Theories come and go -- the experiment is here forever. Often a theory, which we set up to describe an observed physical phenomenon, suffers from the lack of knowledge of decisive parameters, and therefore at best the theory becomes insufficient. Contrary, the experiment always reveals nature itself, though at prevailing experimental conditions. With essential parameters being out of control and even maybe unidentified, apparently similar experiments may deviate way beyond our expectations. However, these discrepancies offer us a chance to reflect on the character of the unknown parameters. In this way non-concordant experimental results may hold the key to the development of better theories - and to new experiments for the testing of their validity. Cavitation and cavitation nuclei are phenomena of that character.
基金supported by the National Natural Science Foundation of China(Grant Nos.51275185,51405171,U1564203)
文摘The Al-Si coating of ultra-high strength steel has been applied to hot stamping more and more widely, owing to solving the problem of oxidation and decarburization. However, the evolution of Al-Si coating during the heating process was rarely studied in the previous study. The tests about the influence of heating parameters, such as heating temperature, heating rates and dwell time, on properties of the Al-Si coating were carried out on the Gleeble-3500 thermal simulator. The properties of the Al-Si coating, for instance, volume fraction of FeAl intermetallics, α-Fe layer as well as porosity and 3D surface topography, were explored in the study. Results showed that more and more Kirkendall voids and cracks appeared in the Al-Si coating when the heating temperature exceeded 600°C. The heating rates almost had no influence on properties of the Al-Si coating when the temperature was equal to or lower than 500°C. The volume fraction of FeAl intermetallics in the coating with dwell time from 3 s to 8 min at 930°C was0, 6.19%, 17.03% and 20.65%, separately. The volume fraction of the α-Fe layer in the coating changed from zero to 31.52%with the prolonged dwell time. The porosity of the coating ranged from 0.51% to 4.98% with the extension of dwell time. The unsmooth degree of the surface of the coating rose gradually with the increasing of heating rates and the extension of dwell time.The 3D surface topography of the coating was determined by the comprehensive effect of atoms diffusion, new formed phases,surface tension and the degree of oxidation of the coating surface. Experiments indicated that rapid heating was not suitable for the coating when the temperature exceeded 500°C. Experiments also demonstrated that enough dwell time was essential to obtain the superior properties of the coating.
