Ⅰ. INTRODUCTION The surface-dissociation reaction caused by collisions between the molecules and solid surface is one of the important elementary processes of the heterogeneous catalytic reactions. The relevant theor...Ⅰ. INTRODUCTION The surface-dissociation reaction caused by collisions between the molecules and solid surface is one of the important elementary processes of the heterogeneous catalytic reactions. The relevant theoretical investigations reported in literature used mainly the classical mechanical methods, therefore, they could not expose the quantum effects, for example, the展开更多
基金Project supported by the National Natural Science Foundation of China.
文摘Ⅰ. INTRODUCTION The surface-dissociation reaction caused by collisions between the molecules and solid surface is one of the important elementary processes of the heterogeneous catalytic reactions. The relevant theoretical investigations reported in literature used mainly the classical mechanical methods, therefore, they could not expose the quantum effects, for example, the