The long-term dumping of coal waste piles has caused serious environmental problems. Release of trace elements(including rare earth elements, REEs) from coal spoils gobs was investigated at Yangquan coal mine, Shanx...The long-term dumping of coal waste piles has caused serious environmental problems. Release of trace elements(including rare earth elements, REEs) from coal spoils gobs was investigated at Yangquan coal mine, Shanxi Province, China. X-ray diffraction(XRD) was used to analyze the mineral composition of the coal spoils. The minerals of the coal-spoil samples are mainly kaolinite and quartz, with a minor proportion of pyrite. The batch and column tests were employed to simulate the leaching behavior of trace elements from coal spoils. Elements V, Cr, Zn, As, Pb, and Cd are highly enriched in all coal spoils. The coal spoils also have elevated levels of Ga, Ge, Se, Sn, Hf, and Th. The leachate of coal spoils, fried coal spoils and CSFGM(coal spoils fire gas mineral) samples are acidic, with the p H values ranging between 3.0 and 6.6. The released elements with high concentrations(over 100 μg/L) include Fe, Mn, Co, Ni and Zn, while moderately-released elements are Cu, Se, Mo and As. A high content of heavy metals in batch-test leachate with CSFGM indicates an increased mobility of heavy metals in coal spoil combustion byproduct. Within the first hour washing with the electrolyte solution, a rapid rise of common cations, trace elements, and REEs content, as well as a drop of p H value, in effluent was observed. An increased leaching velocity favors the release of trace elements from coal spoils. In addition, the pulse input of precipitation led to more elements to be released than continuous leaching.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.41120124003 and 41372251)the Specialized Research Fund for the Doctoral Program of Higher Education(No.20130145120014)+1 种基金the Natural Science Foundation of Hubei Province,China(No.2013CFB41)the Opening Fund of State Key Laboratory of Geohazard Prevention and Geoenvironment Protection(Chengdu University of Technology)(No.SKLGP2012K022)
文摘The long-term dumping of coal waste piles has caused serious environmental problems. Release of trace elements(including rare earth elements, REEs) from coal spoils gobs was investigated at Yangquan coal mine, Shanxi Province, China. X-ray diffraction(XRD) was used to analyze the mineral composition of the coal spoils. The minerals of the coal-spoil samples are mainly kaolinite and quartz, with a minor proportion of pyrite. The batch and column tests were employed to simulate the leaching behavior of trace elements from coal spoils. Elements V, Cr, Zn, As, Pb, and Cd are highly enriched in all coal spoils. The coal spoils also have elevated levels of Ga, Ge, Se, Sn, Hf, and Th. The leachate of coal spoils, fried coal spoils and CSFGM(coal spoils fire gas mineral) samples are acidic, with the p H values ranging between 3.0 and 6.6. The released elements with high concentrations(over 100 μg/L) include Fe, Mn, Co, Ni and Zn, while moderately-released elements are Cu, Se, Mo and As. A high content of heavy metals in batch-test leachate with CSFGM indicates an increased mobility of heavy metals in coal spoil combustion byproduct. Within the first hour washing with the electrolyte solution, a rapid rise of common cations, trace elements, and REEs content, as well as a drop of p H value, in effluent was observed. An increased leaching velocity favors the release of trace elements from coal spoils. In addition, the pulse input of precipitation led to more elements to be released than continuous leaching.
基金National Natural Science Foundation of China(40772093)the Program for Science&Technology Innovation Talents in Universities of Henan Province(2010HASTIT007)