The classical thermodynamics reflects the significant relationship between the heat and the temperature. On the basis of the relationships, according to the mathematical derivation, this paper structures the conceptio...The classical thermodynamics reflects the significant relationship between the heat and the temperature. On the basis of the relationships, according to the mathematical derivation, this paper structures the conceptions of generalized heat, generalized thermodynamic temperature, generalized entropy and so on. The series of conceptions in the classical thermodynamics is merely a special case of the generalized thermodynamics. Based on these conceptions of generalized thermodynamics, this paper presents the new expressions of the first law and the second law of thermodynamics. In other words, these expressions are endued with new explanations. The Eq. LZ = kTS given by this paper provides theoretical basis for these new expressions.展开更多
An advanced precooled airbreathing engine with a closed Brayton cycle is a promising solution for high-speed propulsion,of which the Synergetic Air Breathing Rocket Engine(SABRE)is a representative configuration.The p...An advanced precooled airbreathing engine with a closed Brayton cycle is a promising solution for high-speed propulsion,of which the Synergetic Air Breathing Rocket Engine(SABRE)is a representative configuration.The performance of the latest SABRE-4 cycle was analyzed in this paper.Firstly,a relatively complete engine performance model that considers the characteristics of turbomachinery and heat exchangers was developed.Then,Sobol’global sensitivity analysis of key performance parameters was carried out to identify the most influential design variables.Optimal specific impulses under different target specific thrusts were obtained by particle swarm optimization,of which the thermodynamic parameters corresponding to a specific thrust of 1.12 kN·s·kg^(-1)and a specific impulse of 3163 s were chosen as the design values.Four different control laws were analyzed in contrast,and the charge control method had the strongest ability of thrust regulation as well as maintaining a favorable specific impulse performance.Finally,working characteristics under the charge control and over a typical flight envelope were calculated,in which the average value of the maximum specific impulse was as high as 5315 s.This study would help to deepen the understanding of SABRE-4 thermodynamic characteristics and other precooled airbreathing engine cycles with similar layouts.展开更多
Entropy function is used to demonstrate the Carnot efficiency, even if it is not always easy to understand its bases: the reversible movement or the reversible heat transfer. Here, it is proposed to demonstrate the Ca...Entropy function is used to demonstrate the Carnot efficiency, even if it is not always easy to understand its bases: the reversible movement or the reversible heat transfer. Here, it is proposed to demonstrate the Carnot efficiency “without” using the Entropy function. For this, it is necessary to enhance two concepts: heat transfer based on the source temperature and work transfer based on external pressure. This is achieved through 1) a balance exchanged heat, based on the source temperature and the system temperature, and 2) a balance exchanged work, based on the external pressure and the internal pressure. With these enhanced concepts, Laplace function and Carnot efficiency can be demonstrated without using the Entropy function (S). This is only a new formalism. Usual thermodynamics results are not changed. This new formalism can help to get a better description of realistic phenomena, like the efficiency of a realistic cycle.展开更多
The statistical counting method for the computer simulation of the thermodynamic quantities of polymer solution has been reviewed. The calculating results for a single athermal chain confirm the theory of the renorma...The statistical counting method for the computer simulation of the thermodynamic quantities of polymer solution has been reviewed. The calculating results for a single athermal chain confirm the theory of the renormalization group. The results for the athermal solution are consistent with the scaling law of the osmotic pressure with the exponent 2.25. The results for a single chain with the segmental interaction are in a good agreement with the exact results obtained by the direct counting method. The results for the polymer solution show us that the Flory-Huggins parameter is strongly dependent on both the polymer concentration and the interaction energy between segments. (Author abstract) 15 Refs.展开更多
A novel experiment was designed. Experimental results gave a surprising phenomenon. Homogeneous particles in a suspended solution spontaneously concentrated.
文摘The classical thermodynamics reflects the significant relationship between the heat and the temperature. On the basis of the relationships, according to the mathematical derivation, this paper structures the conceptions of generalized heat, generalized thermodynamic temperature, generalized entropy and so on. The series of conceptions in the classical thermodynamics is merely a special case of the generalized thermodynamics. Based on these conceptions of generalized thermodynamics, this paper presents the new expressions of the first law and the second law of thermodynamics. In other words, these expressions are endued with new explanations. The Eq. LZ = kTS given by this paper provides theoretical basis for these new expressions.
基金supported by the Project of National Key Laboratory of Science and Technology on Aero-engine and Aerothermodynamics at Beihang University,China(No.2022-JCJQ-LB-062-0204).
文摘An advanced precooled airbreathing engine with a closed Brayton cycle is a promising solution for high-speed propulsion,of which the Synergetic Air Breathing Rocket Engine(SABRE)is a representative configuration.The performance of the latest SABRE-4 cycle was analyzed in this paper.Firstly,a relatively complete engine performance model that considers the characteristics of turbomachinery and heat exchangers was developed.Then,Sobol’global sensitivity analysis of key performance parameters was carried out to identify the most influential design variables.Optimal specific impulses under different target specific thrusts were obtained by particle swarm optimization,of which the thermodynamic parameters corresponding to a specific thrust of 1.12 kN·s·kg^(-1)and a specific impulse of 3163 s were chosen as the design values.Four different control laws were analyzed in contrast,and the charge control method had the strongest ability of thrust regulation as well as maintaining a favorable specific impulse performance.Finally,working characteristics under the charge control and over a typical flight envelope were calculated,in which the average value of the maximum specific impulse was as high as 5315 s.This study would help to deepen the understanding of SABRE-4 thermodynamic characteristics and other precooled airbreathing engine cycles with similar layouts.
文摘Entropy function is used to demonstrate the Carnot efficiency, even if it is not always easy to understand its bases: the reversible movement or the reversible heat transfer. Here, it is proposed to demonstrate the Carnot efficiency “without” using the Entropy function. For this, it is necessary to enhance two concepts: heat transfer based on the source temperature and work transfer based on external pressure. This is achieved through 1) a balance exchanged heat, based on the source temperature and the system temperature, and 2) a balance exchanged work, based on the external pressure and the internal pressure. With these enhanced concepts, Laplace function and Carnot efficiency can be demonstrated without using the Entropy function (S). This is only a new formalism. Usual thermodynamics results are not changed. This new formalism can help to get a better description of realistic phenomena, like the efficiency of a realistic cycle.
基金This work was supported by the National Key Project for Fundamental Research"Macromolecular Condensed State",The State Science and Technology Commission of China
文摘The statistical counting method for the computer simulation of the thermodynamic quantities of polymer solution has been reviewed. The calculating results for a single athermal chain confirm the theory of the renormalization group. The results for the athermal solution are consistent with the scaling law of the osmotic pressure with the exponent 2.25. The results for a single chain with the segmental interaction are in a good agreement with the exact results obtained by the direct counting method. The results for the polymer solution show us that the Flory-Huggins parameter is strongly dependent on both the polymer concentration and the interaction energy between segments. (Author abstract) 15 Refs.
文摘A novel experiment was designed. Experimental results gave a surprising phenomenon. Homogeneous particles in a suspended solution spontaneously concentrated.
