利用叔丁醇作为共溶剂可使棕榈油、甲醇和催化剂形成均相体系,用于酯交换反应制备生物柴油,可以缩短反应时间。实验以棕榈油为原料,氢氧化钠为催化剂,在带夹套的玻璃反应器内进行反应。考察了共溶剂质量分数、催化剂质量分数、反应温度...利用叔丁醇作为共溶剂可使棕榈油、甲醇和催化剂形成均相体系,用于酯交换反应制备生物柴油,可以缩短反应时间。实验以棕榈油为原料,氢氧化钠为催化剂,在带夹套的玻璃反应器内进行反应。考察了共溶剂质量分数、催化剂质量分数、反应温度、醇油摩尔比等因素对生物柴油产率的影响,获得了最佳反应条件。实验结果表明,当叔丁醇质量为棕榈油质量的11.6%,催化剂质量为油质量的1.0%,反应温度为60℃,醇油摩尔比为6∶1时,反应2 m in后生物柴油产率达到了90%。展开更多
The catalytic performance of Al-MCM-41 containing 5-35 wt% H3PO4 was studied for the vapor phase alkylation of phenol with tert-butyl alcohol(TBA) from 383 to 493 K.4-Tert-butyl phenol was produced as the main product...The catalytic performance of Al-MCM-41 containing 5-35 wt% H3PO4 was studied for the vapor phase alkylation of phenol with tert-butyl alcohol(TBA) from 383 to 493 K.4-Tert-butyl phenol was produced as the main product with moderate selectivity.The product distribution depends on the reaction temperature,number of acid sites,and the Brnsted to Lewis sites ratios.A lower molar ratio of reactants(TBA/phenol = 2) and a higher space velocity facilitated the production of 4-tert-butyl phenol.The influence of various parameters such as temperature,reactant feed molar ratio,feed rate,and time on stream were investigated for conversion yield and product selectivity.展开更多
文摘利用叔丁醇作为共溶剂可使棕榈油、甲醇和催化剂形成均相体系,用于酯交换反应制备生物柴油,可以缩短反应时间。实验以棕榈油为原料,氢氧化钠为催化剂,在带夹套的玻璃反应器内进行反应。考察了共溶剂质量分数、催化剂质量分数、反应温度、醇油摩尔比等因素对生物柴油产率的影响,获得了最佳反应条件。实验结果表明,当叔丁醇质量为棕榈油质量的11.6%,催化剂质量为油质量的1.0%,反应温度为60℃,醇油摩尔比为6∶1时,反应2 m in后生物柴油产率达到了90%。
基金Research Council of Isfahan University of Technology
文摘The catalytic performance of Al-MCM-41 containing 5-35 wt% H3PO4 was studied for the vapor phase alkylation of phenol with tert-butyl alcohol(TBA) from 383 to 493 K.4-Tert-butyl phenol was produced as the main product with moderate selectivity.The product distribution depends on the reaction temperature,number of acid sites,and the Brnsted to Lewis sites ratios.A lower molar ratio of reactants(TBA/phenol = 2) and a higher space velocity facilitated the production of 4-tert-butyl phenol.The influence of various parameters such as temperature,reactant feed molar ratio,feed rate,and time on stream were investigated for conversion yield and product selectivity.
