The climate change in China shows a considerable similarity to the global change, though there still exist some significant differences between them. In the context of the global warming, the annual mean surface air t...The climate change in China shows a considerable similarity to the global change, though there still exist some significant differences between them. In the context of the global warming, the annual mean surface air temperature in the country as a whole has significantly increased for the past 50 years and 100 years, with the range of temperature increase slightly greater than that in the globe. The change in precipitation trends for the last 50 and 100 years was not significant, but since 1956 it has assumed a weak increasing trend. The frequency and intensity of main extreme weather and climate events have also undergone a significant change. The researches show that the atmospheric CO2 concentration in China has continuously increased and the sum of positive radiative forcings produced by greenhouse gases is probably responsible for the country-wide climate warming for the past 100 years, especially for the past 50 years. The projections of climate change for the 21st century using global and regional climate models indicate that, in the future 20-100 years, the surface air temperature will continue to increase and the annual precipitation also has an increasing trend for most parts of the country.展开更多
利用中国区域550个站点逐日地面气温及降水资料,评估了参与政府间气候变化专门委员会第四次报告(the fourth assessment report of the intergovernmental panel on climate change,IPCCAR4)的13个新一代全球气候系统模式及多模式集合...利用中国区域550个站点逐日地面气温及降水资料,评估了参与政府间气候变化专门委员会第四次报告(the fourth assessment report of the intergovernmental panel on climate change,IPCCAR4)的13个新一代全球气候系统模式及多模式集合对中国近40 a(1961—2000年)地面气温和降水的模拟能力,结果表明:最新全球模式对中国地区地面气温年变化及空间分布的模拟结果均较好,但在整个模拟区域地面气温模拟值系统性偏低,东部地区模拟效果好于中西部;对于降水,大部分模式能模拟出中国降水的年变化及空间分布特征,但模拟的区域性差别较大,多数模式对中国东部季风区夏季雨带北抬的过程有一定的模拟能力,但模拟雨带位置偏北。新一代全球模式能模拟出温度的线性变化趋势,但对温度及降水的年际变率模拟能力较低。比较多种评估指标得出,模式集合对温度的模拟效果最好,模式UKMO-HadCM3对降水的模拟效果最好。展开更多
Fourier-transform infrared（FT-IR） spectroscopic experiments were carried out during phosphate adsorption on highly crystalline gibbsite, poorly crystalline 2-line-ferrihydrite and amorphous iron–aluminum–hydroxide...Fourier-transform infrared（FT-IR） spectroscopic experiments were carried out during phosphate adsorption on highly crystalline gibbsite, poorly crystalline 2-line-ferrihydrite and amorphous iron–aluminum–hydroxide mixtures in the molar ratio 1：0, 10：1, 5：1, 1：1, 1：5, 1：10 and 0：1. The OH stretching vibrational bands were utilized to analyze changes in structural and surface OH groups during adsorption, because the position of characteristic P／O vibrational bands can shift depending on reaction conditions, pH or adsorbed phosphate content.Adsorption and desorption kinetics were studied at pH6 and different initial phosphate concentrations to achieve varying phosphate coverage on the mineral surfaces. For gibbsite the formation of AlHPO4 and Al2HPO4 can be assumed, while for ferrihydrite, a FeHPO4 or Fe2PO4 complex and the precipitation of FePO4 with longer equilibration time were proposed.Fe2HPO4 or a Fe2PO4 surface complex was deduced for Fe-hydroxides, an AlH2PO4 surface complex was identified for Al-hydroxide, and both displayed either hydrogen bonds to neighboring hydroxyl groups or hydrogen bonds to outer-sphere complexes. Fe：Al-hydroxide mixtures with high Al ratios showed a low phosphate desorption rate, while ferrihydrite and the Fe：Al-hydroxide mixtures with high Fe ratios had almost negligible desorption rates. It was concluded that within the weakly associated amorphous FeO（OH） materials, FePO4 precipitated, which was bound by outer-sphere hydrogen bonds. With high Al ratios, desorption increased, which indicated weaker phosphate binding of both inner-sphere and outer-sphere complexes and hence, either no or minor quantities of precipitate. Ferrihydrite showed a more rigid structure and a lower extent of precipitation compared to amorphous Fe-hydroxide.展开更多
文摘The climate change in China shows a considerable similarity to the global change, though there still exist some significant differences between them. In the context of the global warming, the annual mean surface air temperature in the country as a whole has significantly increased for the past 50 years and 100 years, with the range of temperature increase slightly greater than that in the globe. The change in precipitation trends for the last 50 and 100 years was not significant, but since 1956 it has assumed a weak increasing trend. The frequency and intensity of main extreme weather and climate events have also undergone a significant change. The researches show that the atmospheric CO2 concentration in China has continuously increased and the sum of positive radiative forcings produced by greenhouse gases is probably responsible for the country-wide climate warming for the past 100 years, especially for the past 50 years. The projections of climate change for the 21st century using global and regional climate models indicate that, in the future 20-100 years, the surface air temperature will continue to increase and the annual precipitation also has an increasing trend for most parts of the country.
文摘利用中国区域550个站点逐日地面气温及降水资料,评估了参与政府间气候变化专门委员会第四次报告(the fourth assessment report of the intergovernmental panel on climate change,IPCCAR4)的13个新一代全球气候系统模式及多模式集合对中国近40 a(1961—2000年)地面气温和降水的模拟能力,结果表明:最新全球模式对中国地区地面气温年变化及空间分布的模拟结果均较好,但在整个模拟区域地面气温模拟值系统性偏低,东部地区模拟效果好于中西部;对于降水,大部分模式能模拟出中国降水的年变化及空间分布特征,但模拟的区域性差别较大,多数模式对中国东部季风区夏季雨带北抬的过程有一定的模拟能力,但模拟雨带位置偏北。新一代全球模式能模拟出温度的线性变化趋势,但对温度及降水的年际变率模拟能力较低。比较多种评估指标得出,模式集合对温度的模拟效果最好,模式UKMO-HadCM3对降水的模拟效果最好。
基金the German Federal Ministry of Education and Research (BMBF) for funding the BonaR es project InnoS oil Phos (No. 031A558)
文摘Fourier-transform infrared（FT-IR） spectroscopic experiments were carried out during phosphate adsorption on highly crystalline gibbsite, poorly crystalline 2-line-ferrihydrite and amorphous iron–aluminum–hydroxide mixtures in the molar ratio 1：0, 10：1, 5：1, 1：1, 1：5, 1：10 and 0：1. The OH stretching vibrational bands were utilized to analyze changes in structural and surface OH groups during adsorption, because the position of characteristic P／O vibrational bands can shift depending on reaction conditions, pH or adsorbed phosphate content.Adsorption and desorption kinetics were studied at pH6 and different initial phosphate concentrations to achieve varying phosphate coverage on the mineral surfaces. For gibbsite the formation of AlHPO4 and Al2HPO4 can be assumed, while for ferrihydrite, a FeHPO4 or Fe2PO4 complex and the precipitation of FePO4 with longer equilibration time were proposed.Fe2HPO4 or a Fe2PO4 surface complex was deduced for Fe-hydroxides, an AlH2PO4 surface complex was identified for Al-hydroxide, and both displayed either hydrogen bonds to neighboring hydroxyl groups or hydrogen bonds to outer-sphere complexes. Fe：Al-hydroxide mixtures with high Al ratios showed a low phosphate desorption rate, while ferrihydrite and the Fe：Al-hydroxide mixtures with high Fe ratios had almost negligible desorption rates. It was concluded that within the weakly associated amorphous FeO（OH） materials, FePO4 precipitated, which was bound by outer-sphere hydrogen bonds. With high Al ratios, desorption increased, which indicated weaker phosphate binding of both inner-sphere and outer-sphere complexes and hence, either no or minor quantities of precipitate. Ferrihydrite showed a more rigid structure and a lower extent of precipitation compared to amorphous Fe-hydroxide.
