The Oyu Tolgoi cluster of seven porphyry Cu-Au-Mo deposits in southern Mongolia,define a narrow,linear,12 km long,almost continuously mineralised trend,which contains in excess of 42 Mt of Cu and1850 t of Au,and is am...The Oyu Tolgoi cluster of seven porphyry Cu-Au-Mo deposits in southern Mongolia,define a narrow,linear,12 km long,almost continuously mineralised trend,which contains in excess of 42 Mt of Cu and1850 t of Au,and is among the largest high grade porphyry Cu-Au deposits in the world.These deposits lie within the Gurvansayhan island-arc terrane,a fault bounded segment of the broader Silurian to Carboniferous Kazakh-Mongol arc,located towards the southern margin of the Central Asian Orogenic Belt,a collage of magmatic arcs that were periodically active from the late Neoproterozoic to PermoTriassic,extending from the Urals Mountains to the Pacific Ocean.Mineralisation at Oyu Tolgoi is associated with multiple,overlapping,intrusions of late Devonian（～372 to 370 Ma） quartzmonzodiorite intruding Devonian（or older） juvenile,probably intra-oceanic arc-related,basaltic lavas and lesser volcaniclastic rocks,unconformably overlain by late Devonian（～370 Ma） basaltic to dacitic pyroclastic and volcano sedimentary rocks.These quartz-monzodiorite intrusions range from earlymineral porphyritic dykes,to larger,linear,syn-,late- and post-mineral dykes and stocks.Ore was deposited within syn-mineral quartz-monzodiorites,but is dominantly hosted by augite basalts and to a lesser degree by overlying dacitic pyroclastic rocks.Following ore deposition,an allochthonous plate of older Devonian（or pre-Devonian） rocks was overthrust and a post-ore biotite granodiorite intruded at～365 Ma.Mineralisation is characterised by varying,telescoped stages of intrusion and alteration.Early A-type quartz veined dykes were followed by Cu-Au mineralisation associated with potassic alteration,mainly K-feldspar in quartz-monzodiorite and biotite-magnetite in basaltic hosts.Downward reflux of cooled,late-magmatic hydrothermal fluid resulted in intense quartz-sericite retrograde alteration in the upper parts of the main syn-mineral intrusions,and an equivalent chlorite-muscovite/illite-hematite assemblage in basaltic host rocks.Uplift,fa展开更多
Studies on the high temperature creep and fracture behaviours in air or in SO_2 contaminated environment for the Fe-base superalloy GH302 with flat or zigzag grain boundaries(GB) and the Ni-base superalloy Rene 80 wer...Studies on the high temperature creep and fracture behaviours in air or in SO_2 contaminated environment for the Fe-base superalloy GH302 with flat or zigzag grain boundaries(GB) and the Ni-base superalloy Rene 80 were carried out.Although the creep rupture properties of the GH302 with zigzag GB was remarkably superior to that of flat GB in air,the properties of both droped dramatically in 10% SO_2-air environment,the creep rupture properties of the directional solidified Rene 80 were much better than that of the conventionally cast alloy in air,and also kept the same property in SO_2 contaminated environment as in air.Owing to the interaction between creep and sulphidation,the failure mechanism relates to the formation of molten Ni-Ni-3S_2 eutectic along GB,led to the premature failure of the alloy.展开更多
Resistive switching Ag/Ag2S nanoclusters were formed by sulphidation of melting-dispersed thin and continuous Ag films. The morphology, structure and electrical properties of the prepared clusters were characterized b...Resistive switching Ag/Ag2S nanoclusters were formed by sulphidation of melting-dispersed thin and continuous Ag films. The morphology, structure and electrical properties of the prepared clusters were characterized by scanning (SEM), transmitting electron (TEM), scanning resistance microscopes (SRM) and Raman scattering. Hysteretic resistive switching behavior was observed in the samples that were studied with ON/OFF switching voltage equal to 8 - 10 V respectively. Simple empirical numerical simulation model, based on Deal-Grove model assumptions and mechanisms, for silver nanoclusters sulphidation process, was proposed.展开更多
The corrosion of alloys based on Fe,Co and Ni containing 15 and 30 wt-% Nb was studied at 700℃ in H_2-H_2S mixtures providing 10^(-8) atm S_2.The Fe and Co-based alloys formed duplex scales with an outer layer of pur...The corrosion of alloys based on Fe,Co and Ni containing 15 and 30 wt-% Nb was studied at 700℃ in H_2-H_2S mixtures providing 10^(-8) atm S_2.The Fe and Co-based alloys formed duplex scales with an outer layer of pure base-metal sulphide and an inner layer containing both metals.The Nb addi- tions were not able to produce exclusive Nb sulphidation but yielded a significant decrease of the corrosion rates for both types of alloys with respect to the pure metals even though they were still much higher than that of pure Nb.The Ni-base alloys corroded rapidly forming a single complex scale layer,mainly due to the appearance of a liquid Ni-S solution.展开更多
According to the working condition of high temperature oxidation and sulphidation corrosion of the ZG35Cr24Ni7SiN heat resisting stainless steel used for reducing retort in magnesium refining, and the practical situa...According to the working condition of high temperature oxidation and sulphidation corrosion of the ZG35Cr24Ni7SiN heat resisting stainless steel used for reducing retort in magnesium refining, and the practical situation which the weld metal between the body and cover of reducing retort must possess resisting high temperature oxidation and corrosion, a kind of RM 1 type coated electrode for reducing retorts in magnesium refining with special alloying system and excellent usability has been developed. The RM 1 coated electrode is made of H0Cr21Ni10 wire core and is alloyed chromium and nickel simultaneously through coating material and wire core and some rare earth oxides are added in coating material. The electrode has been verified to be satisfied the operation requirements of practical production.展开更多
文摘The Oyu Tolgoi cluster of seven porphyry Cu-Au-Mo deposits in southern Mongolia,define a narrow,linear,12 km long,almost continuously mineralised trend,which contains in excess of 42 Mt of Cu and1850 t of Au,and is among the largest high grade porphyry Cu-Au deposits in the world.These deposits lie within the Gurvansayhan island-arc terrane,a fault bounded segment of the broader Silurian to Carboniferous Kazakh-Mongol arc,located towards the southern margin of the Central Asian Orogenic Belt,a collage of magmatic arcs that were periodically active from the late Neoproterozoic to PermoTriassic,extending from the Urals Mountains to the Pacific Ocean.Mineralisation at Oyu Tolgoi is associated with multiple,overlapping,intrusions of late Devonian（～372 to 370 Ma） quartzmonzodiorite intruding Devonian（or older） juvenile,probably intra-oceanic arc-related,basaltic lavas and lesser volcaniclastic rocks,unconformably overlain by late Devonian（～370 Ma） basaltic to dacitic pyroclastic and volcano sedimentary rocks.These quartz-monzodiorite intrusions range from earlymineral porphyritic dykes,to larger,linear,syn-,late- and post-mineral dykes and stocks.Ore was deposited within syn-mineral quartz-monzodiorites,but is dominantly hosted by augite basalts and to a lesser degree by overlying dacitic pyroclastic rocks.Following ore deposition,an allochthonous plate of older Devonian（or pre-Devonian） rocks was overthrust and a post-ore biotite granodiorite intruded at～365 Ma.Mineralisation is characterised by varying,telescoped stages of intrusion and alteration.Early A-type quartz veined dykes were followed by Cu-Au mineralisation associated with potassic alteration,mainly K-feldspar in quartz-monzodiorite and biotite-magnetite in basaltic hosts.Downward reflux of cooled,late-magmatic hydrothermal fluid resulted in intense quartz-sericite retrograde alteration in the upper parts of the main syn-mineral intrusions,and an equivalent chlorite-muscovite/illite-hematite assemblage in basaltic host rocks.Uplift,fa
文摘Studies on the high temperature creep and fracture behaviours in air or in SO_2 contaminated environment for the Fe-base superalloy GH302 with flat or zigzag grain boundaries(GB) and the Ni-base superalloy Rene 80 were carried out.Although the creep rupture properties of the GH302 with zigzag GB was remarkably superior to that of flat GB in air,the properties of both droped dramatically in 10% SO_2-air environment,the creep rupture properties of the directional solidified Rene 80 were much better than that of the conventionally cast alloy in air,and also kept the same property in SO_2 contaminated environment as in air.Owing to the interaction between creep and sulphidation,the failure mechanism relates to the formation of molten Ni-Ni-3S_2 eutectic along GB,led to the premature failure of the alloy.
文摘Resistive switching Ag/Ag2S nanoclusters were formed by sulphidation of melting-dispersed thin and continuous Ag films. The morphology, structure and electrical properties of the prepared clusters were characterized by scanning (SEM), transmitting electron (TEM), scanning resistance microscopes (SRM) and Raman scattering. Hysteretic resistive switching behavior was observed in the samples that were studied with ON/OFF switching voltage equal to 8 - 10 V respectively. Simple empirical numerical simulation model, based on Deal-Grove model assumptions and mechanisms, for silver nanoclusters sulphidation process, was proposed.
文摘The corrosion of alloys based on Fe,Co and Ni containing 15 and 30 wt-% Nb was studied at 700℃ in H_2-H_2S mixtures providing 10^(-8) atm S_2.The Fe and Co-based alloys formed duplex scales with an outer layer of pure base-metal sulphide and an inner layer containing both metals.The Nb addi- tions were not able to produce exclusive Nb sulphidation but yielded a significant decrease of the corrosion rates for both types of alloys with respect to the pure metals even though they were still much higher than that of pure Nb.The Ni-base alloys corroded rapidly forming a single complex scale layer,mainly due to the appearance of a liquid Ni-S solution.
文摘According to the working condition of high temperature oxidation and sulphidation corrosion of the ZG35Cr24Ni7SiN heat resisting stainless steel used for reducing retort in magnesium refining, and the practical situation which the weld metal between the body and cover of reducing retort must possess resisting high temperature oxidation and corrosion, a kind of RM 1 type coated electrode for reducing retorts in magnesium refining with special alloying system and excellent usability has been developed. The RM 1 coated electrode is made of H0Cr21Ni10 wire core and is alloyed chromium and nickel simultaneously through coating material and wire core and some rare earth oxides are added in coating material. The electrode has been verified to be satisfied the operation requirements of practical production.
