Four classes of core-expanded naphthalene diimides （la, lb, 2a, 2b, 3 and 4） that bear different elec- tron-deficient sulfur heterocycles were designed and synthesized. The solution-processed thin films of la, 2a, 3...Four classes of core-expanded naphthalene diimides （la, lb, 2a, 2b, 3 and 4） that bear different elec- tron-deficient sulfur heterocycles were designed and synthesized. The solution-processed thin films of la, 2a, 3 and 4 operated well in air as n-channel organic transistors with electron mobility ranging from MO 6 to 0.14 cm2/Vs, depending on the different conjugated backbones. The thin film microstructure studies were also carried out to un- derstand the variations of the electron mobility for thin films of la, 2a, 3 and 4.展开更多
The aim of this study is to investigate the possible use of a 1,2-dimethylimidazolium ionic liquid,2,2-bis（（1,2-dimethylimidazolium）methyl）propane-1,3-diol hexafluorophosphate（1）,as an adsorbent to selectively r...The aim of this study is to investigate the possible use of a 1,2-dimethylimidazolium ionic liquid,2,2-bis（（1,2-dimethylimidazolium）methyl）propane-1,3-diol hexafluorophosphate（1）,as an adsorbent to selectively remove aromatic heterocyclic sulfur compounds from model fuels.The result indicates that adsorbent 1 is insoluble in model fuels.The spent IL saturated sulfur compounds could be regenerated by a water dilution process.The influence of extraction time or temperature as well as the molar ratio of 1 to aromatic heterocyclic sulfur compound was also studied.展开更多
基金The present research was financially supported by National Natural Science Foundation of China，the Ministry of Science and Technology，the Chinese Academy of Sciences
文摘Four classes of core-expanded naphthalene diimides （la, lb, 2a, 2b, 3 and 4） that bear different elec- tron-deficient sulfur heterocycles were designed and synthesized. The solution-processed thin films of la, 2a, 3 and 4 operated well in air as n-channel organic transistors with electron mobility ranging from MO 6 to 0.14 cm2/Vs, depending on the different conjugated backbones. The thin film microstructure studies were also carried out to un- derstand the variations of the electron mobility for thin films of la, 2a, 3 and 4.
基金National Key Technology R and D Program (No.2011BAE06B05-4)China Postdoctoral Science Foundation (No.20070410169) for financial support
文摘The aim of this study is to investigate the possible use of a 1,2-dimethylimidazolium ionic liquid,2,2-bis（（1,2-dimethylimidazolium）methyl）propane-1,3-diol hexafluorophosphate（1）,as an adsorbent to selectively remove aromatic heterocyclic sulfur compounds from model fuels.The result indicates that adsorbent 1 is insoluble in model fuels.The spent IL saturated sulfur compounds could be regenerated by a water dilution process.The influence of extraction time or temperature as well as the molar ratio of 1 to aromatic heterocyclic sulfur compound was also studied.
