In the previous papers, we reported the structural elucidation of stellarins A-E, five new cyclopeptides from the fresh roots of Stellaria yunnanensis Franch. Further chemical study on this plant led to the isolation ...In the previous papers, we reported the structural elucidation of stellarins A-E, five new cyclopeptides from the fresh roots of Stellaria yunnanensis Franch. Further chemical study on this plant led to the isolation of two other new cyclopeptide named stellarins F(1) and G(2). By a combination of 2D-NMR, enzymatic degradation and FABMS, their structures were established to by cyclo(Gly-Ala-Gly-Ser-Pro-Trp-Phe-Pro) and cyclo(Gly-Ala-Tyr-Leu-Ala), respectively.展开更多
基金Project supproted by grants from Laboratory of Phytochemistry,Kunming Institute of Botany,Chinese Academy of Sciences and State Key Laboratory of Bio-Organic Chemistry & Natural Products,Chinese Academy of Sciences.
文摘In the previous papers, we reported the structural elucidation of stellarins A-E, five new cyclopeptides from the fresh roots of Stellaria yunnanensis Franch. Further chemical study on this plant led to the isolation of two other new cyclopeptide named stellarins F(1) and G(2). By a combination of 2D-NMR, enzymatic degradation and FABMS, their structures were established to by cyclo(Gly-Ala-Gly-Ser-Pro-Trp-Phe-Pro) and cyclo(Gly-Ala-Tyr-Leu-Ala), respectively.
