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喷雾热解法制备球形YAG∶Ce^(3+)荧光粉研究 被引量:26
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作者 戚发鑫 王海波 朱宪忠 《中国稀土学报》 CAS CSCD 北大核心 2005年第5期568-571,共4页
采用喷雾热解法制备了无团聚的球形YAG∶Ce3+荧光粉。考察了前驱体溶液浓度、载气流速、热解温度对实验结果的影响。当溶液浓度从0.05 mol.L-1增加至0.8 mol.L-1时,所制备的前驱体粒子的平均粒径也从0.60增加至1.50μm,前驱体产量随着... 采用喷雾热解法制备了无团聚的球形YAG∶Ce3+荧光粉。考察了前驱体溶液浓度、载气流速、热解温度对实验结果的影响。当溶液浓度从0.05 mol.L-1增加至0.8 mol.L-1时,所制备的前驱体粒子的平均粒径也从0.60增加至1.50μm,前驱体产量随着前驱体溶液的浓度增加呈现先上升后下降的趋势。提高载气流速可以增加前驱体的产量。当热解温度大于800℃时,得到的粒子呈现实心球体。通过比较喷雾热解法与固相煅烧法所制备的荧光粉,喷雾热解法制备的荧光粉具有发光强度高、形貌好、粒径分布窄等优点。 展开更多
关键词 喷雾热解法 钇铝石榴石 白光LED 球形荧光粉 稀土
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Spherical YAG∶Ce^(3+) Phosphor Particles Prepared by Spray Pyrolysis 被引量:4
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作者 戚发鑫 王海波 朱宪忠 《Journal of Rare Earths》 SCIE EI CAS CSCD 2005年第4期397-400,共4页
Spherical YAG:Ce^3+ phosphor particles with narrow size distribution were prepared by spray pyrolysis. The effects of the concentration of solution, the flow rate of cartier gas and the annexing temperature on the p... Spherical YAG:Ce^3+ phosphor particles with narrow size distribution were prepared by spray pyrolysis. The effects of the concentration of solution, the flow rate of cartier gas and the annexing temperature on the phosphor morphology were studied. The productivity of precursor particles shows a trend of drop after rising with the increase of concentration Raising the flow rate of nitrogen can improve the productivity of the precursor particles. Phosphor prepared by spray pyrolysis has obviously higher emission intensity than that synthesized by solid state reaction, spray pyrolysis makes Ce^3+ ions well distributed in the crystal lattice as the luminescent centers, and phosphor particles have regular sphericity and narrow size distribution. 展开更多
关键词 spray pyrolysis YAG white-LED spherical phosphor particles rare earths
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