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Cd_(1-x)Zn_xTe晶体退火条件的选择及Zn压对退火晶体质量的影响 被引量:4
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作者 李宇杰 张晓娜 介万奇 《物理学报》 SCIE EI CAS CSCD 北大核心 2001年第12期2327-2334,共8页
采用传统Bridgman方法和加入acceleratedcruciblerotationtechnique的Bridgman(缩写为ACRT B)方法生长的Cd1 -xZnxTe(x=0 .0 4)晶体中存在有点缺陷、位错、杂质和Te沉淀等缺陷 .为了减少甚至消除这些缺陷 ,必须将生长后的CdZnTe晶片在C... 采用传统Bridgman方法和加入acceleratedcruciblerotationtechnique的Bridgman(缩写为ACRT B)方法生长的Cd1 -xZnxTe(x=0 .0 4)晶体中存在有点缺陷、位错、杂质和Te沉淀等缺陷 .为了减少甚至消除这些缺陷 ,必须将生长后的CdZnTe晶片在Cd气氛下退火 .从Cd -Te和Cd0 .96 Zn0 .0 4Te的P T相图出发 ,详细讨论了CdZnTe晶体的气 固平衡条件 ,并以此为依据选择退火条件 ,对ACRT -B法生长的Cd0 .96 Zn0 .0 4Te晶体进行了退火实验研究 .实验结果表明 ,气氛中的Zn压在一定程度内高于平衡压力有利于晶体中多余Te向晶体表面扩散 ,即有利于消除Te沉淀 .但过高的Zn压会使晶体表面成分偏离原始的化学配比 .此时 ,晶体表面与气氛强烈的原子交换 ,将造成严重的表面损伤 ,形成一层结晶质量很差的表面层 .同时 ,Zn原子向晶内的扩散 ,抑制了退火过程中晶内杂质向晶体表面的扩散 .因此 ,在较低的Zn压下退火 (但仍处于气 固平衡范围内 ) ,能排除晶内杂质 .通过仔细研究不同条件下退火后晶片的结晶质量和断面成分分布 ,可以认为CdZnTe晶体的退火可分为去沉淀相退火、去杂质退火和均匀化退火几种 ,最佳的退火工艺应是多步骤。 展开更多
关键词 Cd1-xZnxTe 退火 气-固平衡 晶体 锌压 Zn压 质量 Ⅱ-Ⅵ红外半导体材料 镉锌碲化合物 晶体缺陷
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Study of the robustness of a low-temperature dual-pressure process for removal of CO2 from natural gas
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作者 Stefania Moioli Laura A. Pellegrini +1 位作者 Paolo Vergani Fabio Brignoli 《Frontiers of Chemical Science and Engineering》 SCIE EI CAS CSCD 2018年第2期209-225,共17页
The growing use of energy by most of world population and the consequent increasing demand for energy are making unexploited low quality gas reserves interesting from an industrial point of view. To meet the required ... The growing use of energy by most of world population and the consequent increasing demand for energy are making unexploited low quality gas reserves interesting from an industrial point of view. To meet the required specifications for a natural gas grid, some compounds need to be removed from the sour stream. Because of the high content of undesired compounds (i.e., CO2) in the stream to be treated, traditional purification processes may be too energy intensive and the overall system may result unprofitable, therefore new technologies are under study. In this work, a new process for the purification of natural gas based on a low temperature distillation has been studied, focusing on the dynamics of the system. The robustness of the process has been studied by dynamic simulation of an industrial-scale plant, with particular regard to the performances when operating conditions are changed. The results show that the process can obtain the methane product with a high purity and avoid the solidification of carbon dioxide. 展开更多
关键词 CO2 capture innovative process cryogenic distillation dynamic simulation solid-liquid-vapor equilibrium
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