As next-generation rechargeable alternatives,zincbased energy storage devices(ZESs)are being intensely explored due to their merits of abundant resource,low cost,safety and environmental benignity.However,ZESs face a ...As next-generation rechargeable alternatives,zincbased energy storage devices(ZESs)are being intensely explored due to their merits of abundant resource,low cost,safety and environmental benignity.However,ZESs face a succession of critical challenges on pursuing advancing performance,including the stability and kinetics of cathode,stability and transport of zinc electrolyte,reversibility and deep utilization of metallic Zn anode.Biomass,possessing unique molecular structures with abundant functionals groups,motivates the interdisciplinary field emerging from biomass and aqueous rechargeable battery.Concerning its high compatibility with ZES design,we here summarize the application of biomass materials in ZESs from the aspects of cathode,electrolyte,membrane/separator and Zn anode,with their corresponding operational mechanisms and attractive functionalities from polymeric structures.Accordingly,the outlooks and perspectives are provided,regarding current challenges and future directions.We anticipate our minireview paves way on exploring the roles of biomass in aqueous rechargeable batteries.展开更多
Sulfide-based solid-state electrolytes (SSEs) with high Li+ conductivity (δLi^(+)) and trifling grain boundaries have great potential for all-solid-state lithium-metal batteries (ASSLMBs). Nonetheless, the in-situ de...Sulfide-based solid-state electrolytes (SSEs) with high Li+ conductivity (δLi^(+)) and trifling grain boundaries have great potential for all-solid-state lithium-metal batteries (ASSLMBs). Nonetheless, the in-situ development of mixed ionic-electronic conducting solid-electrolyte interphase (SEI) at sulfide electrolyte/Li-metal anode interface induces uneven Li electrodeposition, which causes Li-dendrites and void formation, significantly severely deteriorating ASSLMBs. Herein, we propose a dual anionic, e.g., F and N, doping strategy to Li7P3S11, tuning its composition in conjunction with the chemistry of SEI. Therefore, novel Li_(6.58)P_(2.76)N_(0.03)S_(10.12)F_(0.05) glass-ceramic electrolyte (Li_(7)P_(3)S_(11-5)LiF-3Li_(3)N-gce) achieved superior ionic (4.33 mS·cm^(−1)) and lowest electronic conductivity of 4.33 × 10^(−10) S·cm^(−1) and thus, offered superior critical current density of 0.90 mA·cm^(−2) (2.5 times 】Li7P3S11) at room temperature (RT). Notably, Li//Li cell with Li6.58P2.76N0.03S10.12F0.05-gce cycled stably over 1000 and 600 h at 0.2 and 0.3 mA·cm^(−2) credited to robust and highly conductive SEI (in-situ) enriched with LiF and Li3N species. Li3N’s wettability renders SEI to be highly Li+ conductive, ensures an intimate interfacial contact, blocks reductive reactions, prevents Li-dendrites and facilitates fast Li+ kinetics. Consequently, LiNi0.8Co0.15Al0.05O_(2) (NCA)/Li_(6.58)P_(2.76)N_(0.03)S_(10.12)F_(0.05)-gce/Li cell exhibited an outstanding first reversible capacity of 200.8/240.1 mAh·g^(−1) with 83.67% Coulombic efficiency, retained 85.11% of its original reversible capacity at 0.3 mA·cm^(−2) over 165 cycles at RT.展开更多
研究化成电压对钴酸锂(Li Co O2)正极、石墨负极的锂离子电池性能的影响。从电池容量、倍率、阻抗、存储和循环性能等方面,并从负极固体电解质相界面(SEI)膜形成机理的角度,分析电池性能的差异。化成充电截止电压设定为3.70 V,与3.80 V...研究化成电压对钴酸锂(Li Co O2)正极、石墨负极的锂离子电池性能的影响。从电池容量、倍率、阻抗、存储和循环性能等方面,并从负极固体电解质相界面(SEI)膜形成机理的角度,分析电池性能的差异。化成充电截止电压设定为3.70 V,与3.80 V相比,电池的容量、倍率、阻抗和存储等性能都有所改善。不同化成截止电压生成的SEI膜厚度不同,3.80 V时生成的SEI膜外层疏松,有机锂盐层增厚,因有机层稳定性差导致电芯的存储性能变差。展开更多
基金the support of College Students’Innovation and Entrepreneurship projectthe funding support from the 100 Talented Team of Hunan Province(XiangZu[2016]91)+1 种基金the Natural Science Foundation of Hunan Province(No.2022JJ30613)the Fundamental Research Funds for the Central Universities(No.YJ202280).
文摘As next-generation rechargeable alternatives,zincbased energy storage devices(ZESs)are being intensely explored due to their merits of abundant resource,low cost,safety and environmental benignity.However,ZESs face a succession of critical challenges on pursuing advancing performance,including the stability and kinetics of cathode,stability and transport of zinc electrolyte,reversibility and deep utilization of metallic Zn anode.Biomass,possessing unique molecular structures with abundant functionals groups,motivates the interdisciplinary field emerging from biomass and aqueous rechargeable battery.Concerning its high compatibility with ZES design,we here summarize the application of biomass materials in ZESs from the aspects of cathode,electrolyte,membrane/separator and Zn anode,with their corresponding operational mechanisms and attractive functionalities from polymeric structures.Accordingly,the outlooks and perspectives are provided,regarding current challenges and future directions.We anticipate our minireview paves way on exploring the roles of biomass in aqueous rechargeable batteries.
基金The National Natural Science Foundation of China(Nos.21203008,21975025,12274025 and 22372008)Hainan Province Science and Technology Special Fund(Nos.ZDYF2021SHFZ232 and ZDYF2023GXJS022)Hainan Province Postdoctoral Science Foundation(No.300333)supported this work.
文摘Sulfide-based solid-state electrolytes (SSEs) with high Li+ conductivity (δLi^(+)) and trifling grain boundaries have great potential for all-solid-state lithium-metal batteries (ASSLMBs). Nonetheless, the in-situ development of mixed ionic-electronic conducting solid-electrolyte interphase (SEI) at sulfide electrolyte/Li-metal anode interface induces uneven Li electrodeposition, which causes Li-dendrites and void formation, significantly severely deteriorating ASSLMBs. Herein, we propose a dual anionic, e.g., F and N, doping strategy to Li7P3S11, tuning its composition in conjunction with the chemistry of SEI. Therefore, novel Li_(6.58)P_(2.76)N_(0.03)S_(10.12)F_(0.05) glass-ceramic electrolyte (Li_(7)P_(3)S_(11-5)LiF-3Li_(3)N-gce) achieved superior ionic (4.33 mS·cm^(−1)) and lowest electronic conductivity of 4.33 × 10^(−10) S·cm^(−1) and thus, offered superior critical current density of 0.90 mA·cm^(−2) (2.5 times 】Li7P3S11) at room temperature (RT). Notably, Li//Li cell with Li6.58P2.76N0.03S10.12F0.05-gce cycled stably over 1000 and 600 h at 0.2 and 0.3 mA·cm^(−2) credited to robust and highly conductive SEI (in-situ) enriched with LiF and Li3N species. Li3N’s wettability renders SEI to be highly Li+ conductive, ensures an intimate interfacial contact, blocks reductive reactions, prevents Li-dendrites and facilitates fast Li+ kinetics. Consequently, LiNi0.8Co0.15Al0.05O_(2) (NCA)/Li_(6.58)P_(2.76)N_(0.03)S_(10.12)F_(0.05)-gce/Li cell exhibited an outstanding first reversible capacity of 200.8/240.1 mAh·g^(−1) with 83.67% Coulombic efficiency, retained 85.11% of its original reversible capacity at 0.3 mA·cm^(−2) over 165 cycles at RT.
文摘主要介绍了微米硅、多孔微米硅以及经修饰后的硅-氧化钴电极材料性能。以质量分数12%的氧化钴修饰多孔硅,首次与第二次放电电容量分别为3 590m Ah·g^(–1)和2 679m Ah·g^(–1),其放电电容量衰退率为25.4%。与没有修饰过的微米硅(2 281 m Ah·g^(–1)和555 m Ah·g^(–1))相比,效果明显提升,并且在之后的多次充放电中,也有很大提高。分析结果表明,微米多孔硅减缓了硅在充放电时的体积膨胀;被披覆氧化钴稳定了固态电解质层,进而提高了硅材料在锂离子电池中充放电循环稳定性。
