The structural flexibility of hybrid perovskite materials allows for phase transition and consequently thermochromic properties.Here we investigate the thermochromic performance in a series of copper-based layered per...The structural flexibility of hybrid perovskite materials allows for phase transition and consequently thermochromic properties.Here we investigate the thermochromic performance in a series of copper-based layered perovskites with organic cations having different alky chain lengths. Their transition temperature is found to be dependent on the organic cations due to molecular motion and hydrogen bond interaction, providing possibilities to prepare thermochromic semiconductors near room temperature for smart window applications.展开更多
Rigorous coupled-wave analysis has been used to design a glazing for hot climates. The designed glazing is relatively simple and it transmits most of the visible light and reflects most of the infrared radiation. It d...Rigorous coupled-wave analysis has been used to design a glazing for hot climates. The designed glazing is relatively simple and it transmits most of the visible light and reflects most of the infrared radiation. It does not need any external source of energy to control its optical properties. It consists of ITO and four periodic pairs of Si/SiO2, deposited on a glass sheet. The optimum thicknesses of ITO, Si and SiO2 are 0.1 μm, 0.15 and 0.4 μm, respectively. The glazing acts as an optically selective filter. It transmits about 80% of the visible light and reflects almost all the infrared radiation. The performance of the glazing is almost independent of the angle of incidence of solar radiation. This makes it suitable for all hours of the day. The fabrication of the glazing and the testing have been performed at the laboratories of the Faculty of Science, University of Witwatersrand, South Africa. Magnetron sputtering technique has been used for the fabrication. ITO, Si and SiO2 have been used as sputtering targets. The experimental results are almost identical to the simulation results.展开更多
基金supported by the Ministry of Science and Technology of China (2017YFA0204502)the National Natural Science Foundation of China (21873105)
文摘The structural flexibility of hybrid perovskite materials allows for phase transition and consequently thermochromic properties.Here we investigate the thermochromic performance in a series of copper-based layered perovskites with organic cations having different alky chain lengths. Their transition temperature is found to be dependent on the organic cations due to molecular motion and hydrogen bond interaction, providing possibilities to prepare thermochromic semiconductors near room temperature for smart window applications.
文摘Rigorous coupled-wave analysis has been used to design a glazing for hot climates. The designed glazing is relatively simple and it transmits most of the visible light and reflects most of the infrared radiation. It does not need any external source of energy to control its optical properties. It consists of ITO and four periodic pairs of Si/SiO2, deposited on a glass sheet. The optimum thicknesses of ITO, Si and SiO2 are 0.1 μm, 0.15 and 0.4 μm, respectively. The glazing acts as an optically selective filter. It transmits about 80% of the visible light and reflects almost all the infrared radiation. The performance of the glazing is almost independent of the angle of incidence of solar radiation. This makes it suitable for all hours of the day. The fabrication of the glazing and the testing have been performed at the laboratories of the Faculty of Science, University of Witwatersrand, South Africa. Magnetron sputtering technique has been used for the fabrication. ITO, Si and SiO2 have been used as sputtering targets. The experimental results are almost identical to the simulation results.
