Fine-tuning of the electron-deficient unit in A-DA1D-A typed small-molecule acceptors (SMAs) plays a crucial role in developing efficient SMAs for organic solar cells (OSCs).Here,we developed a SMA based on benzo[4,5]...Fine-tuning of the electron-deficient unit in A-DA1D-A typed small-molecule acceptors (SMAs) plays a crucial role in developing efficient SMAs for organic solar cells (OSCs).Here,we developed a SMA based on benzo[4,5]thieno[2,3-b]quinoxaline,designated as QW1,as well as three SMAs based on 1-methylindoline-2,3-dione,identified as QW2,QW3,and QW4.Compared with QW2,QW1 displays slightly blue-shifted absorption spectra and a lower LUMO energy level due to the stronger electron-withdrawing capability of BTQx in contrast to MDO.On the other hand,the introduction of a bromine atom in QW3 and QW4 causes a blue shift in absorption and a reduction in the LUMO energy level compared to QW2.Density functional theory analysis reveals that QW1 exhibits the best molecular planarity,which endows QW1 with larger electron mobility and tighter molecular stacking.Consequently,PM6:QW1 device affords a better efficiency of 15.63% than those of the devices based on QW2 (14.25%),QW3 (13.21%) and QW4 (15.03%).Moreover,the QW4-based device yields the highest open-circuit voltage of 0.933 V,and the PM6:L8-BO:QW4 ternary device realizes a PCE of 19.03%.Overall,our work demonstrates that regulation of electron-deficient central units is an effective strategy to improve the photovoltaic performance of the resulting A-DA1D-A SMAs.展开更多
Ternary organic solar cells(OSCs) have received extensive attention for improving the power conversion efficiency(PCE) of organic photovoltaics(OPVs). In this work, a novel donor material(ECTBD) consisting of benzodit...Ternary organic solar cells(OSCs) have received extensive attention for improving the power conversion efficiency(PCE) of organic photovoltaics(OPVs). In this work, a novel donor material(ECTBD) consisting of benzodithiophene(BDT) central electron donor unit was developed and synthesized. The small molecular donor has the same central unit as PM6. The addition of ECTBD into PM6:Y6 system could improve the morphology of active blend layer. In addition, ECTBD showed good morphologically compatibility when blending with PM6:Y6 host, resulting in the improvement of fill factor and current density. As a result, the ternary devices based on PM6:ECTBD:Y6 ternary system achieved a highest PCE of 16.51% with fill factor of 76.24%, which was much higher than that of the binary devices(15.7%). Overall, this work provided an effective strategy to fabricate highly efficient ternary organic solar cells through design of the novel small molecular donor as the third component.展开更多
In this paper, the new organization for unit testing embedding pair-wise mode is proposed with the core thought focused on the cooperation of programmer and tester by “cross-testing”. The typical content of unit tes...In this paper, the new organization for unit testing embedding pair-wise mode is proposed with the core thought focused on the cooperation of programmer and tester by “cross-testing”. The typical content of unit testing for the new organizing mode should have three aspects, including self-checking, cross-testing and independent-testing. For cross-testing, executing “pair-wise” mode, mainly tackles data testing, function testing and state testing, which function testing must be done by details and state testing must be considered for completeness. With the specializing of independent-testing, it should be taken as more rigid testing without arbitrariness. Consequently, strategy and measure are addressed for data testing focusing on boundary testing and function/state testing. And organizing method of procedure and key points of tackling unit testing are investigated for the new organizing mode. In order to assess the validity of our study and approach, a series of actual examples are demonstrated for GUI software. The result indicates that the execution of unit testing for the new organizing mode is effective and applicable.展开更多
Small-cell HSY-S zeolite prepared by the gas-phase ultra-stable method had been researched and developed,and industrial preparation tests of HSY-S have been successfully carried out for the first time.The acid resista...Small-cell HSY-S zeolite prepared by the gas-phase ultra-stable method had been researched and developed,and industrial preparation tests of HSY-S have been successfully carried out for the first time.The acid resistance of industrially prepared HSY-S was investigated by acid solutions with different pH values.The structures and properties of HSY-S and its acid-treated samples were characterized by XRD,XRF,BET,and IR.Results show that the HSY-S samples have the characteristics of high crystallinity,good stability,large specific surface area,and good acid resistance.展开更多
Organic small molecules （TPA-BT3T, TPA-PT3T, and TPA-DFBT3T） using triphenylamine as a donor unit, terthiophene as a bridge, and benzo-2,1,3-thiadiazole （BT）, [1,2,5]thiadiazolo[3,4-e]pyridine （PT） or 5,6-difluo...Organic small molecules （TPA-BT3T, TPA-PT3T, and TPA-DFBT3T） using triphenylamine as a donor unit, terthiophene as a bridge, and benzo-2,1,3-thiadiazole （BT）, [1,2,5]thiadiazolo[3,4-e]pyridine （PT） or 5,6-difluorobenzo[c][1,2,5]thiadiazole （DFBT） as an acceptor unit were designed and synthesized through Suzuki coupling reactions. These molecules exhibited good thermal stability with decomposition temperatures over 380℃ and broad absorption from 300 to 700 nm. Photovoltaic devices were fabricated with these small molecules as donors and PC71BM as an acceptor. The TPA-BT3T based devices exhibited a power conversion efficiency of 2.89%, higher than those of the TPA-PT3T- and TPA-DFBT3T-based devices （1.34% and 1.54% respectively）. The effects of electron-withdrawing units on absorption, energy level, charge transport, morphology, and photovoltaic properties also were investigated.展开更多
This is a comparative study examining the influence of a small-scale dementia unit and a traditional dementia unit on behaviors of the residents. The small-scale unit and the traditional unit were selected through two...This is a comparative study examining the influence of a small-scale dementia unit and a traditional dementia unit on behaviors of the residents. The small-scale unit and the traditional unit were selected through two phases in Vancouver, Canada. Seven residents from each facility completed the study. Physical environmental assessments were performed using two tools： PEAP （professional environmental assessment protocol） and TESS-NH （therapeutic environment screening survey for nursing homes）. For the assessment of residents＇ behaviors, three assessment tools were used： MOSES （multidimensional observation scale for elderly subjects）, MDS （minimum data set） and DCM （dementia care mapping）. The study found that the residents living in a small-scale environment were more engaged in activities and more likely to respond in understanding their fellow residents. Residents living in a traditional long-term care exhibited fewer signs of social interaction. The findings suggest that a small-scale homelike environment could positively influence people with dementia to be more engaged in social exchanges and activities, and consequently help in reducing their withdrawn behavior.展开更多
基金supported by the Shenzhen Science and Technology Program(ZDSYS20210623091813040,RCBS20221008093225021)the National Natural Science Foundation of China(NSFC,No.22309119)+2 种基金G.Li acknowledges the support from Research Grants Council of Hong Kong(Project Nos.15320216,15221320,C5037-18G,RGC Senior Research Fellowship Scheme(SRFS2223-5S01))the Hong Kong Polytechnic University(Sir Sze-yuen Chung Endowed Professorship Fund(8-8480)PolyU Distinguished postdoc Fellowship(1-YW4C,R.Ma),G-SAC5)。
文摘Fine-tuning of the electron-deficient unit in A-DA1D-A typed small-molecule acceptors (SMAs) plays a crucial role in developing efficient SMAs for organic solar cells (OSCs).Here,we developed a SMA based on benzo[4,5]thieno[2,3-b]quinoxaline,designated as QW1,as well as three SMAs based on 1-methylindoline-2,3-dione,identified as QW2,QW3,and QW4.Compared with QW2,QW1 displays slightly blue-shifted absorption spectra and a lower LUMO energy level due to the stronger electron-withdrawing capability of BTQx in contrast to MDO.On the other hand,the introduction of a bromine atom in QW3 and QW4 causes a blue shift in absorption and a reduction in the LUMO energy level compared to QW2.Density functional theory analysis reveals that QW1 exhibits the best molecular planarity,which endows QW1 with larger electron mobility and tighter molecular stacking.Consequently,PM6:QW1 device affords a better efficiency of 15.63% than those of the devices based on QW2 (14.25%),QW3 (13.21%) and QW4 (15.03%).Moreover,the QW4-based device yields the highest open-circuit voltage of 0.933 V,and the PM6:L8-BO:QW4 ternary device realizes a PCE of 19.03%.Overall,our work demonstrates that regulation of electron-deficient central units is an effective strategy to improve the photovoltaic performance of the resulting A-DA1D-A SMAs.
基金supported by the National Science Fund for Distinguished Young Scholars (21925506)the National Key R&D Program of China (2017YFE0106000)+5 种基金the National Natural Science Foundation of China (51773212)National Natural Science Foundation of China (21875286)Ningbo S&T Innovation 2025 Major Special Programme (2018B10055)Ningbo Municipal Science and Technology Innovative Research Team (2015B11002, 2016B10005)CAS Key Project of Frontier Science Research (QYZDB-SSW-SYS030)Science Fund for Distinguished Young Scholars of Hunan Province (2017JJ1029)。
文摘Ternary organic solar cells(OSCs) have received extensive attention for improving the power conversion efficiency(PCE) of organic photovoltaics(OPVs). In this work, a novel donor material(ECTBD) consisting of benzodithiophene(BDT) central electron donor unit was developed and synthesized. The small molecular donor has the same central unit as PM6. The addition of ECTBD into PM6:Y6 system could improve the morphology of active blend layer. In addition, ECTBD showed good morphologically compatibility when blending with PM6:Y6 host, resulting in the improvement of fill factor and current density. As a result, the ternary devices based on PM6:ECTBD:Y6 ternary system achieved a highest PCE of 16.51% with fill factor of 76.24%, which was much higher than that of the binary devices(15.7%). Overall, this work provided an effective strategy to fabricate highly efficient ternary organic solar cells through design of the novel small molecular donor as the third component.
文摘In this paper, the new organization for unit testing embedding pair-wise mode is proposed with the core thought focused on the cooperation of programmer and tester by “cross-testing”. The typical content of unit testing for the new organizing mode should have three aspects, including self-checking, cross-testing and independent-testing. For cross-testing, executing “pair-wise” mode, mainly tackles data testing, function testing and state testing, which function testing must be done by details and state testing must be considered for completeness. With the specializing of independent-testing, it should be taken as more rigid testing without arbitrariness. Consequently, strategy and measure are addressed for data testing focusing on boundary testing and function/state testing. And organizing method of procedure and key points of tackling unit testing are investigated for the new organizing mode. In order to assess the validity of our study and approach, a series of actual examples are demonstrated for GUI software. The result indicates that the execution of unit testing for the new organizing mode is effective and applicable.
基金The authors gratefully acknowledge the funding of the project by SINOPEC(No.118001-6).
文摘Small-cell HSY-S zeolite prepared by the gas-phase ultra-stable method had been researched and developed,and industrial preparation tests of HSY-S have been successfully carried out for the first time.The acid resistance of industrially prepared HSY-S was investigated by acid solutions with different pH values.The structures and properties of HSY-S and its acid-treated samples were characterized by XRD,XRF,BET,and IR.Results show that the HSY-S samples have the characteristics of high crystallinity,good stability,large specific surface area,and good acid resistance.
基金supported by the National Natural Science Foundation of China(21025418,51261130582)the National Basic Research Program of China(2011CB808401)the Chinese Academy of Sciences
文摘Organic small molecules （TPA-BT3T, TPA-PT3T, and TPA-DFBT3T） using triphenylamine as a donor unit, terthiophene as a bridge, and benzo-2,1,3-thiadiazole （BT）, [1,2,5]thiadiazolo[3,4-e]pyridine （PT） or 5,6-difluorobenzo[c][1,2,5]thiadiazole （DFBT） as an acceptor unit were designed and synthesized through Suzuki coupling reactions. These molecules exhibited good thermal stability with decomposition temperatures over 380℃ and broad absorption from 300 to 700 nm. Photovoltaic devices were fabricated with these small molecules as donors and PC71BM as an acceptor. The TPA-BT3T based devices exhibited a power conversion efficiency of 2.89%, higher than those of the TPA-PT3T- and TPA-DFBT3T-based devices （1.34% and 1.54% respectively）. The effects of electron-withdrawing units on absorption, energy level, charge transport, morphology, and photovoltaic properties also were investigated.
文摘This is a comparative study examining the influence of a small-scale dementia unit and a traditional dementia unit on behaviors of the residents. The small-scale unit and the traditional unit were selected through two phases in Vancouver, Canada. Seven residents from each facility completed the study. Physical environmental assessments were performed using two tools： PEAP （professional environmental assessment protocol） and TESS-NH （therapeutic environment screening survey for nursing homes）. For the assessment of residents＇ behaviors, three assessment tools were used： MOSES （multidimensional observation scale for elderly subjects）, MDS （minimum data set） and DCM （dementia care mapping）. The study found that the residents living in a small-scale environment were more engaged in activities and more likely to respond in understanding their fellow residents. Residents living in a traditional long-term care exhibited fewer signs of social interaction. The findings suggest that a small-scale homelike environment could positively influence people with dementia to be more engaged in social exchanges and activities, and consequently help in reducing their withdrawn behavior.
